公开(公告)号：WO2015085083A1

公开(公告)日：2015-06-11

申请号：PCT/US2014/068604

申请日：2014-12-04

Applicant: BASF SE

Inventor： HOEY, Michael Dennis ,  SCANLON, Eugene ,  MENSAH, Frederick ,  BROWN, Douglas, S. ,  JUNG, Alfred, Karl ,  SEIBEL, Shaun, Robert ,  HASENHUETL, Patrick, Daniel ,  SCHMITT, Ralf Lorenz

IPC: C10M137/00 ,  C10M133/04

CPC classification number: C10M159/123 ,  C07F9/06 ,  C07F9/1651 ,  C10M137/105 ,  C10M2223/043 ,  C10M2223/047 ,  C10N2220/021 ,  C10N2230/06 ,  C10N2230/08 ,  C10N2230/50 ,  C10N2230/64 ,  C10N2240/08 ,  C10N2240/10 ,  C10N2240/12 ,  C10N2240/14 ,  C10N2240/40

Abstract: A composition comprises the reaction product of a dithiophosphate derivative and an amine. The reaction product is present in the composition in an amount of at least about 25 wt.%. The composition may include additional components. A method of forming the composition comprises the step of combining the dithiophosphate derivative and the amine to form the composition. A method of increasing thermal stability of a dithiophosphate derivative comprises the step of combining the dithiophosphate derivative and an amine. The dithiophosphate derivative can decompose to form hydrogen sulfide (H2S). However, the amine substantially prevents thermal decomposition of the dithiophosphate derivative. An example of the dithiophosphate derivative is 3-(di-isobutoxy-thiophosphorylsulfanyl)-2-methyl-propanoic acid. An example of the amine is ditridecyl amine. The composition can be used for a variety of applications. For example, the composition can be used as an antiwear compound/additive in lubricants, metalworking fluids, hydraulic fluids, etc.

Abstract translation: 组合物包含二硫代磷酸酯衍生物与胺的反应产物。 反应产物以至少约25重量％的量存在于组合物中。 组合物可以包括另外的组分。 形成组合物的方法包括将二硫代磷酸酯衍生物和胺组合以形成组合物的步骤。 提高二硫代磷酸酯衍生物的热稳定性的方法包括将二硫代磷酸酯衍生物与胺组合的步骤。 二硫代磷酸酯衍生物可分解形成硫化氢（H2S）。 然而，胺基本上防止二硫代磷酸酯衍生物的热分解。 二硫代磷酸酯衍生物的实例是3-（二 - 异丁氧基 - 硫代磷酰基硫烷基）-2-甲基 - 丙酸。 胺的实例是二联三联胺。 该组合物可用于各种应用。 例如，组合物可用作润滑剂，金属加工液，液压油等中的抗磨料/添加剂。

公开(公告)号：WO2016069873A1

公开(公告)日：2016-05-06

申请号：PCT/US2015/058009

申请日：2015-10-29

Applicant: BASF SE

Inventor： SCANLON, Eugene ,  HAYDEN, Thomas ,  JUNG, Alfred ,  HOEY, Michael

IPC: C10M133/16 ,  C10M169/04

CPC classification number: C10M141/10 ,  C10M133/06 ,  C10M133/16 ,  C10M137/10 ,  C10M141/12 ,  C10M2203/1006 ,  C10M2203/1025 ,  C10M2205/0285 ,  C10M2207/28 ,  C10M2215/04 ,  C10M2215/08 ,  C10M2215/082 ,  C10M2223/045 ,  C10N2210/02 ,  C10N2230/06 ,  C10N2230/54 ,  C10N2240/10 ,  C10N2220/022

Abstract: The present disclosure provides an additive package for a lubricant composition that includes an alkoxvlated amide, an ester, and an anti-wear agent including phosphorus, molybdenum, or a combination thereof. The present disclosure also provides a lubricant composition that includes a base oil, the alkoxvlated amide, the ester, and the anti-wear agent including phosphorus, molybdenum, or a combination thereof. The present disclosure further provides a method of lubricating an internal combustion engine for improving fuel economy.

Abstract translation: 本公开提供了一种用于润滑剂组合物的添加剂包，其包含烷氧基化酰胺，酯和包含磷，钼或其组合的抗磨剂。 本公开还提供了包含基础油，烷氧基化酰胺，酯和包含磷，钼或其组合的抗磨剂的润滑剂组合物。 本公开还提供了一种润滑内燃机以提高燃料经济性的方法。

公开(公告)号：WO2013009381A1

公开(公告)日：2013-01-17

申请号：PCT/US2012/036327

申请日：2012-05-03

Applicant: BASF SE ,  RABBAT, Philippe, Marc Andre ,  FENTON, Ryan, James ,  CHASAN, David, Eliezer ,  DESANTIS, Kevin, J. ,  HOEY, Michael ,  SCANLON, Eugene

Inventor： RABBAT, Philippe, Marc Andre ,  FENTON, Ryan, James ,  CHASAN, David, Eliezer ,  DESANTIS, Kevin, J. ,  HOEY, Michael ,  SCANLON, Eugene

IPC: C10M141/10 ,  C10M161/00

CPC classification number: C10M161/00 ,  C10M141/10 ,  C10M2207/124 ,  C10M2209/104 ,  C10M2223/043 ,  C10M2223/047 ,  C10M2223/049 ,  C10N2230/06 ,  C10N2230/45 ,  C10N2240/10 ,  C10M2209/108 ,  C10M2209/105

Abstract: The instant disclosure provides a lubricant composition having improved four- ball antiwear properties. The lubricant composition includes a base oil and one or more alkylethercarboxylic acid corrosion inhibitor(s) having the formula: (formula) wherein R is a straight or branched chain C 6 -C 18 alkyl group and n is a number of from 0 to 5. The lubricant composition also includes an ashless antiwear additive including phosphorous. The four-ball antiwear properties are reported as an average diameter of wear scars pursuant to ASTM D4172. The average diameter of the wear scars resulting from the lubricant composition are at least 5% smaller than the average diameter of the wear scars resulting from a standard that includes the base oil and the antiwear additive and that is free of the one or more alkylethercarboxylic acid corrosion inhibitor(s).

Abstract translation: 本公开提供了具有改进的四球抗磨损性质的润滑剂组合物。 润滑剂组合物包括基础油和一种或多种具有下式的烷基醚羧酸腐蚀抑制剂：（式）其中R是直链或支链C6-C18烷基，n是0至5的数。 润滑剂组合物还包括含有磷的无灰抗磨添加剂。 根据ASTM D4172，四球抗磨损性能被报告为磨损痕迹的平均直径。 由润滑剂组合物产生的磨损痕迹的平均直径比由包括基础油和抗磨添加剂的标准产生的并且不含一种或多种烷基醚羧酸的磨损痕迹的平均直径小至少5％ 腐蚀抑制剂。

公开(公告)号：WO2012135054A1

公开(公告)日：2012-10-04

申请号：PCT/US2012/030415

申请日：2012-03-23

Applicant: BASF SE ,  SCANLON, Eugene ,  DESANTIS, Kevin ,  BETTE, Virginie ,  PETZOLDT, Jochen

Inventor： SCANLON, Eugene ,  DESANTIS, Kevin ,  BETTE, Virginie ,  PETZOLDT, Jochen

IPC: C10M145/14 ,  C08F20/18 ,  C10M149/04 ,  C10N20/04 ,  C10N30/02 ,  C10N30/08 ,  C10N70/00

CPC classification number: C10M145/14 ,  C08F220/14 ,  C08F220/18 ,  C08F2220/1833 ,  C10M149/04 ,  C10M2209/084 ,  C10N2220/021 ,  C10N2230/02 ,  C10N2230/08 ,  C10N2270/00

Abstract: A lubricant composition having improved non-Newtonian viscometrics includes at least 85 weight percent of a base oil and 1 to 15 weight percent of a lubricant additive. The additive itself includes 10 to 80 weight percent of a diluent oil and 30 to 80 weight percent of a random co-polymeric viscosity index improver. The viscosity index improver is the free -radical polymerization product of at least 5 to 15 weight percent methyl methacrylate and 5 to 95 weight percent of a C 8 -C 10 alkyl (meth)acrylate. The additive is formed using a method that includes the step of providing the diluent oil, the methyl methacrylate, the C 8 -C 10 alkyl (meth)acrylate, and a free-radical initiator. The method also includes the steps of flowing the diluent oil into a reactor, flowing the methyl methacrylate and the C 8 -C 10 alkyl (meth)acrylate into the reactor independently from the free-radical initiator, and flowing the free-radical initiator into the reactor.

Abstract translation: 具有改进的非牛顿粘度的润滑剂组合物包括至少85重量％的基础油和1至15重量％的润滑剂添加剂。 添加剂本身包含10至80重量％的稀释油和30至80重量％的无规共聚粘度指数改进剂。 粘度指数改进剂是至少5至15重量％甲基丙烯酸甲酯和5至95重量％的（甲基）丙烯酸C 8 -C 10烷基酯的自由基聚合产物。 使用包括提供稀释油，甲基丙烯酸甲酯，（甲基）丙烯酸C 8 -C 10烷基酯和自由基引发剂的步骤的方法形成添加剂。 该方法还包括将稀释油流入反应器中的步骤，将甲基丙烯酸甲酯和（甲基）丙烯酸烷基酯（甲基）丙烯酸烷基酯独立于自由基引发剂流入反应器，并将自由基引发剂流入反应器 。

公开(公告)号：WO2018089416A1

公开(公告)日：2018-05-17

申请号：PCT/US2017/060527

申请日：2017-11-08

Applicant: BASF SE ,  DESANTIS, Kevin ,  SCANLON, Eugene ,  KUHLMAN, Roger

Inventor： DESANTIS, Kevin ,  SCANLON, Eugene ,  KUHLMAN, Roger

IPC: C10M133/02

Abstract: A lubricant composition includes a base oil and an additive package. The additive package includes a seal compatibility additive chosen from a halide seal compatibility additive, an epoxide seal compatibility additive, a boroxine seal compatibility additive, a sulfonate ester seal compatibility additive, and combinations thereof. The alkoxylated amide and the ester are set forth in general formulas A and B, respectively: In general formulas A and B, each R 13 , R II , R III , and R IV , is, independently, a linear or branched, saturated or unsaturated, hydrocarbyl group. In addition, at least one of R II and R III include an alkoxy group, and R IV includes an amine group.

Abstract translation: 润滑剂组合物包含基础油和添加剂包。 添加剂包装包括选自卤化物密封相容性添加剂，环氧化物密封相容性添加剂，环硼氧烷密封相容性添加剂，磺酸酯密封相容性添加剂及其组合的密封相容性添加剂。 烷氧基化酰胺和酯分别在通式A和B中给出：在通式A和B中，每个R 13，R II，R 51， III和R IV独立地为直链或支链的饱和或不饱和的烃基。 此外，R 1和R 3中的至少一个包括烷氧基，并且R 4包括胺基。

公开(公告)号：WO2016004353A1

公开(公告)日：2016-01-07

申请号：PCT/US2015/039061

申请日：2015-07-02

Applicant: BASF SE ,  DESANTIS, Kevin ,  HOEY, Michael ,  JUNG, Alfred, K. ,  JONES, Stephen, R. ,  SCANLON, Eugene ,  RABBAT, Philippe

Inventor： DESANTIS, Kevin ,  HOEY, Michael ,  JUNG, Alfred, K. ,  JONES, Stephen, R. ,  SCANLON, Eugene ,  RABBAT, Philippe

IPC: C10M129/68 ,  C10M169/04

CPC classification number: C10M141/08 ,  C10M135/10 ,  C10M2203/1006 ,  C10M2207/026 ,  C10M2215/02 ,  C10M2215/064 ,  C10M2215/221 ,  C10M2219/044 ,  C10M2223/045 ,  C10N2210/02 ,  C10N2230/36 ,  C10N2230/45 ,  C10N2230/52 ,  C10N2240/10

Abstract: This disclosure is directed to a lubricant composition having improved compatibility with fluoropolymer seals. The lubricant composition includes a base oil and a sulfonate ester. The disclosure is also directed to an additive package for a lubricant composition that provides improved compatibility with fluoropolymer seals. The additive package includes the sulfonate ester. The disclosure is also directed to a method of improving compatibility of a lubricant composition with a fluoropolymer seal disposed in an internal combustion engine. The sulfonate ester improves the compatibility with fluoropolymer seals of the resultant lubricant composition.

Abstract translation: 本发明涉及具有改进的与氟聚合物密封相容性的润滑剂组合物。 润滑剂组合物包括基础油和磺酸酯。 本公开还涉及用于润滑剂组合物的添加剂包，其提供与含氟聚合物密封件的改进的相容性。 添加剂包括磺酸酯。 本发明还涉及一种提高润滑剂组合物与设置在内燃机中的氟聚合物密封件的相容性的方法。 磺酸酯改善了与所得润滑剂组合物的氟聚合物密封件的相容性。

公开(公告)号：EP3212746A1

公开(公告)日：2017-09-06

申请号：EP15855929.4

申请日：2015-10-29

Applicant: BASF SE

Inventor： SCANLON, Eugene ,  HAYDEN, Thomas ,  JUNG, Alfred ,  HOEY, Michael

IPC: C10M133/16 ,  C10M169/04

CPC classification number: C10M141/10 ,  C10M133/06 ,  C10M133/16 ,  C10M137/10 ,  C10M141/12 ,  C10M2203/1006 ,  C10M2203/1025 ,  C10M2205/0285 ,  C10M2207/28 ,  C10M2215/04 ,  C10M2215/08 ,  C10M2215/082 ,  C10M2223/045 ,  C10N2210/02 ,  C10N2230/06 ,  C10N2230/54 ,  C10N2240/10 ,  C10N2220/022

Abstract: Also disclosed is a method for maximizing the effectiveness of a friction modifier in a racing oil composition thus increasing the fuel economy of a racing vehicle. The method includes providing the racing oil composition and lubricating an internal combustion engine of a racing vehicle to increase the fuel economy of the racing vehicle.

Abstract translation: 本公开提供了用于润滑剂组合物的添加剂包，其包含烷氧基化酰胺，酯和包含磷，钼或其组合的抗磨剂。 本发明还提供了一种润滑剂组合物，其包含基础油，烷氧基化酰胺，酯和包含磷，钼或其组合的抗磨剂。 本公开还提供了一种润滑内燃机以提高燃料经济性的方法。

公开(公告)号：EP3077488A1

公开(公告)日：2016-10-12

申请号：EP14868196.8

申请日：2014-12-04

Applicant: BASF SE

Inventor： HOEY, Michael Dennis ,  SCANLON, Eugene ,  MENSAH, Frederick ,  BROWN, Douglas, S. ,  JUNG, Alfred, Karl ,  SEIBEL, Shaun, Robert ,  HASENHUETL, Patrick, Daniel ,  SCHMITT, Ralf Lorenz

IPC: C10M137/00 ,  C10M133/04

CPC classification number: C10M159/123 ,  C07F9/06 ,  C07F9/1651 ,  C10M137/105 ,  C10M2223/043 ,  C10M2223/047 ,  C10N2220/021 ,  C10N2230/06 ,  C10N2230/08 ,  C10N2230/50 ,  C10N2230/64 ,  C10N2240/08 ,  C10N2240/10 ,  C10N2240/12 ,  C10N2240/14 ,  C10N2240/40

Abstract: A composition comprises the reaction product of a dithiophosphate derivative and an amine. The reaction product is present in the composition in an amount of at least about 25 wt. %. The composition may include additional components. A method of forming the composition comprises the step of combining the dithiophosphate derivative and the amine to form the composition. A method of increasing thermal stability of a dithiophosphate derivative comprises the step of combining the dithiophosphate derivative and an amine. The dithiophosphate derivative can decompose to form hydrogen sulfide (H2S). However, the amine substantially prevents thermal decomposition of the dithiophosphate derivative. An example of the dithiophosphate derivative is 3-(di-isobutoxy-thiophosphorylsulfanyl)-2-methyl-propanoic acid. An example of the amine is ditridecyl amine. The composition can be used for a variety of applications. For example, the composition can be used as an antiwear compound/additive in lubricants, metalworking fluids, hydraulic fluids, etc.

公开(公告)号：EP2688993B1

公开(公告)日：2018-10-31

申请号：EP12711107.8

申请日：2012-03-23

Applicant: BASF SE

Inventor： SCANLON, Eugene ,  DESANTIS, Kevin ,  BETTE, Virginie ,  PETZOLDT, Jochen

IPC: C10M145/14 ,  C08F20/18 ,  C10M149/04 ,  C10N20/04 ,  C10N30/02 ,  C10N30/08 ,  C10N70/00

CPC classification number: C10M145/14 ,  C08F220/14 ,  C08F220/18 ,  C08F2220/1833 ,  C10M149/04 ,  C10M2209/084 ,  C10N2220/021 ,  C10N2230/02 ,  C10N2230/08 ,  C10N2270/00

Abstract: A lubricant composition having improved non-Newtonian viscometrics includes at least 85 weight percent of a base oil and 1 to 15 weight percent of a lubricant additive. The additive itself includes 10 to 80 weight percent of a diluent oil and 30 to 80 weight percent of a random co-polymeric viscosity index improver. The viscosity index improver is the free-radical polymerization product of at least 5 to 15 weight percent methyl methacrylate and 5 to 95 weight percent of a C8-C10 alkyl (meth)acrylate. The additive is formed using a method that includes the step of providing the diluent oil, the methyl methacrylate, the C8-C10 alkyl (meth)acrylate, and a free-radical initiator. The method also includes the steps of flowing the diluent oil into a reactor, flowing the methyl methacrylate and the C8-C10 alkyl (meth)acrylate into the reactor independently from the free-radical initiator, and flowing the free-radical initiator into the reactor.

公开(公告)号：EP3164473A1

公开(公告)日：2017-05-10

申请号：EP15814190.3

申请日：2015-07-02

Applicant: BASF SE

Inventor： DESANTIS, Kevin ,  HOEY, Michael ,  JUNG, Alfred, K. ,  JONES, Stephen, R. ,  SCANLON, Eugene ,  RABBAT, Philippe

IPC: C10M129/68 ,  C10M169/04

CPC classification number: C10M141/08 ,  C10M135/10 ,  C10M2203/1006 ,  C10M2207/026 ,  C10M2215/02 ,  C10M2215/064 ,  C10M2215/221 ,  C10M2219/044 ,  C10M2223/045 ,  C10N2210/02 ,  C10N2230/36 ,  C10N2230/45 ,  C10N2230/52 ,  C10N2240/10

Abstract: This disclosure is directed to a lubricant composition having improved compatibility with fluoropolymer seals. The lubricant composition includes a base oil and a sulfonate ester. The disclosure is also directed to an additive package for a lubricant composition that provides improved compatibility with fluoropolymer seals. The additive package includes the sulfonate ester. The disclosure is also directed to a method of improving compatibility of a lubricant composition with a fluoropolymer seal disposed in an internal combustion engine. The sulfonate ester improves the compatibility with fluoropolymer seals of the resultant lubricant composition.

Abstract translation: 本公开涉及与氟聚合物密封件具有改善的相容性的润滑剂组合物。 润滑剂组合物包含基础油和磺酸酯。 本公开还涉及用于润滑剂组合物的添加剂包，其提供与氟聚合物密封件的改进的相容性。 添加剂包装包括磺酸酯。 本公开还涉及改善润滑剂组合物与设置在内燃机中的含氟聚合物密封件的相容性的方法。 磺酸酯改善了与所得润滑剂组合物的氟聚合物密封件的相容性。