公开(公告)号：US20130150542A1

公开(公告)日：2013-06-13

申请号：US13738227

申请日：2013-01-10

Applicant: BASF SE

Inventor： MICHAEL ROTH ,  RUDOLF PFAENDNER ,  GERHARD LUFT ,  FRANK FREIDEL

IPC: C08F110/02

CPC classification number: C08F110/02 ,  C08F10/00 ,  C08F4/32 ,  C08F4/00 ,  C08F2/00 ,  C08F2500/12 ,  C08F2500/10

Abstract: The present invention relates to a method for the radical polymerization or copolymerization of ethylene at high pressures using a hydroxylamine ester as radical initiator. The hydroxylamine esters according to the invention are suitable initiators for the high pressure polymerization of ethylene leading to high molecular weight polyethylenes with narrow molecular weight distributions (Poyldispersity Index PD=1,2−4.5).

Abstract translation: 本发明涉及使用羟胺作为自由基引发剂在高压下自由基聚合或共聚乙烯的方法。 根据本发明的羟胺酯是用于乙烯的高压聚合的引发剂，其导致具有窄分子量分布（分散度指数PD = 1,2-4.5）的高分子量聚乙烯。