SOLUBILIZED ANIONIC POLYMERIZATION INITIATORS AND PRODUCTS THEREFROM

    公开(公告)号:CA2124144A1

    公开(公告)日:1994-11-25

    申请号:CA2124144

    申请日:1994-05-24

    Abstract: The present invention is directed toward anionic polymerization initiators which are soluble in acyclic alkane solvents. The initiators include a solubilized lithio amine having the general formula (A)Li(SOL)y. SOL is a solubilizing component and A is an alkyl, dialkyl or cycloalkyl amine radical or a cyclic amine and y is from about 1 to 4. The cyclic amine has an alkylene, oxy- or amino-alkylene group having from about 3 to about 16 methylene groups. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.

    SOLUBILIZED ANIONIC POLYMERIZATION INITIATORS AND PRODUCTS THEREFROM

    公开(公告)号:CA2124144C

    公开(公告)日:2007-09-18

    申请号:CA2124144

    申请日:1994-05-24

    Abstract: The present invention is directed toward anionic polymerization initiators which are soluble in acyclic alkane solvents. The initiators include a solubilized lithio amine having the general formula (A)Li(SOL)y. SOL is a solubilizing componen t and A is an alkyl, dialkyl or cycloalkyl amine radical or a cyclic amine and y i s from about 1 to 4. The cyclic amine has an alkylene, oxy- or amino-alkylene group havin g from about 3 to about 16 methylene groups. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and a n organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer wtih a multifunctionality.

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