-
公开(公告)号:ZA201509117B
公开(公告)日:2020-05-27
申请号:ZA201509117
申请日:2015-12-14
Applicant: BASF SE A GERMAN COMPANY
Inventor: KIRSTEN SPANNHOFF , ANDREI-NICOLAE PARVULESCU , ARMIN LANGE DE OLIVEIRA , STEFAN MARX , MATHIAS FEYEN , ULRICH MÜLLER , EKKEHARD SCHWAB
Abstract: The present invention relates to a gas-phase process for the preparation of butadiene comprising (i) providing a gas stream G-1 comprising ethanol; (ii) contacting the gas stream G-1 comprising ethanol with a catalyst, thereby obtaining a gas stream G-2 comprising butadiene, wherein the catalyst comprises a zeolitic material having a framework structure comprising YO2, Y standing for one or more tetravalent elements, wherein at least a portion of Y comprised in the framework structure is isomorphously substituted by one or more elements X, as well as to a zeolitic material having a framework structure comprising YO2, Y standing for one or more tetravalent elements, wherein at least a portion of Y comprised in the framework structure is isomorphously substituted by one or more elements X, wherein the zeolitic material displays a specific X-ray powder diffraction pattern, and to its use.
-
2.
公开(公告)号:ZA201705589B
公开(公告)日:2020-11-25
申请号:ZA201705589
申请日:2017-08-17
Applicant: BASF SE A GERMAN COMPANY
Inventor: MATHIAS FEYEN , STEFAN MAURER , ULRICH MUELLER , XINHE BAO , WEIPING ZHANG , DIRK DE VOS , HERMANN GIES , FENG-SHOU XIAO , YOKOI TOSHIYUKI , BILGE YILMAZ , RYOICHI OTOMO
Abstract: The present invention relates to a method for the preparation of a treated zeolitic material having a BEA framework structure comprising the steps of: (i) providing a zeolitic material having a BEA framework structure, wherein the BEA framework structure comprises YO2 and X2O3, wherein Y is a tetravalent element, and X is a trivalent element, and wherein the zeolitic material having a BEA framework structure is obtainable and/or obtained from an organotemplate-free synthetic process; (ii) calcining the zeolitic material provided in step (i) at a temperature of 650° C. or more; and (iii) treating the calcined zeolitic material obtained from step (ii) with an aqueous solution having a pH of 5 or less, as well as to zeolitic materials per se preferably obtainable according to the inventive method and to their use, and to a process for converting oxygenates to olefins employing the inventive zeolitic materials.
-
公开(公告)号:ZA201608280B
公开(公告)日:2020-05-27
申请号:ZA201608280
申请日:2016-11-30
Applicant: BASF SE A GERMAN COMPANY
Inventor: MATHIAS FEYEN , JEFF YANG , ROGER RUETZ , ULRICH MÜLLER
-
公开(公告)号:ZA201603841B
公开(公告)日:2019-09-25
申请号:ZA201603841
申请日:2016-06-06
Applicant: BASF SE A GERMAN COMPANY
Inventor: KIRSTEN BRAUNSMANN , BERND BASTIAN SCHAACK , EKKEHARD SCHWAB , MANUELA GAAB , MATHIAS FEYEN
Abstract: The present invention relates to a catalyst for the conversion of oxygenates to olefins, wherein the catalyst comprises one or more zeolites of the MFI, MEL and/or MWW structure type and particles of one or more metal oxides, the one or more zeolites of the MFI, MEL and/or MWW structure type comprising one or more alkaline earth metals selected from the group consisting of Mg, Ca, Sr, Ba and combinations of two or more thereof, wherein the catalyst displays a water uptake of 9.0 wt.-% or less, as well as to a process for the production thereof and to its use, in particular in a process for converting oxygenates to olefins.
-
公开(公告)号:ZA201604699B
公开(公告)日:2020-10-28
申请号:ZA201604699
申请日:2016-07-08
Applicant: BASF SE A GERMAN COMPANY , TOKYO INST TECH
Inventor: MATHIAS FEYEN , STEFAN MAURER , ULRICH MÜLLER , XINHE BAO , WEIPING ZHANG , DIRK DE VOS , HERMANN GIES , FENG-SHOU XIAO , TOSHIYUKI YOKOI , BILGE YILMAZ
Abstract: The present invention relates to a process for the production of a zeolitic material having a BEA-type framework structure comprising YO2 and X2O3, wherein said process comprises the steps of (1) preparing a mixture comprising one or more sources for YO2 and one or more sources for X2O3; (2) crystallizing the mixture obtained in step (1); (3) subjecting the zeolitic material having a BEA-type framework structure obtained in step (2) to an ion-exchange procedure with Cu; and (4) subjecting the Cu ion-exchanged zeolitic material obtained in step (3) to an ion-exchange procedure with Fe; wherein Y is a tetravalent element, and X is a trivalent element, wherein the mixture provided in step (1) and crystallized in step (2) further comprises seed crystals comprising one or more zeolitic materials having a BEA-type framework structure, and wherein the mixture provided in step (1) and crystallized in step (2) does not contain an organotemplate as a structure-directing agent, as well as to the zeolitic material having a BEA framework structure per se, and to its use, in particular in a method for the treatment of NOx by selective catalytic reduction (SCR).
-
-
-
-