公开(公告)号：WO2013072292A1

公开(公告)日：2013-05-23

申请号：PCT/EP2012/072445

申请日：2012-11-13

Applicant: BASF SE ,  FASEL, Roman ,  RUFFIEUX, Pascal ,  MÜLLEN, Klaus ,  BLANKENBURG, Stephan ,  CAI, Jinming ,  FENG, Xinliang ,  PIGNEDOLI, Carlo ,  PASSERONE, Daniele ,  EMPA MATERIALS SCIENCE AND TECHNOLOGY

Inventor： FASEL, Roman ,  RUFFIEUX, Pascal ,  MÜLLEN, Klaus ,  BLANKENBURG, Stephan ,  CAI, Jinming ,  FENG, Xinliang ,  PIGNEDOLI, Carlo ,  PASSERONE, Daniele

IPC: C01B31/04 ,  C08G61/10

CPC classification number: C01B32/184 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/00 ,  C01B32/182 ,  C01B2204/06 ,  C01B2204/065 ,  C08G61/10 ,  C08G2261/148 ,  C08G2261/312 ,  C08G2261/314 ,  Y10S977/734 ,  Y10S977/842 ,  Y10S977/896 ,  Y10S977/932 ,  Y10T428/298 ,  Y10T428/2982

Abstract: The present invention relates to a segmented graphene nanoribbon, comprising at least two different graphene segments covalently linked to each other, each graphene segment having a monodisperse segment width, wherein the segment width of at least one of said graphene segments is 4 nm or less and to a method for preparing it by polymerizing at least one polycyclic aromatic monomer compound and/or at least one oligo phenylene aromatic hydrocarbon monomer compound to form at least one polymer and by at least partially cyclodehydrogenating the one or more polymer.

Abstract translation: 本发明涉及一种分段石墨烯纳米棒，其包括彼此共价连接的至少两个不同的石墨烯段，每个石墨烯段具有单分散段宽度，其中至少一个所述石墨烯段的段宽度为4nm或更小， 涉及一种通过聚合至少一种多环芳族单体化合物和/或至少一种低聚亚苯基芳族烃单体化合物以形成至少一种聚合物并通过至少部分地将该一种或多种聚合物环化而制备该方法。

公开(公告)号：EP2780280A1

公开(公告)日：2014-09-24

申请号：EP12787698.5

申请日：2012-11-13

Applicant: BASF SE ,  EMPA Materials Science and Technology

Inventor： FASEL, Roman ,  RUFFIEUX, Pascal ,  MÜLLEN, Klaus ,  BLANKENBURG, Stephan ,  CAI, Jinming ,  FENG, Xinliang ,  PIGNEDOLI, Carlo ,  PASSERONE, Daniele

IPC: C01B31/04 ,  C08G61/10

CPC classification number: C01B32/184 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/00 ,  C01B32/182 ,  C01B2204/06 ,  C01B2204/065 ,  C08G61/10 ,  C08G2261/148 ,  C08G2261/312 ,  C08G2261/314 ,  Y10S977/734 ,  Y10S977/842 ,  Y10S977/896 ,  Y10S977/932 ,  Y10T428/298 ,  Y10T428/2982

Abstract: The present invention relates to a segmented graphene nanoribbon, comprising at least two different graphene segments covalently linked to each other, each graphene segment having a monodisperse segment width, wherein the segment width of at least one of said graphene segments is 4 nm or less and to a method for preparing it by polymerizing at least one polycyclic aromatic monomer compound and/or at least one oligo phenylene aromatic hydrocarbon monomer compound to form at least one polymer and by at least partially cyclodehydrogenating the one or more polymer.

公开(公告)号：EP2780280B1

公开(公告)日：2018-01-10

申请号：EP12787698.5

申请日：2012-11-13

Applicant: BASF SE ,  EMPA Materials Science and Technology

Inventor： FASEL, Roman ,  RUFFIEUX, Pascal ,  MÜLLEN, Klaus ,  BLANKENBURG, Stephan ,  CAI, Jinming ,  FENG, Xinliang ,  PIGNEDOLI, Carlo ,  PASSERONE, Daniele

IPC: C08G61/10 ,  C01B32/20 ,  B82Y30/00 ,  B82Y40/00

CPC classification number: C01B32/184 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/00 ,  C01B32/182 ,  C01B2204/06 ,  C01B2204/065 ,  C08G61/10 ,  C08G2261/148 ,  C08G2261/312 ,  C08G2261/314 ,  Y10S977/734 ,  Y10S977/842 ,  Y10S977/896 ,  Y10S977/932 ,  Y10T428/298 ,  Y10T428/2982

Abstract: The present invention relates to a segmented graphene nanoribbon, comprising at least two different graphene segments covalently linked to each other, each graphene segment having a monodisperse segment width, wherein the segment width of at least one of said graphene segments is 4 nm or less and to a method for preparing it by polymerizing at least one polycyclic aromatic monomer compound and/or at least one oligo phenylene aromatic hydrocarbon monomer compound to form at least one polymer and by at least partially cyclodehydrogenating the one or more polymer.

公开(公告)号：WO2013175342A1

公开(公告)日：2013-11-28

申请号：PCT/IB2013/053886

申请日：2013-05-13

Applicant: BASF SE ,  EMPA ,  MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V. ,  BASF SCHWEIZ AG ,  BASF (CHINA) COMPANY LIMITED

Inventor： FASEL, Roman ,  RUFFIEUX, Pascal ,  MÜLLEN, Klaus ,  CAI, Jinming ,  FENG, Xinliang ,  BERGER, Reinhard

IPC: B82B3/00

CPC classification number: C07D403/10 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/182 ,  C01B32/184 ,  C01B2204/06 ,  C01B2204/065 ,  C07D209/56 ,  C07D215/18 ,  C07D237/26 ,  C07D239/72

Abstract: The present invention relates to a graphene nanoribbon, comprising a repeating unit which comprises at least one modification,wherein the modification is selected from a heteroatomic substitution, a vacancy, a sp 3 hybridization, a Stone-Wales defect, an inverse Stone-Wales defect, a hexagonal sp 2 hybridized carbon network ring size modification, and any combination thereof.

Abstract translation: 本发明涉及石墨烯纳米棒，其包含重复单元，其包含至少一个修饰，其中所述修饰选自杂原子取代，空位，sp3杂交，石 - 威尔斯缺陷，反石 - 威尔斯缺陷， 六角形sp2杂化碳网络环尺寸修改，以及它们的任何组合。

公开(公告)号：WO2015121785A1

公开(公告)日：2015-08-20

申请号：PCT/IB2015/050951

申请日：2015-02-09

Applicant: BASF SE ,  EMPA- EIDGENÖSSISCHE MATERIALPRÜFUNGS- UND FORSCHUNGSANSTALT ,  MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V. ,  BASF (CHINA) COMPANY LIMITED

Inventor： SCHWAB, Matthias Georg ,  MÜLLEN, Klaus ,  FENG, Xinliang ,  YANG, Bo ,  DUMSLAFF, Tim ,  FASEL, Roman ,  RUFFIEUX, Pascal ,  LIU, Jia ,  CAI, Jinming ,  SANCHEZ-SANCHEZ, Carlos ,  LIU, Junzhi

IPC: C07C15/20 ,  C01B31/04 ,  C08G61/10 ,  B82Y40/00

CPC classification number: C08G61/10 ,  C01B32/184 ,  C01B2204/06 ,  C07C15/20 ,  C07C25/22 ,  C08G2261/312 ,  C08G2261/314 ,  C08G2261/72 ,  C08G2261/724

Abstract: Provided are graphene nanoribbons with controlled zig-zag edge and cove edge configuration and methods for preparing such graphene nanoribbons. The nanoribbons are selected from the following formulae.

Abstract translation: 提供了具有可控曲折边缘和凸缘边缘配置的石墨烯纳米带以及用于制备这种石墨烯纳米带的方法。 纳米带选自下列公式。

公开(公告)号：WO2015173215A1

公开(公告)日：2015-11-19

申请号：PCT/EP2015/060421

申请日：2015-05-12

Applicant: BASF SE ,  MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V.

Inventor： SCHWAB, Matthias Georg ,  MÜLLEN, Klaus ,  FENG, Xinliang ,  DUMSLAFF, Tim ,  RUFFIEUX, Pascal ,  FASEL, Roman

IPC: C07C25/18 ,  C01B31/04 ,  C08G61/10 ,  H01L51/00

CPC classification number: C01B31/0446 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/184 ,  C01B2204/06 ,  C01B2204/22 ,  C07C25/18 ,  C08G61/10 ,  C08G2261/148 ,  C08G2261/51 ,  C08G2261/72 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  H01L29/1606 ,  H01L51/0045 ,  H01L51/0508 ,  H01L51/42 ,  H01L51/50 ,  Y10S977/734 ,  Y10S977/842 ,  Y10S977/932

Abstract: The present invention concerns ortho-Terphenyls of general formula (I); wherein R 1 , R 2 , R 3 and R 4 are independently selected from the group consisting of H; CN; NO 2 ; and saturated, unsaturated or aromatic C 1 -C 40 hydrocarbon residues, which can be substituted 1 - to 5- fold with F, CI, OH, NH 2 , CN and/or NO 2 , and wherein one or more -CH 2 -groups can be replaced by -O-, -NH-, -S-, -C(=O)O-, -OC(=O)- and/or -C(=O)-; and X and Y are the same or different, and selected from the group consisting of F, CI, Br, I, and OTf (trifluoromethanesulfonate); and their use for the preparation of graphene nanoribbons as well as a process for the preparation of graphene nanoribbons from said ortho-Terphenyls.

Abstract translation: 本发明涉及通式（I）的邻 - 三联苯; 其中R1，R2，R3和R4独立地选自H; CN; NO2; 和饱和的，不饱和的或芳族的C 1 -C 40烃残基，其可被F，Cl，OH，NH 2，CN和/或NO 2取代1至5倍，并且其中一个或多个-CH 2 - 基团可被 -O - ， - NH - ， - S - ， - C（= O）O-，-OC（= O） - 和/或-C（= O） - ; X和Y相同或不同，选自F，Cl，Br，I和OTf（三氟甲磺酸酯）; 以及它们用于制备石墨烯纳米带的用途以及从所述邻三联苯制备石墨烯纳米带的方法。

公开(公告)号：WO2014076634A1

公开(公告)日：2014-05-22

申请号：PCT/IB2013/060075

申请日：2013-11-12

Applicant: BASF SE ,  MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V. ,  BASF (CHINA) COMPANY LIMITED

Inventor： MÜLLEN, Klaus ,  FENG, Xinliang ,  CAI, Jinming ,  RUFFIEUX, Pascal ,  FASEL, Roman ,  NARITA, Akimitsu

IPC: C07C15/14 ,  C07C15/12 ,  C07C15/20 ,  C07C15/30 ,  C07C25/18 ,  C07C309/66 ,  C07C245/20 ,  C01B31/04 ,  C08G61/10

CPC classification number: C08G61/121 ,  B82Y40/00 ,  C01B32/182 ,  C01B32/184 ,  C01B2204/06 ,  C01B2204/22 ,  C07C25/18 ,  C08G61/10 ,  C08G2261/148 ,  C08G2261/312 ,  C08G2261/314 ,  C08G2261/414 ,  C08G2261/72 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  H01L51/102 ,  H01L51/441 ,  H01L51/5206 ,  H01L51/5221

Abstract: The invention relates to oligophenylene monomers of general formula I, wherein R 1 is H, halogene, -OH, -NH 2 , -CN,-NO 2 , or a linear or branched, saturated or un-saturated C 1 -C 40 hydrocarbon residue, which can be substituted 1-to 5-fold with halogene (F, Cl, Br, I), -OH, -NH 2 , -CN and/or -NO 2 , and wherein one or more CH 2 -groups can be replaced by -O-, -S-, -C(O)O-, -O-C(O)-, -C(O)-, -NH-or – NR 3 -, wherein R 3 is an optionally substituted C 1 -C 40 hydrocarbon residue, or an optionally substituted aryl, alkylaryl, alkoxyaryl, alkanoyl or aroyl residue; R 2a and R 2b are H, or optionally one or more of the pairs of adjacent R 2a /R 2b is joined to form a single bond in a six-membered carbocycle; m is an integer of from 0 to 3; n is 0 or 1; and X is halogene or trifluoromethylsulfonate, and Y is H; or X is H, and Y is halogene or trifluoromethylsulfonate. The invention further relates to polymeric precursors as well as methods for preparing graphene nanoribbons from the oligophenylene monomers and the polymeric precur- sors.

Abstract translation: 本发明涉及通式I的低聚苯乙烯单体，其中R 1是H，卤素，-OH，-NH 2，-CN，-NO 2或直链或支链，饱和或不饱和的C 1 -C 40烃残基，其可以是 用卤素（F，Cl，Br，I），-OH，-NH 2，-CN和/或-NO 2取代1至5倍，并且其中一个或多个CH 2 - 可以被-O - ， - S，-C（O）O-，-OC（O） - ， - C（O） - ， - NH-或-NR 3 - ，其中R 3是任选取代的C 1 -C 40烃残基或任选取代的芳基 ，烷基芳基，烷氧基芳基，烷酰基或芳酰基残基; R2a和R2b是H或任选的一对或多个相邻的R 2a / R 2b结合形成六元碳环中的单键; m为0〜3的整数; n为0或1; X为卤素或三氟甲基磺酸盐，Y为H; 或X为H，Y为卤素或三氟甲磺酸酯。 本发明还涉及聚合物前体以及从低聚苯乙烯单体和聚合物前体制备石墨烯纳米带的方法。

公开(公告)号：WO2014045148A1

公开(公告)日：2014-03-27

申请号：PCT/IB2013/058275

申请日：2013-09-04

Applicant: BASF SE ,  EMPA EIDGENÖSSISCHE MATERIALPRÜFUNGS- UND FORSCHUNGSANSTALT ,  BASF (CHINA) COMPANY LIMITED

Inventor： HINTERMANN, Tobias ,  DR. FASEL, Roman ,  RUFFIEUX, Pascal ,  JINMING, Cai ,  SANCHEZ VALENCIA, Juan Ramon

IPC: C01B31/04 ,  B82Y40/00

CPC classification number: C01B31/0446 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/184 ,  C01B2204/06

Abstract: The present invention relates to a process for preparing a graphene nanoribbon, which comprises: (a) providing at least one aromatic monomer compound which is selected from at least one polycyclic aromatic monomer compound, at least one oligo phenylene aromatic monomer compound, or combinations thereof, on a solid substrate, (b) polymerization of the aromatic monomer compound so as to form at least one polymer on the surface of the solid substrate, (c) at least partially cyclodehydrogenating the one or more polymers of step (b), wherein at least step (b) is carried out at a total pressure p(total) of at least 1 x 10 -9 mbar; and a partial oxygen pressure p(O 2 ) and partial water pressure p(H 2 O) which satisfy the following relation: p(O 2 ) x p(H20) -14 mbar 2 .

Abstract translation: 本发明涉及一种制备石墨烯纳米棒的方法，其包括：（a）提供至少一种选自至少一种多环芳族单体化合物，至少一种低聚亚苯基芳族单体化合物或其组合的芳族单体化合物 （b）芳族单体化合物的聚合以在固体基质的表面上形成至少一种聚合物，（c）至少部分地使步骤（b）的一种或多种聚合物环化脱氢，其中 至少步骤（b）以至少1×10 -9毫巴的总压力p（总计）进行; 和满足以下关系的部分氧气压力p（O2）和部分水压p（H 2 O）：p（O 2）x p（H 2 O）<3×10 -4 mbar 2。

公开(公告)号：EP3142994A1

公开(公告)日：2017-03-22

申请号：EP15720351.4

申请日：2015-05-12

Applicant: BASF SE ,  Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V.

Inventor： SCHWAB, Matthias Georg ,  MÜLLEN, Klaus ,  FENG, Xinliang ,  DUMSLAFF, Tim ,  RUFFIEUX, Pascal ,  FASEL, Roman

IPC: C07C25/18 ,  C08G61/10 ,  H01L51/00

CPC classification number: C01B31/0446 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/184 ,  C01B2204/06 ,  C01B2204/22 ,  C07C25/18 ,  C08G61/10 ,  C08G2261/148 ,  C08G2261/51 ,  C08G2261/72 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  H01L29/1606 ,  H01L51/0045 ,  H01L51/0508 ,  H01L51/42 ,  H01L51/50 ,  Y10S977/734 ,  Y10S977/842 ,  Y10S977/932

Abstract: The present invention concerns ortho-Terphenyls of general formula (I); wherein R
1 , R
2 , R
3 and R
4 are independently selected from the group consisting of H; CN; NO
2 ; and saturated, unsaturated or aromatic C
1 -C
40 hydrocarbon residues, which can be substituted 1 - to 5- fold with F, CI, OH, NH
2 , CN and/or NO
2 , and wherein one or more -CH
2 -groups can be replaced by -O-, -NH-, -S-, -C(=O)O-, -OC(=O)- and/or -C(=O)-; and X and Y are the same or different, and selected from the group consisting of F, CI, Br, I, and OTf (trifluoromethanesulfonate); and their use for the preparation of graphene nanoribbons as well as a process for the preparation of graphene nanoribbons from said ortho-Terphenyls.

Abstract translation: 本发明涉及通式（I）的邻三联苯; 其中R1，R2，R3和R4独立地选自H; CN; NO2; 和饱和的，不饱和的或芳族的C 1 -C 40烃残基，其可以被F，Cl，OH，NH 2，CN和/或NO 2取代1至5倍，并且其中一个或多个-CH 2 - 基团可被 -O - ， - NH - ， - S - ， - C（= O）O-，-OC（= O） - 和/或-C（= O） - ; X和Y相同或不同，选自F，Cl，Br，I和OTf（三氟甲磺酸酯）; 以及它们用于制备石墨烯纳米带的用途以及从所述邻三联苯制备石墨烯纳米带的方法。

公开(公告)号：EP2897901A1

公开(公告)日：2015-07-29

申请号：EP13839100.8

申请日：2013-09-04

Applicant: BASF SE ,  EMPA Eidgenössische Materialprüfungs- und Forschungsanstalt

Inventor： HINTERMANN, Tobias ,  FASEL, Roman ,  RUFFIEUX, Pascal ,  CAI, Jinming ,  SANCHEZ VALENCIA, Juan Ramon

IPC: C01B31/04 ,  B82Y40/00

CPC classification number: C01B31/0446 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/184 ,  C01B2204/06

Abstract: The present invention relates to a process for preparing a graphene nanoribbon, which comprises: (a) providing at least one aromatic monomer compound which is selected from at least one polycyclic aromatic monomer compound, at least one oligo phenylene aromatic monomer compound, or combinations thereof, on a solid substrate, (b) polymerization of the aromatic monomer compound so as to form at least one polymer on the surface of the solid substrate, (c) at least partially cyclodehydrogenating the one or more polymers of step (b), wherein at least step (b) is carried out at a total pressure p(total) of at least 1 x 10
-9 mbar; and a partial oxygen pressure p(O
2 ) and partial water pressure p(H
2 O) which satisfy the following relation: p(O
2 ) x p(H20) -14 mbar
2 .