Abstract:
PURPOSE: To obtain a dental molding product highly cross-linked in short molding device and having high mechanical strength (e.g. hardness and abrasion resistance) and resistance to solvent, especially false tooth. CONSTITUTION: This dental cross-linked molding product having the above effects is obtained by molding a curable composition consisting essentially of (A) 40-90wt.% polymer component comprising 40-100wt.% uncross-linked polymer and 0-60wt.% cross-linked polymer and having 8-12.5(cal/cm ) , preferably 8.5-12(cal/cm ) solubility parameter, (B) 10-60wt.% polyfunctional (meth) acrylate and (C) 0.1-5wt.% optical activating agent into a molding product by a thermoplastic method and cross-linking the molding product by photopolymerization. The molding product includes e.g. false teeth, crowns, bridges, veneer shells, inlays (e.g. hole-embedding of dental caries) and onlays (facing), especially false teeth.
Abstract:
The present invention relates to polyisocyanate compositions containing reversibly blocked catalysts for the isocyanate addition reaction, characterized in that they contain (a) at least one organic polyisocyanate, (b) at least one addition product dissolved or dispersed in the polyisocyanate compositions, of a sulfonyl isocyanate with a tertiary amine and/or with a catalyst having a tin(II)- or tin(IV)-carboxylate structure as the reversibly blocked catalyst. The present invention also relates to a process for producing these polyisocyanate compositions and to the use of new polyisocyanate compositions as reactants for compounds containing isocyanate-reactive groups for the production of isocyanate addition products such as polyurethane plastics using a one-component or two-component principle. The present invention finally relates to the latent polyurethane catalysts prepared from a sulfonyl isocyanate and a tin(II)- or tin(IV)-carboxylate.
Abstract:
A process for preparing a mixture of polyhydroxyl compounds having low molecular weight by catalytically hydrogenating a formose mixture with hydrogen on a metal catalyst. The hydrogenation is carried out at a pH of 7.5 to 12.5 and at elevated temperature and pressure. The formose mixture comprises (i) up to 70 wt. % formose, (ii) up to 1.6 wt. % lead ions and (iii) up to 5 wt. % calcium ions with at least one of (ii) or (iii) being present. The catalyst which is present in an amount of 4-240 wt. % (based on formose solution) is a compound taken from the group consisting of nickel, cobalt and compounds thereof. The mixture of polyhydroxyl compounds made in accordance with the present invention is useful as a starting material in the production of polyether polyols, polyester polyols and polyurethane plastics.
Abstract:
PURPOSE: To prevent foaming of a fixing bandage by using a polyisocyanate agent contained in a flexible support material, which comprises a polyisocyanate, a catalyst, adjuvant and an additive. CONSTITUTION: A fixed bandage contains a polyisocyanate in a flexible support material. The polyisocyanate agent comprises an organic polyisocyanate, a catalyst, an adjuvant and an additive. The adjuvant and additive are octamethylcyclotetrasiloxane compounds expressed by formula (I). In the formula (I), R indicates methyl, ethyl, or propyl, and 1