-
公开(公告)号:JPH05131118A
公开(公告)日:1993-05-28
申请号:JP9620192
申请日:1992-04-16
Applicant: CORNING INC
Inventor: LACHMAN IRWIN M , PATIL MALLANAGOUDA D , WILLIAMS JIMMIE L
IPC: B01D53/94 , B01J23/56 , B01J23/63 , B01J29/06 , B01J35/04 , F01N3/20 , F01N3/28 , F01N13/02 , F01N13/04
Abstract: PURPOSE: To carry out a catalytic conversion of an exhaust gas into an innocuous substance without using rhodium catalyst and without supplying ammonia from the outside. CONSTITUTION: An exhaust gas introduced via a first conduit 12 is passed through a first multicellular unit 16. A first catalyst disposed in the first unit converts at least a portion of NOX into ammonia and a modified mixture is produced. The modified mixture introduced via a second conduit 18 into a second multicellular unit 24. Ammonia and the residual NOX are converted into an innocuous substance by a catalytic reaction with a second catalyst disposed in the second unit. The innocuous substance converted are exhausted from an exhausting conduit 26 to the surrounding atmosphere.
-
公开(公告)号:CA2128562A1
公开(公告)日:1995-02-17
申请号:CA2128562
申请日:1994-07-21
Applicant: CORNING INC
Inventor: HERTL WILLIAM , LACHMAN IRWIN M
IPC: B01D53/04 , B01D53/72 , B01D53/86 , B01D53/94 , B01J29/072 , B01J35/02 , F01N3/08 , F01N3/20 , F01N3/24 , F01N13/02 , F02M25/07 , B01D53/36
Abstract: A modified large pore zeolite molecular sieve structure is disclosed for adsorbing alkenes emitted during engine start-up, before the catalytic converter has attained its effective operating temperature. The zeolite molecular sieve is modified by inserting certain metal ions into the molecular sieve structure. In particular, a modified y-zeolite having a high adsorption capacity for propylene is disclosed.
-
公开(公告)号:CA2096197A1
公开(公告)日:1994-02-06
申请号:CA2096197
申请日:1993-05-13
Applicant: CORNING INC
Inventor: LACHMAN IRWIN M , PATIL MALLANAGOUDA D
IPC: B01D53/04 , B01D53/86 , B01D53/94 , B01J20/02 , B01J29/83 , B01J29/85 , B01J29/89 , B01J35/04 , F01N3/08 , F01N3/20 , F01N3/28 , F01N13/02 , B01J8/06 , B01D53/36
Abstract: An apparatus, system and method are disclosed for modifying a gaseous mixture. The apparatus comprises a unitary body having an inlet end, an outlet end, and a multiplicity of cells extending from inlet end to outlet end, the cells being separated from one another by porous walls, and filler material comprising electrically nonconducting active powder material, loaded into at least part of the volume of the cells, with some of the cells being unloaded and open, wherein a gaseous mixture enters the body at the inlet end through the open cells, and at least some of the gaseous mixture passes through the porous walls and is compositionally modified by the active material, and thereafter the resultant modified mixture passes through the open cells and exits the body at the outlet end. The apparatus can be used in conjunction with other apparatuses which are catalyzed to form a gas modifying system. The apparatus and system are especially suited for conversion of hydrocarbons, NOx, and CO as from auto exhaust, and for Denox applications.
-
公开(公告)号:BR9403249A
公开(公告)日:1995-08-22
申请号:BR9403249
申请日:1994-08-15
Applicant: CORNING INC
Inventor: HERTL WILLIAM , LACHMAN IRWIN M
IPC: B01D53/04 , B01D53/72 , B01D53/86 , B01D53/94 , B01J29/072 , B01J35/02 , F01N3/08 , F01N3/20 , F01N3/24 , F01N13/02 , F02M25/07 , B01D53/92
Abstract: A modified large pore zeolite molecular sieve structure is disclosed for adsorbing alkenes emitted during engine start-up, before the catalytic converter has attained its effective operating temperature. The zeolite molecular sieve is modified by inserting certain metal ions into the molecular sieve structure. In particular, a modified y-zeolite having a high adsorption capacity for propylene is disclosed.
-
公开(公告)号:BR9403248A
公开(公告)日:1995-08-22
申请号:BR9403248
申请日:1994-08-15
Applicant: CORNING INC
Inventor: HERTL WILLIAM , LACHMAN IRWIN M , PATIL MALLANAGOUDA D
IPC: B01D53/04 , B01D53/72 , B01D53/86 , B01D53/94 , B01J29/072 , B01J35/02 , F01N3/08 , F01N3/20 , F01N3/24 , F02M25/07 , B01D53/92
Abstract: A molecular sieve structure is disclosed for adsorbing hydrocarbons emitted during engine start-up, before the catalytic converter has attained its effective operating temperature. The molecular sieve can be zeolites or ceramic substrates having a zeolite surface. The molecular sieve is modified by inserting certain metal ions into the molecular sieve structure. The molecular sieve structure is also capable of releasing or desorbing the hydrocarbons when the molecular sieve reaches a certain temperature.
-
公开(公告)号:CA2100935A1
公开(公告)日:1994-04-21
申请号:CA2100935
申请日:1993-07-20
Applicant: CORNING INC
Inventor: HERTL WILLIAM , LACHMAN IRWIN M
Abstract: An improvement in a system and method is disclosed for converting exhaust gas from an exhaust gas generating device, to innocuous products in which exhaust gas is contacted with a catalyst system comprising a NOx, CO, and hydrocarbon conversion catalyst. The improvement comprises providing a zeolite upstream of the conversion catalyst and positioned close enough to the device to allow the temperature of the zeolite to reach at least about 100.degree.C within a period of time of no longer than about 100 seconds after start-up of the device, and contacting the exhaust gas with the zeolite to cause adsorption of hydrocarbons during that period. The zeolite has a SiO, to Al2O, mole ratio of no greater than about 250 to 1, and pore openings of about 3.8 to about 6.0.ANG. in diameter.
-
公开(公告)号:CA2043191A1
公开(公告)日:1991-12-09
申请号:CA2043191
申请日:1991-05-24
Applicant: CORNING INC
Inventor: LACHMAN IRWIN M , PATIL MALLANAGOUDA D , SOCHA LOUIS S JR
IPC: B01J35/04 , B01D53/04 , B01D53/94 , B01J29/035 , F01N3/08 , F01N3/20 , F01N3/24 , F01N13/02 , F02D21/08 , F01N3/28
Abstract: DUAL CONVERTER ENGINE EXHAUST SYSTEM FOR REDUCING HYDROCARBON EMISSIONS of the Invention An engine exhaust system and method of controlling hydrocarbon emissions are provided. The system and method are based on the use of two catalytic converter chambers, a first chamber containing a catalytic material and a second chamber containing catalyst as well as molecular sieves capable of adsorbing hydrocarbons during engine start-up and of having hydrocarbons desorbed therefrom when the catalysts reach an effective converting temperature. According to the invention, engine exhaust is selectively conveyed to each of the two converters in a manner such that initially produced hydrocarbon is withheld in the system by the molecular sieves in order to be recycled through the converters and brought into contact with the catalyst after an effective converting temperature has been attained.
-
8.
公开(公告)号:CA1267879A
公开(公告)日:1990-04-17
申请号:CA500480
申请日:1986-01-28
Applicant: CORNING INC
Inventor: BARDHAN PRONOB , LACHMAN IRWIN M , NORDLIE LAWRENCE A
IPC: B01D53/86 , B01J20/28 , B01J21/04 , B01J21/06 , B01J21/12 , B01J21/16 , B01J23/02 , B01J29/06 , B01J32/00 , B01J35/02 , B01J35/04 , B01J37/00 , B01J37/04
Abstract: PREPARATION OF MONOLITHIC CATALYST SUPPORT STRUCTURES HAVING AN INTEGRATED HIGH SURFACE AREA PHASE A method of forming a monolithic ceramic catalyst support having a high surface area phase of porous oxide embedded within the monolith structure is provided. The porous oxide phase is incorporated into a sinterable ceramic structure as a discrete discontinuous phase. The high surface area necessary for effective catalyst support is thereby provided within the ceramic structure, which is sintered to provide appreciable density and strength.
-
公开(公告)号:DE69217108T2
公开(公告)日:1997-07-10
申请号:DE69217108
申请日:1992-04-15
Applicant: CORNING INC
Inventor: LACHMAN IRWIN M , PATIL MALLANAGOUDA D , SWAROOP SRINIVAS H , WILLIAMS JIMMIE L
IPC: B01D53/94 , B01J23/56 , B01J23/63 , B01J29/06 , B01J35/04 , F01N3/20 , F01N3/28 , F01N13/02 , F01N13/04 , B01D53/56 , B01D53/88
Abstract: An apparatus and method for converting exhaust gases to innocuous products is disclosed. Exhaust gas is conveyed by a first conduit to, and passed through a first multicellular unit in which a portion of the cells are catalyzed with a first catalyst for reacting at least a portion of the NOx to ammonia, and thereafter the resulting modified mixture only is conveyed by a second conduit from the first unit and to a second multicellular unit to react the ammonia and the remaining NOx to produce innocuous products. The second conduit is connected only to the first and second units. The passage of the exhaust gas through the units results in conversion of NOx, CO, and hydrocarbons to innocuous products.
-
公开(公告)号:DE69217108D1
公开(公告)日:1997-03-13
申请号:DE69217108
申请日:1992-04-15
Applicant: CORNING INC
Inventor: LACHMAN IRWIN M , PATIL MALLANAGOUDA D , SWAROOP SRINIVAS H , WILLIAMS JIMMIE L
IPC: B01D53/94 , B01J23/56 , B01J23/63 , B01J29/06 , B01J35/04 , F01N3/20 , F01N3/28 , F01N13/02 , F01N13/04 , B01D53/56 , B01D53/88
Abstract: An apparatus and method for converting exhaust gases to innocuous products is disclosed. Exhaust gas is conveyed by a first conduit to, and passed through a first multicellular unit in which a portion of the cells are catalyzed with a first catalyst for reacting at least a portion of the NOx to ammonia, and thereafter the resulting modified mixture only is conveyed by a second conduit from the first unit and to a second multicellular unit to react the ammonia and the remaining NOx to produce innocuous products. The second conduit is connected only to the first and second units. The passage of the exhaust gas through the units results in conversion of NOx, CO, and hydrocarbons to innocuous products.
-
-
-
-
-
-
-
-
-