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    S,S-dialkyl-o-and s-alkenyl phosphites and phosphates
    1.
    发明授权
    S,S-dialkyl-o-and s-alkenyl phosphites and phosphates 失效
    S，S-二烷基-O-和s-烯基亚磷酸酯和磷酸酯

    公开(公告)号：US3885000A

    公开(公告)日：1975-05-20

    申请号：US37421873

    申请日：1973-06-27

    Applicant: CIBA GEIGY AG

    Inventor： BERIGER ERNST ,  MARTIN HENRY

    IPC: C07F9/165 ,  C07F9/201 ,  C07F9/16 ,  A01N9/36

    CPC classification number: C07F9/201 ,  C07F9/1651 ,  C07F9/1653

    Abstract: Phosphoric acid esters of the formula

    WHEREIN X denotes oxygen or sulphur, the integer n is the number 0 or 1, R'' and R'''' independently of each other represent an alkyl radical with 3 to 5 carbon atoms and wherein A. IF X is oxygen, R represents an alkoxyalkylene, alkylmercaptoalkylene or alkenyloxyalkylene radical with at most 7 carbon atoms, an alkenyl radical with 3 to 6 carbon atoms or an unsubstituted benzyl group or a benzyl group which is substituted by halogen, methyl and/or methoxy, or wherein B. IF X is sulphur, R represents an alkenyl radical with 3 to 6 carbon atoms or an unsubstituted benzyl group or a benzyl group substituted by halogen, methyl and/or methoxy; these compounds are useful for defoliating and promoting the ripening of crop plants especially cotton.

    Abstract translation: 式WHEREIN X表示氧或硫的磷酸酯，整数n为数0或1，R'和R“彼此独立地表示具有3至5个碳原子的烷基，其中A.Ix X为 氧，R表示烷氧基亚烷基，具有至多7个碳原子的烷基巯基亚烷基或烯氧基亚烷基，具有3至6个碳原子的烯基或未被取代的苄基或被卤素，甲基和/或甲氧基取代的苄基，或其中 B.FX是硫，R表示具有3至6个碳原子的烯基或未被取代的苄基或被卤素，甲基和/或甲氧基取代的苄基; 这些化合物可用于脱叶和促进作物特别是棉花的成熟。

    S,S-Dialkyl-O-alkylthioalkyl phosphites and phosphates
    2.
    发明授权
    S,S-Dialkyl-O-alkylthioalkyl phosphites and phosphates 失效
    S，S-二烷基-O-烷基硫代烷基亚磷酸酯和磷酸酯

    公开(公告)号：US3897521A

    公开(公告)日：1975-07-29

    申请号：US37421973

    申请日：1973-06-27

    Applicant: CIBA GEIGY AG

    Inventor： BERIGER ERNST ,  MARTIN HENRY

    IPC: C07F9/165 ,  C07F9/173 ,  C07F9/201 ,  C07F9/16 ,  A01N9/36

    CPC classification number: C07F9/201 ,  C07F9/1651 ,  C07F9/1653 ,  C07F9/173

    Abstract: Phosphoric acid esters of the formula

    wherein X denotes oxygen or sulphur, the integer n is the number 0 or 1, R'' and R'''' independently of each other represent an alkyl radical with 3 to 5 carbon atoms and wherein A. IF X is oxygen, R represents an alkoxyalkylene, alkylmercaptoalkylene or alkenyloxyalkylene radical with at most 7 carbon atoms, and alkenyl radical with 3 to 6 carbon atoms or an unsubstituted benzyl group or a benzyl group which is substituted by halogen, methyl and/or methoxy, or wherein B. IF X is sulphur, R represents an alkenyl radical with 3 to 6 carbon atoms or an unsubstituted benzyl group or a benzyl group substituted by halogen, methyl and/or methoxy; these compounds are useful for defoliating and promoting the ripening of crop plants especially cotton.

    Abstract translation: 式[O] n PARALLEL SR'RXP ANGLE S-R“的磷酸酯其中X表示氧或硫，整数n是数字0或1，R'和R”彼此独立地表示烷基 具有3至5个碳原子的基团，并且其中A。IF X是氧，R表示烷氧基亚烷基，具有至多7个碳原子的烷基巯基亚烷基或烯氧基亚烷基，以及具有3至6个碳原子的烯基或未取代的苄基或苄基 其被卤素，甲基和/或甲氧基取代，或其中B.IF X是硫，R表示具有3至6个碳原子的烯基或未被取代的苄基或被卤素，甲基和/或甲氧基取代的苄基 ; 这些化合物可用于脱叶和促进作物特别是棉花的成熟。

    S,s-bis-benzyl alkylphosphonates
    3.
    发明授权
    S,s-bis-benzyl alkylphosphonates 失效
    S，S-BIS-BENZYL ALKYLPHOSPHONATES

    公开(公告)号：US3867484A

    公开(公告)日：1975-02-18

    申请号：US2485570

    申请日：1970-04-01

    Applicant: CIBA GEIGY AG

    Inventor： BERIGER ERNST

    IPC: C07F9/40 ,  A01N9/36

    CPC classification number: C07F9/4087

    Abstract: S,S-bis-benzyl-alkylphosphonates and S,S-bis-benzylalkylthiophosphonates, each of them optionally unsubstituted or substituted in the aromatic nucleus of the benzyl group, are effective fungicidal agents, preferably for combatting plantpathogenic fungi. They may be used in fungicidal preparations.

    Abstract translation: S，S-双苄基 - 烷基膦酸酯和S，S-双苄基 - 烷基硫代膦酸酯，它们各自任选未取代或在苄基的芳香核中被取代，是有效的杀真菌剂，优选用于对抗植物致病真菌。 它们可用于杀真菌剂。

    Phosphonic acid dithiol esters
    4.
    发明授权
    Phosphonic acid dithiol esters 失效
    膦酸二硫醇酯

    公开(公告)号：US3894125A

    公开(公告)日：1975-07-08

    申请号：US39257473

    申请日：1973-08-29

    Applicant: CIBA GEIGY AG

    Inventor： BERIGER ERNST

    IPC: C07F9/40

    CPC classification number: C07F9/4087 ,  C07F9/4006

    Abstract: The present invention describes new phosphonic acid dithiol esters, a method for their preparation, compositions containing them and a method for regulating the abscission of fruits by applying these new esters or compositions containing them to fruit trees, olive, nut trees, berry bushes and grapes. The new phosphonic acid esters correspond to the formula

    WHEREIN R'' is hydrogen, chlorine, -CF3, -CN, methyl, ethyl, methoxy or ethoxy, R'''' is hydrogen, chlorine, methyl or methoxy.

    Abstract translation: 本发明描述了新的膦酸二硫醇酯，其制备方法，含有它们的组合物和通过将这些新的酯或组合物应用于果树，橄榄，坚果树，浆果灌木和葡萄来调节水果脱落的方法 。 新的膦酸酯对应于式WHEREIN R'是氢，氯，-CF 3，-CN，甲基，乙基，甲氧基或乙氧基，R“是氢，氯，甲基或甲氧基。

    5-HETEROCYCLIC SUBSTITUTED-1,3,4-OXA-, AND THIA-DIAZOLES AND PESTICIDAL COMPOSITIONS
    5.
    发明专利
    5-HETEROCYCLIC SUBSTITUTED-1,3,4-OXA-, AND THIA-DIAZOLES AND PESTICIDAL COMPOSITIONS 未知

    公开(公告)号：NZ232981A

    公开(公告)日：1991-02-26

    申请号：NZ23298190

    申请日：1990-03-19

    Applicant: CIBA GEIGY AG

    Inventor： ECKHARDT WOLFGANG ,  BERIGER ERNST

    IPC: C07D413/04 ,  A01N43/76 ,  A01N43/78 ,  A01N43/82 ,  A01N43/824 ,  C07D413/06 ,  C07D413/14 ,  C07D417/04 ,  C07D417/14

    Abstract: There are described 2-mercapto-5-thiazol(2-, 4- or 5-yl)-1,3,4-oxa- and -thiadiazoles and 2-mercapto-5-oxazol(2-, 4- or 5-yl)-1,3,4-oxa- and -thiadiazoles of the formula I in which X1 and X2 independently of one another represent oxygen or sulphur, R1 represents C1-C5-alkyl which is unsubstituted or substituted by halogen, C1-C3-alkoxy or cyano; C3-C7-alkenyl which is unsubstituted or substituted by halogen; C3-C7-alkynyl which is unsubstituted or substituted by halogen, R2 and R3 independently of one another represent hydrogen, C1-C5-alkyl, C3-C7-alkenyl which is unsubstituted or substituted by halogen; phenyl which is unsubstituted or substituted by identical or different substituents from the series comprising C1-C3-alkyl, C1-C3-alkoxy or halogen, the radical -NR4R5, where R4 and R5 independently of one another represent hydrogen, C1-C5-alkyl or C3-C7-alkenyl which is unsubstituted or substituted by halogen, or one of the two substituents R2 and R3 also represents an unsubstituted or substituted heterocycle pyridyl, thienyl, furyl or thiazolyl, and processes for the preparation of the compounds of the formula I and novel intermediates of the preparation process. The compounds of the formula I have nematicidal and fungicidal properties. There are described nematicides and fungicides which contain, as active substance, at least one active substance of the formula I, and furthermore methods for using the active substances and the agents in the control of nematodes and fungi.

    METHOD OF CONTROLLING INSECTS
    9.
    发明专利
    METHOD OF CONTROLLING INSECTS 未知

    公开(公告)号：CA1066615A

    公开(公告)日：1979-11-20

    申请号：CA269507

    申请日：1977-01-12

    Applicant: CIBA GEIGY AG

    Inventor： BERIGER ERNST

    IPC: A01N43/32 ,  C07D319/06 ,  C07D319/08 ,  A01N9/20 ,  A01N9/24

    Abstract: METHOD OF CONTROLLING INSECTS of the Dislosure The invention provides a method for controlling insect pests at a locus which comprises applying to said locus a compound of the formula I (I) wherein R1 and R2 both represent a methyl group or together represent a tetramethylene or pentamethylene group and R3 represents a phenyl, 3-chlorophenyl, 4-chlorophenyl, 3,4dichlorophenyl or 4-fluorophenyl group.

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