公开(公告)号：CA2042857C

公开(公告)日：2002-09-10

申请号：CA2042857

申请日：1991-05-17

Applicant: CIBA GEIGY AG

Inventor： BRUNNER RUDOLF ,  STOCKINGER FRIEDRICH

IPC: C07C243/00 ,  C07D403/00 ,  C08F222/40 ,  C08G59/40 ,  C08G59/62 ,  C08G65/48 ,  C08G73/12 ,  C08K5/13 ,  C08K5/3415 ,  C08L71/00 ,  C08L71/08 ,  C08L71/10 ,  C08L79/08 ,  C08L81/00 ,  C08L81/06 ,  C08L39/00 ,  C08L71/12 ,  C08J3/24

Abstract: There are disclosed novel compositions comprising a) at least one bismaleide, b) at least one mono- or polynuclear alkenylphenol, one alkenylphenol ether or a mixture thereof, wherein the alkenyl group contains at least three 3 carbon atoms, c) a copolyether resin. The compositions of the invention can be cured to products having improved toughness and high glass transition temperatures. These products are suitable for maki ng high-performance moulded articles which can be subjected to high temperature s, for example fibre-reinforced composites, structural adhesives, laminating or electrical insulating resins.

公开(公告)号：CA2041885A1

公开(公告)日：1991-11-09

申请号：CA2041885

申请日：1991-05-06

Applicant: CIBA GEIGY AG

Inventor： PFAENDNER RUDOLF ,  KAINMUELLER THOMAS ,  HOFFMANN KURT ,  STOCKINGER FRIEDRICH ,  KRAMER ANDREAS

IPC: C07C45/46 ,  C07C45/67 ,  C07C49/813 ,  C07C49/83 ,  C07C49/84 ,  C08G59/24 ,  C08G59/62 ,  C08G63/193 ,  C08G64/06 ,  C08G65/40 ,  C08G69/26 ,  C08G75/23 ,  C08L71/00 ,  C07C49/76 ,  C07C317/24 ,  C07D303/32

Abstract: K-18064/A/CGM367 Essentially linear polymers of the disclosure Essentially linear polymers having a reduced viscosity of from 0.1 to 2.0 dl/g, measured on a 1 % by weight solution in N-methylpyrrolidone (NMP) at 25.degree.C, and containing at least a proportion of structural units of the formula I (I), in which the aromatic rings are unsubstituted or substituted, Ar is a divalent aliphatic, cycloaliphatic, araliphatic or aromatic radical having up to 50 carbon atoms, X1 is a direct bond, -SO2-, -CO-, -CO-O-, -CO-NH- or in which R2 is a hydrogen atom or methyl and Q1 is -O-, -NH-, -S- or -OCO-, Y1 is a direct bond, -SO2-, -CO-, -O-CO-, -NH-CO- or in which R2 is a hydrogen atom or methyl and Q2 is -O-, -NH-, -S- or -OCO-, R1 is a divalent aliphatic, cycloaliphatic, aromatic or araliphatic radical having up to 30 carbon atoms, which increases the solubility of the polymer in organic solvents can advantageously be processed from the solution and are suitable for modifying matrix resins.

公开(公告)号：CA1242216A

公开(公告)日：1988-09-20

申请号：CA422011

申请日：1983-02-21

Applicant: CIBA GEIGY AG

Inventor： STOCKINGER FRIEDRICH ,  LOHSE FRIEDRICH ,  MOSER ROLAND

IPC: C08G59/00 ,  C07C67/00 ,  C07C239/00 ,  C07C261/04 ,  C07C313/00 ,  C07C315/04 ,  C07C317/40 ,  C07C323/41 ,  C07C323/42 ,  C07C323/60 ,  C08G59/40 ,  C08G59/44 ,  C07C125/08

Abstract: N-Cyanocarboxylic acid amides, processes for their preparation and their use N-Cyanocarboxylic acid amide derivatives which contain two or three groupings in the molecule are obtained by reacting 1 mol of a dicyanodiamine with 2 mols of a carboxylic acid anhydride or 1 mol of a dicyandiamine salt with 2 mols of a carboxylic acid halide or 1 mol of a dihalogeno compound with 2 mols of an N-cyanocarboxylic acid amide salt or by reacting 1 mol of a carboxylic acid dichloride or trichloride with 2 or respectively 3 mols of a cyanamide or 1 mol of a carboxylic acid dicyandiamide or tricyantriamide salt with 2 or 3 mols of an alkylating agent. The Ncyanocarboxylic acid amide derivatives according to the invention are useful hardeners for epoxide resins.

公开(公告)号：CA1142294A

公开(公告)日：1983-03-01

申请号：CA377343

申请日：1981-05-11

Applicant: CIBA GEIGY AG

Inventor： ELDIN SAMEER H ,  STOCKINGER FRIEDRICH

IPC: C08F226/06 ,  C08F246/00

Abstract: The present invention relates to novel polymers which comprises repeating units derived from hydantoin vinyl ethers of the formula in which R1 is hydrogen or an organic radical, R2 is an alkylene group, and R3 and R4 are preferably lower alkylene groups, and optionally repeating units from one or two cocomponents derived from other olefinically unsaturated compounds. The novel polymers can be used as thickeners, solubilising agents, binders, thixotropic agents, complexing agents, stabilisers and so forth.

公开(公告)号：CH629485A5

公开(公告)日：1982-04-30

申请号：CH1344877

申请日：1977-11-04

Applicant: CIBA GEIGY AG

Inventor： STOCKINGER FRIEDRICH ,  LOHSE FRIEDRICH DR

IPC: C07D207/28 ,  C08G59/50

公开(公告)号：AU3849097A

公开(公告)日：1998-02-10

申请号：AU3849097

申请日：1997-07-19

Applicant: CIBA GEIGY AG

Inventor： STEINMANN BETTINA ,  STOCKINGER FRIEDRICH

IPC: B29C33/06 ,  B29C35/08 ,  B29C39/02 ,  C08F2/48 ,  C08F290/06 ,  C08F299/02 ,  C08G59/68 ,  C08G65/332 ,  C08J5/00 ,  C08L71/02 ,  G02B1/04

公开(公告)号：FI973157A

公开(公告)日：1997-09-24

申请号：FI973157

申请日：1997-07-30

Applicant: CIBA GEIGY AG

Inventor： STOCKINGER FRIEDRICH ,  MUELLER BEAT

IPC: B29D11/00 ,  C08F8/00 ,  G02C7/04 ,  C08F8/30 ,  C08F216/06 ,  C08F299/00 ,  C08G18/81 ,  C08J3/24 ,  G02B1/04 ,  G02B

Abstract: PCT No. PCT/EP96/00243 Sec. 371 Date Oct. 6, 1997 Sec. 102(e) Date Oct. 6, 1997 PCT Filed Jan. 22, 1996 PCT Pub. No. WO96/24073 PCT Pub. Date Aug. 8, 1996A process for the production of mouldings, in particular contact lenses, in which a water-soluble, crosslinkable polymer is crosslinked in solution, and mouldings, in particular contact lenses, obtainable by this process; and novel water-soluble, crosslinkable polymers which can be employed in the crosslinking process, in particular those based on polyvinyl alcohol having a molecular weight of at least about 2000 which comprises units of the formulae: XI and XII, XI and XIII or XI, XII and XIII. In said Formulae, U is (a) or -Y-NH-CO-O-Z-O-CH=CH2 group, and a unit of the formula XII and a unit of the formula XIII as defined in the description, and crosslinked polymers, either homopolymers or copolymers, made from these novel water-soluble, crosslinkable polymers, a process for the preparation of the novel water-soluble, crosslinkable polymers and the homopolymers and copolymers obtainable therefrom, mouldings made from said homopolymers or copolymers, in particular contact lenses made from these homopolymers or copolymers, and a process for the production of contact lenses using said homopolymers or copolymers.

公开(公告)号：NO973514D0

公开(公告)日：1997-07-30

申请号：NO973514

申请日：1997-07-30

Applicant: CIBA GEIGY AG

Inventor： STOCKINGER FRIEDRICH ,  MUELLER BEAT

IPC: B29D11/00 ,  G02C7/04 ,  C08F8/00 ,  C08F8/30 ,  C08F216/06 ,  C08F299/00 ,  C08G18/81 ,  C08J3/24 ,  G02B1/04

Abstract: PCT No. PCT/EP96/00243 Sec. 371 Date Oct. 6, 1997 Sec. 102(e) Date Oct. 6, 1997 PCT Filed Jan. 22, 1996 PCT Pub. No. WO96/24073 PCT Pub. Date Aug. 8, 1996A process for the production of mouldings, in particular contact lenses, in which a water-soluble, crosslinkable polymer is crosslinked in solution, and mouldings, in particular contact lenses, obtainable by this process; and novel water-soluble, crosslinkable polymers which can be employed in the crosslinking process, in particular those based on polyvinyl alcohol having a molecular weight of at least about 2000 which comprises units of the formulae: XI and XII, XI and XIII or XI, XII and XIII. In said Formulae, U is (a) or -Y-NH-CO-O-Z-O-CH=CH2 group, and a unit of the formula XII and a unit of the formula XIII as defined in the description, and crosslinked polymers, either homopolymers or copolymers, made from these novel water-soluble, crosslinkable polymers, a process for the preparation of the novel water-soluble, crosslinkable polymers and the homopolymers and copolymers obtainable therefrom, mouldings made from said homopolymers or copolymers, in particular contact lenses made from these homopolymers or copolymers, and a process for the production of contact lenses using said homopolymers or copolymers.

公开(公告)号：DE4238261A1

公开(公告)日：1993-05-19

申请号：DE4238261

申请日：1992-11-12

Applicant: CIBA GEIGY AG

Inventor： PFAENDNER RUDOLF DR ,  WOLF JEAN-PIERRE DR ,  KAINMUELLER THOMAS DR ,  KRAMER ANDREAS DR ,  HOFFMANN KURT DR ,  STOCKINGER FRIEDRICH

IPC: C07C37/055 ,  C08L63/00 ,  C08L71/00 ,  C08L71/10 ,  C08L81/06 ,  C09D171/10

Abstract: The mixts. (I) contain (A) epoxy resin with glycidyl gps. directly linked to O, N or S atoms, (B) polyarylene ether with reduced viscosity 0.1-2.0 dl/g (1% in NMP), contg. 1-100 mol.% untis of formula (II) and 99-0 mol.% units of formula -(O-Ar'-O-Ar)- (III) and opt. (C) amino or phenolic hardener. Ar' = divalent residue of activated dihalo cpd. which may be nucleophile substd. and Ar = divalent residue of diphenol. Pref. (I) contain 20-80 wt.% (A), 2-40 wt.% (B) and 5-50 wt.% amine hardener. (A) is a diglycidyl ether of Bisphenol A, F or S, N,N,O-triglycidyl-m- (or p)-aminophenol (A1), or N,N,N',N'-tetra glycidyl-4,4'-diamino-diphenylmethane (A2) or -3,3-diethyl-4,4'-diamino diphenylmethane. Ar' = (opt. 1-4C alkyl- or alkoxy-substd.), -pPhe-X-(Phe-X)c-pPhe-, -pPhe-X-(Phe)d-X-pPhe- (with Phe = phenylene; and pPhe = 1,4-phenylene; X = CO, SO2 or SO; c = 0 or 1; and d = 2 or 3), CN-substd. phenylene, pyridine or 1,2-pyrazine diyl, pref. -pPhe-SO2-pPhe-, 2-cyano-1,3-phenylene or -pPhe-Co-pPhe, (-pPhe-SO2-pPhe). USE/ADVANTAGE - W.r.t. prior art sulphone modifiers based on 2,2'-dihydroxy biphenyl, polyether-sulphones based on 4,4'-dihydroxy-3,3'-diphenyl biphenyl (IV) give epoxy resin mixts. (I) with improved mechanical properties.

公开(公告)号：CA2021689A1

公开(公告)日：1991-01-25

申请号：CA2021689

申请日：1990-07-20

Applicant: CIBA GEIGY AG

Inventor： PFAENDNER RUDOLF ,  KAINMULLER THOMAS ,  HOFFMANN KURT ,  WOLF JEAN-PIERRE ,  KRAMER ANDREAS ,  STOCKINGER FRIEDRICH

IPC: C07C43/295 ,  C07C43/23 ,  C07C45/71 ,  C07C49/84 ,  C07C69/017 ,  C07D303/24 ,  C08G59/20 ,  C08G59/22 ,  C08G59/24 ,  C08G63/19 ,  C08G63/193 ,  C08G63/672 ,  C08G63/685 ,  C08G63/688 ,  C08G64/00 ,  C08G64/16 ,  C08G65/40 ,  C08G69/40 ,  C08G69/44 ,  C08G69/46 ,  C08G75/00 ,  C08G75/23 ,  C08G75/24 ,  C09D171/00 ,  C09D171/10 ,  C09J171/00 ,  C09J171/10 ,  C08G83/00

Abstract: K-17675/+/CGM 354 Linear polymers Substantially linear polymers that are characterised by the presence of a radical of formula wherein X1 is selected from the group consisting of -O-,-O-SO2-,-O-CO-,-O-CO-O-and -O-CO-NH-, Y1 is selected from the group consisting of -O-,-SO2-O-,-CO-O-,-O-CO-O-and -NH-CO-O-, R1 is a divalent aliphatic, cycloaliphatic, aromatic or araliphatic radical after the removal of the functional groups, or wherein, if Y1 is -O- or -O-CO-O-, the group X1-R1 may alternatively be a direct C-C bond, R2 is alkyl, alkenyl, cycloalkyl, aryl or halogen, R3 is alkyl, cycloalkyl, aryl or halogen, and each of m and n, independently of the other, is an integer from 0 to 4, are described.