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公开(公告)号:CA2869988A1
公开(公告)日:2014-01-16
申请号:CA2869988
申请日:2013-04-11
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor: SAYRE JAY R , MCGINNISS VINCE , TOLBERT BYRON C , JENKINS KELLY J , ELLIS JEFFREY L , HUTSON TIM B , ANGEL SUNDEE , THURSTON RACHEL
IPC: D06M13/513
Abstract: A method of treating fibers to improve resistance to high temperatures and relative humidity includes providing poly(p-phenylene~2,6-benzobisoxazole) (PBO) fibers, exposing the PBO fibers to an atmosphere of supercritical CO2 saturated with an epoxy silane, i.e. 3-glycidoxypropyl methyldimethoxysilane. The PBO fibers are subjected to a first pressurizing and heating stage at a first temperature (50°C) for a first period of time. The PBO fibers are then subjected to a second pressurizing and heating stage including increasing the temperature to a second temperature (110°C) and holding at the second temperature for an additional period of time. The PBO fibers include 2-5 wt% of 3-glycidoxypropyl methyldimethoxysilane after diffusing the CO2 out of the PBO fibers. The fibers are particularly useful in making lightweight body armor system components.
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公开(公告)号:DE60332003D1
公开(公告)日:2010-05-20
申请号:DE60332003
申请日:2003-02-06
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor: VIJAYENDRAN BHIMA , MCGINNISS VINCENT D , RISSER STEVEN M , SCHULTE MICHAEL D , SAYRE JAY R , CAFMEYER JEFFREY T
IPC: C08J5/22 , H01M8/02 , B01D69/14 , B01D71/46 , B01D71/52 , B01D71/68 , B01D71/82 , H01B1/06 , H01B13/00 , H01M8/10
Abstract: This invention relates to a polymer electrolyte membrane comprising a proton conducting hydrocarbon-based polymer membrane, the polymer having a backbone and having acidic groups on side chains attached to the backbone. The invention also relates to a polymer electrolyte membrane comprising a proton conducting hydrocarbon-based polymer membrane having a phase separated morphological microstructure. The invention also relates to a polymer electrolyte membrane comprising a proton conducting membrane, the membrane comprising a basic material in combination with an acidic material selected from acidic hydrocarbon-based polymers, acidic hydrocarbon-based oligomers, and blends thereof.
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公开(公告)号:CA2878756A1
公开(公告)日:2007-04-12
申请号:CA2878756
申请日:2006-09-29
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor: LALGUDI RAMANATHAN S , VIJAYENDRAN BHIMA R , CAFMEYER JEFFREY , SAYRE JAY R
Abstract: A proton conducting hydrocarbon-based polymer has acid groups on side chains attached to the main chain, where the acid groups are between 7 and 12 atoms away from the main chain. Another polymer includes a semi-fluorinated aromatic hydrocarbon main chain and side chains that include at least one -CF2- group and an acid group. Another polymer includes an aromatic hydrocarbon main chain and side chains that include at least one -CH2-CF2- group and an acid group. Another aromatic polymer includes acid groups attached to both the main chain and the side chains where less than about 65 wt% of the acid groups are attached to the side chains. Another aromatic polymer includes side chains attached to the main chain that include at least one aryl ring, and acid groups attached to both the main chain and to the aryl groups. Another polymer includes an aliphatic hydrocarbon main chain, side chains that include at least one deactivating aryl ring, and acid groups attached to the deactivating aryl rings. Another aliphatic polymer has side chains that include -CF2- groups and an acid group. A fuel cell component includes a proton conducting polymer, a water insoluble inorganic material, and a heteropolyacid immobilized on the inorganic material.
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公开(公告)号:CA2624459A1
公开(公告)日:2007-04-12
申请号:CA2624459
申请日:2006-09-29
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor: VIJAYENDRAN BHIMA R , LALGUDI RAMANATHAN S , SAYRE JAY R
Abstract: A fuel cell component is made with a composite including a proton conducting polymer, a water insoluble proton conducting inorganic material, and a heteropolyacid immobilized by chemically bonding to the inorganic material. In another embodiment, the fuel cell component is made with a composite including a non- proton conducting polymer, a water insoluble inorganic material, and a heteropolyacid immobilized by chemically bonding to the inorganic material, the heteropolyacid causing the composite to show proton conductivity. In a further embodiment, the fuel cell component is made with a composite comprising a proton conducting polymer, a water insoluble proton conducting inorganic material, and a heteropolyacid immobilized by chemically bonding to the inorganic material, the composite having substantially identical structure of the unmodified heteropolyacid.
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公开(公告)号:CA2619952A1
公开(公告)日:2007-03-08
申请号:CA2619952
申请日:2006-08-31
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor: GEORGE PAUL E II , MONZYK BRUCE F , PESTAK CHRISTOPHER J , SAYRE JAY R
IPC: H01M8/06 , B01J35/00 , B64G1/00 , C01B13/00 , C01B15/00 , C25B1/00 , H01M8/18 , H01M14/00 , H01M16/00
Abstract: A system for oxygen, hydrogen and carbon mass regeneration and recycling for breathing, and fuel/energy generation purposes, especially for fuel cells an d rocket motors, by combination and integration of a photoelectrolytically powered electrochemical and gas handling system with one or more fuel cells.
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公开(公告)号:CA2587729C
公开(公告)日:2014-06-10
申请号:CA2587729
申请日:2005-11-16
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor: SAYRE JAY R , SESSLAR MEGAN E , WHITE JAMES L , STICKEL JOHN R , STASIK MARK C , VIJAYENDRAN BHIMA R
Abstract: This invention relates in general to components of electrochemical devices, and to methods of preparing the components. The components and methods include the use of a composition comprising an ionically conductive polymer and at least one solvent, where the polymer and the solvent are selected based on the thermodynamics of the combination. In one embodiment, the invention relates to a component for an electrochemical device which is prepared from a composition comprising a true solution of an ionically conductive polymer and at least one solvent, the polymer and the at least one solvent being selected such that (.delta. solvent- .delta. solute)
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公开(公告)号:CA2704515A1
公开(公告)日:2009-03-12
申请号:CA2704515
申请日:2008-08-28
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor: SAYRE JAY R , LALGUDI RAMANATHAN S , VIJAYENDRAN BHIMA R
Abstract: An ionically conductive polymer is a copolymer including first and second polymer segments. The first polymer segments have a hydrophobic character and a high oxygen permeability. The second polymer segments have a hydrophilic character and a low oxygen permeability. The copolymer has an ionic conductivity of at least about 1 x 10-5 S/cm at any point within a temperature range of from 30°C to 15O°C and a relative humidity range of from 20% to 100%. The ionically conductive polymer can be used in an electrochemical device such as a fuel cell, for example, used as a binder in an electrode or used to produce a membrane.
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公开(公告)号:AU2005307820A1
公开(公告)日:2006-05-26
申请号:AU2005307820
申请日:2005-11-17
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor: PLAXICO CHUCK A , VALENTINE KARY L , SAYRE JAY R , MIELE CHARLES R , VERSLUIS W SCOTT , SERMAN CARL J , PRESTON JOSEPH R , KENNEDY JAMES C JR
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公开(公告)号:AU2003209080A1
公开(公告)日:2003-09-02
申请号:AU2003209080
申请日:2003-02-06
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor: SCHULTE MICHAEL D , SAYRE JAY R , CAFMEYER JEFFREY T , VIJAYENDRAN BHIMA , MCGINNISS VINCENT D , RISSER STEVEN M
IPC: C08J5/22 , B01D69/14 , B01D71/46 , B01D71/52 , B01D71/68 , B01D71/82 , H01B1/06 , H01B13/00 , H01M8/02 , H01M8/10
Abstract: This invention relates to a polymer electrolyte membrane comprising a proton conducting hydrocarbon-based polymer membrane, the polymer having a backbone and having acidic groups on side chains attached to the backbone. The invention also relates to a polymer electrolyte membrane comprising a proton conducting hydrocarbon-based polymer membrane having a phase separated morphological microstructure. The invention also relates to a polymer electrolyte membrane comprising a proton conducting membrane, the membrane comprising a basic material in combination with an acidic material selected from acidic hydrocarbon-based polymers, acidic hydrocarbon-based oligomers, and blends thereof.
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公开(公告)号:IL241645A
公开(公告)日:2018-12-31
申请号:IL24164515
申请日:2015-09-16
Applicant: BATTELLE MEMORIAL INSTITUTE , SAYRE JAY R , VALENTINE KARY L , POLLOCK CLARENCE E
Inventor: SAYRE JAY R , VALENTINE KARY L , POLLOCK CLARENCE E
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