PROCESS FOR PREPARING METAL COMPLEXES OF 1-PHENYL-2-TRIAZOLYL ETHYL DERIVATIVES

    公开(公告)号:KR840000701B1

    公开(公告)日:1984-05-21

    申请号:KR780001453

    申请日:1978-05-13

    Applicant: BAYER AG

    Abstract: The title compds. I (R=halo, alkyl, alkoxy, alkylthio, alkylsulfonyl, halogenoalkyl, nitro, cyano, Ph, phenoxy; R1= OR2, -OCOR4; R2=alkyl, alkenyl, alkynyl, cycloalkyl, aryl, arylalkyl, arylalkenyl; R4=alkyl, alkenyl, cycloalkyl, etc.; A=anion of inorg. acid or its hydrate; M=metal; n=0-5; p=1-6; X=1-4) were prepd. Thus, 2,4-C12C6H3COCH2Br was treated with 1,2,4-triazole, the oxo group reduced the alco and treated with CH2:CHCH2Br to give 1-(2,4-dichlorophenyl)-2-(,2,4-triazol-1-yl)-ethylarylether, which was treated with CuCl2 to give I (M=Cu; R=2,4-C1; R4=OCH2CH:CH2; X=C1; n=p=2, III). At 0.0025% III gave 85% protection against Fusicladiun dentriticum attack on apple seedlings.

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