公开(公告)号：US10351422B2

公开(公告)日：2019-07-16

申请号：US14651862

申请日：2013-12-12

Applicant: BASF SE ,  LINDE AG

Inventor： Otto Machhammer ,  Wolfgang Alois Hormuth ,  Christian Schneider ,  Andreas Bode ,  Volker Goeke ,  Hans-Juergen Maass ,  Matthias Kern ,  Dirk Klingler ,  Rene Koenig ,  Philipp Brueggemann ,  Jens Bernnat ,  Grigorios Kolios

IPC: C01B3/28 ,  B01J19/00 ,  B01J8/00

Abstract: The invention relates to a method of carrying out heat-consuming processes, wherein the total energy required averaged over a year for the heat-consuming process originates from at least two different energy sources, where one of the energy sources is an electric energy source whose power varies in the range from 0 to 100% of the total power required, and three different energy modes can individually provide the total power required for the heat-consuming process: (i) exclusively electric energy, (ii) a mixture of electric energy and at least one further nonelectric energy source or (iii) exclusively nonelectric energy, where the changeover time in which the change from one energy mode to another energy mode is completed is not more than 30 minutes.

公开(公告)号：US10233078B2

公开(公告)日：2019-03-19

申请号：US14653482

申请日：2013-12-13

Applicant: BASF SE ,  Linde AG ,  ThyssenKrupp Industrial Solutions AG

Inventor： Christian Schneider ,  Andreas Bode ,  Dirk Klingler ,  Otto Machhammer ,  Philipp Brueggemann ,  Matthias Kern ,  Wolfgang Alois Hormuth ,  Marcus Guzmann ,  Rene Koenig ,  Jens Bernnat ,  Grigorios Kolios ,  Volker Goeke ,  Hans-Juergen Maass ,  Karsten Bueker

IPC: C01B3/34

Abstract: The invention relates to a process for utilizing a hydrocarbon-comprising and/or carbon dioxide-comprising coproduct gas, accompanying gas and/or biogas, wherein hydrocarbon-comprising and/or carbon dioxide-comprising coproduct gas, accompanying gas and/or biogas is introduced into a reaction space and the multicomponent mixture comprised in the coproduct gas, accompanying gas and/or biogas is converted in a high-temperature zone at temperatures of more than 1000° C. and in the presence of a carrier into a product gas mixture which comprises more than 95% by volume of CO, CO2, H2, H2O, CH4 and N2 and optionally into a carbon-comprising solid which is deposited to an extent of at least 75% by weight, based on the total mass of the carbon-comprising solid, on the carrier where the flow velocity of the gas mixture of coproduct gas, accompanying gas and/or biogas in the reaction zone is less than 20 m/s.

公开(公告)号：US20130236801A1

公开(公告)日：2013-09-12

申请号：US13781965

申请日：2013-03-01

Applicant: BASF SE

Inventor： Bernd Bastian SCHAACK ,  Alexander Panchenko ,  Philipp Brueggemann

IPC: H01M8/06 ,  C07C209/02 ,  H01M8/10

CPC classification number: H01M8/0612 ,  C07C209/02 ,  H01M2008/1095 ,  Y02P20/582 ,  C07C211/04 ,  C07C211/46 ,  C07C211/47 ,  C07C211/50 ,  C07C211/51

Abstract: The present invention relates to a process for direct amination of hydrocarbons to amino hydrocarbons, comprising (a) the reaction of a reactant stream E comprising at least one hydrocarbon and at least one aminating reagent to give a reaction mixture R comprising at least one amino hydrocarbon and hydrogen in a reaction zone RZ, and (b) electrochemical removal of at least a portion of the hydrogen formed in the reaction from the reaction mixture R by means of at least one gas-tight membrane electrode assembly which is in contact with the reaction zone RZ on the retentate side and which has at least one selectively proton-conducting membrane, at least a portion of the hydrogen being oxidized over an anode catalyst to protons on the retentate side of the membrane, and the protons, after passing through the membrane, being partly or fully reacted with an oxidizing agent over a cathode catalyst to give water on the permeate side, and the oxidizing agent originating from a stream O which is contacted with the permeate side of the membrane.

Abstract translation: 本发明涉及将烃直接胺化成氨基烃的方法，其包括（a）包含至少一种烃和至少一种胺化试剂的反应物流E的反应，得到包含至少一种氨基烃的反应混合物R 和反应区RZ中的氢，和（b）通过与反应接触的至少一个气密膜电极组件电化学去除反应混合物R中形成的氢的至少一部分 并且具有至少一个选择性质子传导膜，所述氢的至少一部分在阳极催化剂上被氧化以在所述膜的滞留侧上的质子和所述质子在通过所述膜之后 ，在阴极催化剂上与氧化剂部分或完全反应以在渗透侧产生水，并且源自流O的氧化剂，其中i s与膜的渗透侧接触。

公开(公告)号：US20130233721A1

公开(公告)日：2013-09-12

申请号：US13785980

申请日：2013-03-05

Applicant: BASF SE

Inventor： Bernd Bastian SCHAACK ,  Alexander Panchenko ,  Philipp Brueggemann

IPC: C07C209/02 ,  C25B3/04

CPC classification number: C07C209/02 ,  C25B3/00 ,  C25B3/04 ,  Y02P20/582 ,  C07C211/46 ,  C07C211/47 ,  C07C211/50 ,  C07C211/51 ,  C07C211/04

Abstract: The present invention relates to a process for direct amination of hydrocarbons to amino hydrocarbons, comprising (a) the reaction of a reactant stream E comprising at least one hydrocarbon and at least one aminating reagent to give a reaction mixture R comprising at least one amino hydrocarbon and hydrogen in a reaction zone RZ, and (b) electrochemical removal of at least a portion of the hydrogen formed in the reaction from the reaction mixture R by means of at least one gas-tight membrane electrode assembly which is in contact with the reaction zone RZ on the retentate side and which has at least one selectively proton-conducting membrane, at least a portion of the hydrogen being oxidized over an anode catalyst to protons on the retentate side of the membrane, and the protons, after passing through the membrane, being partly or fully reduced by applying a voltage over a cathode catalyst to give hydrogen on the permeate side.

Abstract translation: 本发明涉及将烃直接胺化成氨基烃的方法，其包括（a）包含至少一种烃和至少一种胺化试剂的反应物流E的反应，得到包含至少一种氨基烃的反应混合物R 和反应区RZ中的氢，和（b）通过与反应接触的至少一个气密膜电极组件电化学去除反应混合物R中形成的氢的至少一部分 并且具有至少一个选择性质子传导膜，所述氢的至少一部分在阳极催化剂上被氧化以在所述膜的滞留侧上的质子和所述质子在通过所述膜之后 ，通过在阴极催化剂上施加电压以在渗透侧产生氢来部分或完全还原。