PROCESS FOR THE PREPARATION OF BORONCONTAINING PHENOL/FORMALDEHYDE RESINS

    公开(公告)号:ZA79518B

    公开(公告)日:1980-03-26

    申请号:ZA79518

    申请日:1979-02-07

    Applicant: BAYER AG

    Abstract: The invention relates to a process for the preparation of boron-containing phenol/formaldehyde resins be reacting diphenylol alkane novolaks with unsaturated fatty acids or fatty acid esters and boron compounds, characterized in that diphenylol alkane novolaks having a molecular weight of from 400 to 1600 are reacted with from 15 to 35 parts by weight of an unsaturated fatty acid or its esters, accompanied by the azeotropic removal of water, and then with from 20 to 100 parts by weight of a boric acid trialkyl ester containing from 1 to 4 carbon atoms per alkyl group or with 14 to 72 parts by weight of a boric acid alkyl ester anhydride of the general formula (RO)2 B-O-B-(OR)2 with 1 to 4 carbon atoms per alkyl group R or with from 10 to 50 parts by weight, preferably from 15 to 20 parts by weight of boron trioxide or with from 18 to 90 parts by weight, preferably from 25 to 36 parts by weight of boric acid in the presence of a C1-C4 alcohol.

    PROCESS FOR THE PREPARATION OF BORONCONTAINING PHENOL/FORMALDEHYDE RESINS

    公开(公告)号:IN150525B

    公开(公告)日:1982-11-06

    申请号:IN18DE1979

    申请日:1979-01-11

    Applicant: BAYER AG

    Abstract: The invention relates to a process for the preparation of boron-containing phenol/formaldehyde resins be reacting diphenylol alkane novolaks with unsaturated fatty acids or fatty acid esters and boron compounds, characterized in that diphenylol alkane novolaks having a molecular weight of from 400 to 1600 are reacted with from 15 to 35 parts by weight of an unsaturated fatty acid or its esters, accompanied by the azeotropic removal of water, and then with from 20 to 100 parts by weight of a boric acid trialkyl ester containing from 1 to 4 carbon atoms per alkyl group or with 14 to 72 parts by weight of a boric acid alkyl ester anhydride of the general formula (RO)2 B-O-B-(OR)2 with 1 to 4 carbon atoms per alkyl group R or with from 10 to 50 parts by weight, preferably from 15 to 20 parts by weight of boron trioxide or with from 18 to 90 parts by weight, preferably from 25 to 36 parts by weight of boric acid in the presence of a C1-C4 alcohol.

    5.
    发明专利
    未知

    公开(公告)号:BR7900742A

    公开(公告)日:1979-08-28

    申请号:BR7900742

    申请日:1979-02-07

    Applicant: BAYER AG

    Abstract: The invention relates to a process for the preparation of boron-containing phenol/formaldehyde resins be reacting diphenylol alkane novolaks with unsaturated fatty acids or fatty acid esters and boron compounds, characterized in that diphenylol alkane novolaks having a molecular weight of from 400 to 1600 are reacted with from 15 to 35 parts by weight of an unsaturated fatty acid or its esters, accompanied by the azeotropic removal of water, and then with from 20 to 100 parts by weight of a boric acid trialkyl ester containing from 1 to 4 carbon atoms per alkyl group or with 14 to 72 parts by weight of a boric acid alkyl ester anhydride of the general formula (RO)2 B-O-B-(OR)2 with 1 to 4 carbon atoms per alkyl group R or with from 10 to 50 parts by weight, preferably from 15 to 20 parts by weight of boron trioxide or with from 18 to 90 parts by weight, preferably from 25 to 36 parts by weight of boric acid in the presence of a C1-C4 alcohol.

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