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公开(公告)号:AU2014249741A1
公开(公告)日:2015-09-17
申请号:AU2014249741
申请日:2014-03-04
Applicant: BASF SE
Inventor: YANG MICHAEL , KUMAR RAJESH
IPC: C07F9/6568
Abstract: A method of producing a phospholene oxide is disclosed. A dihalohydrocarbylphosphine, 2-methyl-l,3-butadiene, and a halogenated hydrocarbon solvent are combined to form an adduct via an addition reaction in a homogenous system wherein the ratio of the 2-methyl- 1,3 -butadiene to the dihalohydrocarbylphosphine is from 1.0 to 2.0 and wherein the solvent is present in an amount of greater than 200 mL per mole of dihalohydrocarbylphosphine. The adduct is combined with alcohol and a carbonate or with a solution of metal hydroxide and water to form the phospholene oxide.