METHOD FOR PRODUCING RADIATION-CURABLE URETHANE (METH)ACRYLATES

    公开(公告)号:US20170327626A1

    公开(公告)日:2017-11-16

    申请号:US15520863

    申请日:2015-10-16

    Applicant: BASF SE

    Abstract: Disclosed are urethane (meth)acrylates obtainable by implementation of the following steps: (r1) partially reacting an alkoxylated polyol (A) with (meth)acrylic acid (B) in the presence of at least one esterification catalyst (C) and at least one polymerization inhibitor (D) and also, optionally, of a solvent (E) that forms an azeotrope with water, (o1) optionally removing at least some of the water formed in r1) from the reaction mixture, it being possible for o1) to take place during and/or after r1), (o2) optionally neutralizing the reaction mixture, (o3) if a solvent (E) has been used, optionally removing this solvent by distillation and/or (o4) stripping with a gas which is inert under the reaction conditions, (r2) reacting the reaction mixture obtained after the last of the above reaction steps with a compound (G) containing at least two epoxy groups, optionally in the presence of a catalyst (H), and (r3) reacting the reaction mixture from (r2) with at least one polyisocyanate (J) and at least one hydroxyalkyl (meth)acrylate (K) and optionally with at least one further compound (M) which contains one or more isocyanate-reactive groups, in the presence of a catalyst (L), with the proviso that the catalyst (L) used in step (r3) is a bismuth-containing catalyst.

    Heat transfer films for the dry coating of surfaces

    公开(公告)号:US10710388B2

    公开(公告)日:2020-07-14

    申请号:US16389144

    申请日:2019-04-19

    Abstract: A heat transfer film having a) a carrier film, b) at least one coating layer arranged directly on the carrier film, and c) at least one hot-sealable polymer adhesive layer is disclosed. The coating layer is based on a non-aqueous, radiation-curable, liquid composition which contains at least 60 wt %, based on the total weight of the composition, of curable constituents selected from organic oligomers which have ethylenically unsaturated double bonds. Use of the heat transfer films for the dry coating of surfaces, production of such heat transfer films, and methods for coating or lacquering surfaces of objects using the heat transfer films are also disclosed.

    HEAT TRANSFER FILMS FOR THE DRY COATING OF SURFACES
    7.
    发明申请
    HEAT TRANSFER FILMS FOR THE DRY COATING OF SURFACES 审中-公开
    用于表面干燥涂层的热转印膜

    公开(公告)号:US20160297226A1

    公开(公告)日:2016-10-13

    申请号:US14917980

    申请日:2014-09-18

    Abstract: The present invention relates to heat transfer films, comprising: a) a carrier film (2), b) at least one, for example one, two or three, coating layer(s) (3) arranged directly on the carrier film (2), c) at least one, in particular precisely one, hot-sealable polymer adhesive layer (4), wherein the coating layer is based on a non-aqueous, radiation-curable, liquid composition which contains at least 60 wt %, in particular at least 70 wt %, based on the total weight of the composition, curable constituents selected from organic oligomers which have ethylenically unsaturated double bonds and mixtures of these oligomers with monomers which have at least one ethylenically unsaturated double bond. The invention also relates to the use of the heat transfer films for the dry coating of surfaces. The invention also relates to the production of such heat transfer films and to a method for coating or lacquering surfaces of objects using the heat transfer films according to the invention.

    Abstract translation: 本发明涉及传热膜,包括:a)载体膜(2),b)直接布置在载体膜(2)上的至少一个例如一个,两个或三个涂层(3) ),c)至少一个,特别是一个可热封的聚合物粘合剂层(4),其中涂层基于非水可辐射固化的液体组合物,其含有至少60重量% 特别是至少70重量%,基于组合物的总重量,可固化组分选自具有烯键式不饱和双键的有机低聚物和这些低聚物与具有至少一个烯键式不饱和双键的单体的混合物。 本发明还涉及用于表面干涂层的传热膜。 本发明还涉及这种传热膜的生产以及使用根据本发明的传热膜涂覆或涂漆物体表面的方法。

    HEAT TRANSFER FILMS FOR THE DRY COATING OF SURFACES

    公开(公告)号:US20190315144A1

    公开(公告)日:2019-10-17

    申请号:US16389144

    申请日:2019-04-19

    Abstract: A heat transfer film having a) a carrier film, b) at least one coating layer arranged directly on the carrier film, and c) at least one hot-sealable polymer adhesive layer is disclosed. The coating layer is based on a non-aqueous, radiation-curable, liquid composition which contains at least 60 wt %, based on the total weight of the composition, of curable constituents selected from organic oligomers which have ethylenically unsaturated double bonds. Use of the heat transfer films for the dry coating of surfaces, production of such heat transfer films, and methods for coating or lacquering surfaces of objects using the heat transfer films are also disclosed.

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