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公开(公告)号:US11643561B2
公开(公告)日:2023-05-09
申请号:US16630146
申请日:2018-07-25
Applicant: BASF SE
Inventor: Nikolay A. Grigorenko , Michelle Richert
IPC: C09D11/101 , C23C18/14 , C09D11/033 , C09D7/61 , C09D7/63 , B42D25/373 , C09D7/40 , B05D3/00 , B05D5/06 , B42D25/378
CPC classification number: C09D11/101 , B05D3/002 , B05D5/067 , B42D25/373 , C09D7/61 , C09D7/63 , C09D7/66 , C09D11/033 , C23C18/143 , B05D2401/10 , B05D2601/02 , B42D25/378
Abstract: The present invention relates to a process for the preparation of thin silver nano-particles containing layers, which are produced directly on a substrate as part of a coating or printing process. The layers can show different colours in transmittance and reflectance. The invention further relates to decorative and security elements. When the layers are applied over a security element, such as a hologram, the obtained products may show different colours in reflection and transmission, an extremely bright optically variable image (OVD image). Depending on the thickness of the layer a more or less intensive metallic aspect appears.
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公开(公告)号:US20150241845A1
公开(公告)日:2015-08-27
申请号:US14423843
申请日:2013-09-13
Applicant: BASF SE
Inventor: Michelle Richert , Roland Fleury , Nikolay A. Grigorenko , Frank Knocke
IPC: G03H1/18 , G03H1/00 , B42D25/328
CPC classification number: G03H1/182 , B42D25/328 , C09D5/29 , C09D7/40 , C09D7/68 , C09D7/70 , G02B5/18 , G02B5/1833 , G03H1/0011 , G03H1/0256 , G03H1/28 , G03H2001/2635 , G03H2250/43 , G03H2260/33
Abstract: The present invention relates to complex security elements based on recording materials for optical elements with refractive index modulation, in particular, holograms, which are subsequently coated with specific metallic nano-shaped metal particles, a method for their manufacture, in particular on a paper or on a plastic substrate and a security product obtainable using the security element. A further aspect of the invention is the use of such a security element for the prevention of counterfeit or reproduction of a document of value.
Abstract translation: 本发明涉及基于用于具有折射率调制的光学元件(特别是全息图)的记录材料的复合安全元件,其随后涂覆有特定的金属纳米金属颗粒,其制造方法,特别是在纸张或纸张上 在塑料基板上和使用安全元件可获得的安全产品。 本发明的另一方面是使用这种安全元件来防止伪造或复制有价值的文件。
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公开(公告)号:US10322603B2
公开(公告)日:2019-06-18
申请号:US14578657
申请日:2014-12-22
Applicant: BASF SE
Inventor: Michelle Richert , Thomas Bolle , Roland Fleury
IPC: G03H1/04 , B41M7/00 , B41M3/14 , B42D25/23 , B42D25/24 , B42D25/328 , B42D25/324 , B42D25/30 , B42D25/378 , B42D25/405 , B42D25/21 , B42D25/373 , G03H1/02 , B42D25/42 , B42D25/425 , B42D25/29 , B05D3/06 , B41M3/06 , B41M1/24 , G03H1/18
Abstract: A method and an apparatus for forming a surface relief microstructure, especially an optically variable image on a paper substrate are provided, the method comprising the steps of: A) applying a curable composition to at least a portion of the frontside of the paper substrate; B) contacting at least a portion of the curable composition with surface relief microstructure, especially optically variable image forming means; C) curing the composition by using at least one UV lamp (1, 2, 3) which is arranged on the backside of the paper substrate; D) optionally depositing a layer of a transparent high refractive index material and/or a metallic layer on at least a portion of the cured composition, wherein the lamp (1, 2, 3) having emission peak(s) in the UV-A and near VIS range and the curable composition comprises at least a photoinitiator which absorbs in the UV-A region and preferably in the near VIS range. A paper product obtainable uses the method and an apparatus for forming a surface relief microstructure on a paper substrate. Surface relief microstructures, such as holograms may be replicated rapidly and with accuracy on a paper substrate by using the method and the apparatus.
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公开(公告)号:US09765227B2
公开(公告)日:2017-09-19
申请号:US15224789
申请日:2016-08-01
Applicant: BASF SE
Inventor: Nikolay A. Grigorenko , Michelle Richert
IPC: B41M3/14 , B44F1/12 , C09D11/037 , B44F1/14 , C09D5/29 , C09D7/12 , C09D11/101 , B05D3/00 , C09D11/107 , C09D11/14 , C09D11/50 , C08K3/08
CPC classification number: C09D11/037 , B05D3/007 , B41M3/148 , B44F1/14 , C08K3/08 , C08K2003/0806 , C08K2201/016 , C09D5/29 , C09D7/67 , C09D7/68 , C09D7/70 , C09D11/101 , C09D11/107 , C09D11/14 , C09D11/50 , Y10T156/10 , Y10T428/24851 , Y10T428/25 , Y10T428/256
Abstract: The present invention relates to the use of coating compositions, comprising shaped transition metal, especially silver, particles and a binder, wherein the ratio of pigment to binder is preferably such that the resulting coating shows an angle dependent color change, for the production of security elements and holograms. When the coating compositions of the present invention are used in coating a hologram the obtained products show a an angle dependent color change (flip/flop effect), different colors in reflection and transmission, an extremely bright OVD image and extremely strong rainbow effect, high purity and contrast.
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公开(公告)号:US09678475B2
公开(公告)日:2017-06-13
申请号:US14423843
申请日:2013-09-13
Applicant: BASF SE
Inventor: Michelle Richert , Roland Fleury , Nikolay A. Grigorenko , Frank Knocke
IPC: G03H1/02 , G02B5/18 , G03H1/18 , C09D5/29 , G03H1/28 , C09D7/12 , B42D25/328 , G03H1/00 , G03H1/26
CPC classification number: G03H1/182 , B42D25/328 , C09D5/29 , C09D7/40 , C09D7/68 , C09D7/70 , G02B5/18 , G02B5/1833 , G03H1/0011 , G03H1/0256 , G03H1/28 , G03H2001/2635 , G03H2250/43 , G03H2260/33
Abstract: The present invention relates to complex security elements based on recording materials for optical elements with refractive index modulation, in particular, holograms, which are subsequently coated with specific metallic nano-shaped metal particles, a method for their manufacture, in particular on a paper or on a plastic substrate and a security product obtainable using the security element. A further aspect of the invention is the use of such a security element for the prevention of counterfeit or reproduction of a document of value.
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公开(公告)号:US12296391B2
公开(公告)日:2025-05-13
申请号:US17424607
申请日:2020-01-20
Applicant: BASF SE
Inventor: Nikolay A. Grigorenko , Michelle Richert
IPC: B22F7/04 , B22F1/054 , B42D25/373 , B42D25/382 , B42D25/45 , C09D11/033 , C09D11/037 , C09D11/14
Abstract: The present invention relates to security elements, comprising (a) a substrate, (b) on at least part of the substrate surface a metal layer, (c) optionally on at least part of the metal layer a dielectric layer, (d) on at least part of the metal layer, or the dielectric layer, a layer obtained by overcoating the metal layer, or the dielectric layer with a composition, comprising (i) silver nanoparticles, (ii) a solvent, (iii) (surface) stabilizing agent(s) and (iv) optionally a binder, and (e) a protective layer on top of layer (d). The maximum absorption wavelength of the silver nanoparticles in layer (d) is controlled by the amount of (surface) stabilizing agent(s) and optionally binder relative to the amount of silver nanoparticles to be preferably in the range of 700 to 1600 nm.
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公开(公告)号:US20150158323A1
公开(公告)日:2015-06-11
申请号:US14407706
申请日:2013-06-10
Applicant: BASF SE
Inventor: Michelle Richert , Roland Fleury , Nikolay A. Grigorenko
IPC: B42D25/405 , B42D25/30 , G03H1/04
CPC classification number: B42D25/405 , B29C35/0888 , B29C35/10 , B29C59/046 , B29C2035/0827 , B29C2059/023 , B41F17/00 , B41M1/24 , B41M3/003 , B41M3/006 , B41M3/14 , B41M3/148 , B42D25/29 , B42D25/30 , B42D25/324 , B42D25/328 , B42D25/351 , B42D25/36 , B42D25/42 , B42D25/425 , B42D2035/20 , C09D5/29 , C09D5/36 , C09D5/38 , C09D7/67 , C09D7/68 , C09D7/70 , G03H1/0011 , G03H1/0244 , G03H1/028 , G03H1/04 , G03H2250/43 , G03H2270/32
Abstract: The present invention relates to a method for forming a surface relief microstructure, especially an optically variable image (an optically variable device) on a transparent or translucent substrate and a product obtainable using the method. A further aspect of the invention is the use for the prevention of counterfeit or reproduction of a document of value and a method of forming a coating showing an angle dependent color change.
Abstract translation: 本发明涉及一种用于形成表面浮雕微结构的方法,特别是在透明或半透明基底上的光学可变图像(光学可变装置)和可使用该方法获得的产品。 本发明的另一方面是用于防止有价值的文件的伪造或再现的用途以及形成依赖于角度的颜色变化的涂层的方法。
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公开(公告)号:US12208447B2
公开(公告)日:2025-01-28
申请号:US17288207
申请日:2019-10-21
Applicant: BASF SE
Inventor: Nikolay A. Grigorenko , Andre Oswald , Michelle Richert
IPC: B42D25/373 , B22F1/00 , B22F1/052 , B22F1/054 , B22F1/0545 , B22F1/07 , B22F1/102 , B22F9/24 , B41M3/14 , B42D25/391 , C08K3/08 , C09D7/63 , B82Y30/00 , B82Y40/00 , C09D5/29 , C09D11/037
Abstract: The present invention relates to compositions, comprising silver nanoplatelets, wherein the mean diameter of the silver nanoplatelets, present in the composition, is in the range of 20 to 70 nm with standard deviation being less than 50% and the mean thickness of the silver nanoplatelets, present in the composition, is in the range of 5 to 30 nm with standard deviation being less than 50%, wherein the mean aspect ratio of the silver nanoplatelets is higher than 1.5, a process for its production, printing inks containing the compositions and their use in security products. The highest wavelength absorption maximum of the population of all silver nanoplatelets in the composition being within the range of 450 to 550 nm. A coating, comprising the composition, shows a red, or magenta color in transmission and a greenish-metallic color in reflection.
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公开(公告)号:US10252561B2
公开(公告)日:2019-04-09
申请号:US14891528
申请日:2014-05-16
Applicant: BASF SE
Inventor: Michelle Richert , Oliver Seeger , Nikolay A. Grigorenko
IPC: B42D25/29 , B42D25/364 , B42D25/328 , B42D25/373 , B42D25/24 , B42D25/30 , B42D25/40 , C09D7/00 , C09D101/18 , C09D5/29 , B41M3/14 , C08K3/08 , B32B7/02 , B32B9/00 , C08L101/00 , G07D7/00 , G09F3/00 , C09D5/00
Abstract: The present invention relates to complex security elements based on liquid crystal coatings which are subsequently coated with specific metallic nano-shaped metal particles, a method for their manufacture, in particular on a glass, paper or on a plastic substrate and a security product obtainable using the security element. The security element may contain additionally an embossed surface relief microstructure, especially an optically variable image (an optically variable device, OVD), such as a hologram. A further aspect of the invention is the use of such a security element for the prevention of counterfeit or reproduction of a document of value.
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公开(公告)号:US10125278B2
公开(公告)日:2018-11-13
申请号:US15650132
申请日:2017-07-14
Applicant: BASF SE
Inventor: Nikolay A. Grigorenko , Michelle Richert
IPC: B41M3/14 , C09D11/037 , B44F1/14 , C09D5/29 , C09D11/101 , B05D3/00 , C09D11/107 , C09D11/14 , C09D11/50 , C09D7/40 , C08K3/08
Abstract: The present invention relates to the use of coating compositions, comprising shaped transition metal, especially silver, particles and a binder, wherein the ratio of pigment to binder is preferably such that the resulting coating shows an angle dependent color change, for the production of security elements and holograms. When the coating compositions of the present invention are used in coating a hologram the obtained products show a an angle dependent color change (flip/flop effect), different colors in reflection and transmission, an extremely bright OVD image and extremely strong rainbow effect, high purity and contrast.
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