8.
    发明专利
    未知

    公开(公告)号:SE359305B

    公开(公告)日:1973-08-27

    申请号:SE1059668

    申请日:1968-08-06

    Applicant: BAYER AG

    Inventor: ZECHER W MERTEN R

    Abstract: 1,239,422. Coated products. FARBENFABRIKEN BAYER A.G. 26 June, 1968 [7 Aug., 1967 (2)], No. 30433/68. Heading B2E. [Also in Division C3] Polyimides are produced by a process which comprises reacting (a) a Schiff's base Xz- R 1 -N=CR 2 .R 3 , or a trimer thereof, where R 1 is a z+1 valent aliphatic or aromatic radical; R 2 and R 3 are each H, alkyl, cycloalkyl, aralkyl or aryl or together complete a 5 to 7 membered carbo-or hetero-cyclic ring; X is -N=CR 2 .R 3 ; -OH, or -NH 2 ; and z is 1 or 2, at 0 to 450‹C with (b) an aliphatic or aromatic compound containing 1, 2 or 3 dicarboxylic acid cyclic anhydride groups, and where there is only 1 anhydride group at least one other group able to participate in the polycondensation reaction. Either or both of (a) and (b) may be formed in situ. Numerous suitable reactants are specified. Other polyfunctional reactants such as diamines, polyols, e.g. glycol, and polycarboxylic acids (including OH or COOH terminated polyethers or polyesters), or polyisocyanates may also be present. Reaction may be effected in various solvents in the presence of catalysts, fillers, pigments or polyesters giving products suitable for lacquers, films and mouldings. In Examples trimellitic or pyromellitic anhydride or trimellitic anhydride glycol ester is reacted with various Schiff's bases. In Exs. 5, 6 and 12 an OH-terminated terephthalic acid/glycol/ glycerol polyester is included in the reaction while in Ex. 8 such a polyester is mixed with the polymer lacquer before stoving. The lacquers are applied to wires or to glass or metal plates and stoved. They may be mixed with terephthalic acid polyesters.

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