PROCESS FOR PREPARATION OF BENZYLIC AMIDES
    3.
    发明申请

    公开(公告)号:WO2018137959A1

    公开(公告)日:2018-08-02

    申请号:PCT/EP2018/050937

    申请日:2018-01-16

    Applicant: BASF SE

    Abstract: The present invention relates to a process for preparing benzylic amides of formula (I) wherein the variables have the meaning as defined in the description, by reductive amidation of a nitrile of formula (II) wherein the variables have the meanings given for formula I, with an activated carbonyl compound of formula (III), and which nitrile is obtained by reaction of a compound of formula (IV) with a halogen compound of formula (V), wherein X is a halogen atom, preferably bromo, which halogen compound V in turn is obtained by Sandmeyer reaction of an aniline derivative of formula (VI) novel compounds of formula (I), and processes for preparing compounds of formula (XII) wherein the variables have the meaning as defined in the description by condensing compounds of formula I with compounds of formula (X) and subjecting the resulting α,β-unsaturated ketone of formula (XI) to a reaction with hydroxylamine to yield compounds of formula (XII.)

    PESTICIDAL COMPOUNDS
    9.
    发明申请

    公开(公告)号:WO2018108671A1

    公开(公告)日:2018-06-21

    申请号:PCT/EP2017/081700

    申请日:2017-12-06

    Applicant: BASF SE

    Abstract: The present invention relates to the compounds of formula (I), and the N-oxides, stereoisomers, tautomers and agriculturally or veterinarily acceptable salts thereof wherein the variables are defined according to the description. The compounds of formula (I), as well as the N-oxides, stereoisomers, tautomers and agriculturally or veterinarily acceptable salts thereof, are useful for combating or controlling invertebrate pests, in particular arthropod pests and nematodes. The invention also relates to a method for controlling invertebrate pests by using these compounds and to plant propagation material and to an agricultural and a veterinary composition comprising said compounds.

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