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公开(公告)号：DE50114747D1
公开(公告)日：2009-04-16
申请号：DE50114747
申请日：2001-11-13
Applicant: BASF SE
Inventor： DISTELDORF WALTER , GOLFIER GUENTHER , MORSBACH BERND , SCHWIRTEN KURT
Abstract: A process is described for preparing esters of an acid component selected from among polybasic C 4 -C 10 carboxylic acids and an alcohol component selected from among C 3 -C 12 alkanols or from among C 3 -C 12 alkanediols, the alkyl chain of which may have interruption by from 1 to 3 oxygen atoms, by a) heating at boiling point, in a reaction zone and in the presence of an esterification catalyst, a mixture essentially consisting of the acid component or of an anhydride thereof and of the alcohol component, b) using rectification to separate the vapor comprising alcohol and water into an alcohol-rich fraction and a water-rich fraction, and c) returning the alcohol-rich fraction into the reaction zone and conducting the water-rich fraction out of the process. The process is simple to carry out and permits rapid achievement of essentially quantitative conversion.
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Patent Agency Ranking
公开(公告)号：ES2320197T3
公开(公告)日：2009-05-20
申请号：ES01993597
申请日：2001-11-13
Applicant: BASF SE
Inventor： DISTELDORF WALTER , GOLFIER GUNTHER , MORSBACH BERND , SCHWIRTEN KURT
Abstract: Procedimiento para la obtención de ésteres de un componente ácido, elegido entre los ácidos carboxílicos polibásicos con 4 hasta 10 átomos de carbono, y de un componente alcohólico, elegido entre el hexanol, el 2-etilhexanol y el etilenglicolmonobutiléter, en el que a) se calienta hasta ebullición, en una zona de reacción, una mezcla, que está constituida esencialmente por el componente ácido o por un anhídrido del mismo y por el componente alcohólico, en presencia de un catalizador para la esterificación, b) los vapores, que contienen alcohol y agua, se separan por rectificación en una fracción rica en alcohol, con un contenido en alcohol mayor que un 80% en peso y en una fracción enriquecida en agua, con respecto a la composición de los vapores retirados de la zona de la reacción, c) la fracción rica en alcohol se recicla hasta la zona de la reacción y la fracción rica en agua se purga del procedimiento.
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公开(公告)号：DE50113891D1
公开(公告)日：2008-06-05
申请号：DE50113891
申请日：2001-07-04
Applicant: BASF SE
Inventor： BREITSCHEIDEL BORIS , SELBERDINGER RICHARD , ROSSATO KLAUS , STORZUM UWE , HOLZMANN JUERGEN , DISTELDORF WALTER , UEBLER CHRISTOPH , MORSBACH BERND , PETERS JARREN , GOLFIER GUENTER
IPC: C07C67/08 , C07B61/00 , C07C29/141 , C07C29/16 , C07C31/125 , C07C45/50 , C07C47/02 , C07C69/80 , C08K5/12 , C08L27/06
Abstract: A process is described for preparing mixtures of diesters of phthalic acid with decanols and tridecanols by reacting phthalic acid or a reactive derivative of phthalic acid with a mixture made from at least one decanol and at least one tridecanol. Mixtures obtainable in this way are also described, as is their use as plasticizers for molding compositions, and also mixtures of isomeric tridecanols suitable for preparing the mixtures of diesters.
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公开(公告)号：AT424381T
公开(公告)日：2009-03-15
申请号：AT01993597
申请日：2001-11-13
Applicant: BASF SE
Inventor： DISTELDORF WALTER , GOLFIER GUENTHER , MORSBACH BERND , SCHWIRTEN KURT
Abstract: A process is described for preparing esters of an acid component selected from among polybasic C 4 -C 10 carboxylic acids and an alcohol component selected from among C 3 -C 12 alkanols or from among C 3 -C 12 alkanediols, the alkyl chain of which may have interruption by from 1 to 3 oxygen atoms, by a) heating at boiling point, in a reaction zone and in the presence of an esterification catalyst, a mixture essentially consisting of the acid component or of an anhydride thereof and of the alcohol component, b) using rectification to separate the vapor comprising alcohol and water into an alcohol-rich fraction and a water-rich fraction, and c) returning the alcohol-rich fraction into the reaction zone and conducting the water-rich fraction out of the process. The process is simple to carry out and permits rapid achievement of essentially quantitative conversion.
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公开(公告)号：DK1296926T3
公开(公告)日：2008-07-21
申请号：DK01945338
申请日：2001-07-04
Applicant: BASF SE
Inventor： BREITSCHEIDEL BORIS , SELBERDINGER RICHARD , ROSSATO KLAUS , STORZUM UWE , DISTELDORF WALTER , UEBLER CHRISTOPH , MORSBACH BERND , HOLZMANN JUERGEN , PETERS JARREN , GOLFIER GUENTER
IPC: C07C67/08 , C07B61/00 , C07C29/141 , C07C29/16 , C07C31/125 , C07C45/50 , C07C47/02 , C07C69/80 , C08K5/12 , C08L27/06
Abstract: A process is described for preparing mixtures of diesters of phthalic acid with decanols and tridecanols by reacting phthalic acid or a reactive derivative of phthalic acid with a mixture made from at least one decanol and at least one tridecanol. Mixtures obtainable in this way are also described, as is their use as plasticizers for molding compositions, and also mixtures of isomeric tridecanols suitable for preparing the mixtures of diesters.
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公开(公告)号：AT393138T
公开(公告)日：2008-05-15
申请号：AT01945338
申请日：2001-07-04
Applicant: BASF SE
Inventor： BREITSCHEIDEL BORIS , SELBERDINGER RICHARD , ROSSATO KLAUS , STORZUM UWE , HOLZMANN JUERGEN , DISTELDORF WALTER , UEBLER CHRISTOPH , MORSBACH BERND , PETERS JARREN , GOLFIER GUENTER
IPC: C07C67/08 , C07B61/00 , C07C29/141 , C07C29/16 , C07C31/125 , C07C45/50 , C07C47/02 , C07C69/80 , C08K5/12 , C08L27/06
Abstract: A process is described for preparing mixtures of diesters of phthalic acid with decanols and tridecanols by reacting phthalic acid or a reactive derivative of phthalic acid with a mixture made from at least one decanol and at least one tridecanol. Mixtures obtainable in this way are also described, as is their use as plasticizers for molding compositions, and also mixtures of isomeric tridecanols suitable for preparing the mixtures of diesters.
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