1.
    发明专利
    未知

    公开(公告)号:MX9206226A

    公开(公告)日:1993-05-01

    申请号:MX9206226

    申请日:1992-10-28

    Applicant: CORNING INC

    Abstract: This invention is drawn to a method for eliminating the grayish discoloration which customarily develops when lead-free and cadmium-free glass frits are applied to substrates employing an organic vehicle and which are thereafter fired to fuse the frit particles into a glaze. The grayish hue results from a carbonaceous residue left upon thermally decomposing the organic vehicle. The inventive method comprises five general elements: (a) glass frit particles of a desired composition are prepared; (b) a coating of an organic compound containing at least one sulfur oxide group as an oxidizing agent is adsorbed on the surface of the particles; (c) the coated particles are mixed with an organic vehicle; (d) that mixture is coated onto a surface of a substrate; and (e) that coated substrate is fired to fuse the frit particles into a glaze, the oxidizing agent eliminating the carbonaceous residue left upon thermal decomposition of the organic vehicle.

    2.
    发明专利
    未知

    公开(公告)号:DE69011806D1

    公开(公告)日:1994-09-29

    申请号:DE69011806

    申请日:1990-10-18

    Applicant: CORNING INC

    Abstract: There is disclosed a sintered, alpha-cordierite solid solution glass-ceramic body in which the properties of coefficient of thermal expansion and modulus of rupture are stabilized and controlled by using a combination of two dopants in the glass during sintering and crystallization. There is further disclosed the method of producing such bodies, and controlling such properties, through the use of the two dopants.

    3.
    发明专利
    未知

    公开(公告)号:DE69206578D1

    公开(公告)日:1996-01-18

    申请号:DE69206578

    申请日:1992-09-15

    Applicant: CORNING INC

    Abstract: This invention is drawn to a method for eliminating the grayish discoloration which customarily develops when lead-free and cadmium-free glass frits are applied to substrates employing an organic vehicle and which are thereafter fired to fuse the frit particles into a glaze. The grayish hue results from a carbonaceous residue left upon thermally decomposing the organic vehicle. The inventive method comprises five general elements: (a) glass frit particles of a desired composition are prepared; (b) a coating of an organic compound containing at least one sulfur oxide group as an oxidizing agent is adsorbed on the surface of the particles; (c) the coated particles are mixed with an organic vehicle; (d) that mixture is coated onto a surface of a substrate; and (e) that coated substrate is fired to fuse the frit particles into a glaze, the oxidizing agent eliminating the carbonaceous residue left upon thermal decomposition of the organic vehicle.

    4.
    发明专利
    未知

    公开(公告)号:DE69206578T2

    公开(公告)日:1996-08-08

    申请号:DE69206578

    申请日:1992-09-15

    Applicant: CORNING INC

    Abstract: This invention is drawn to a method for eliminating the grayish discoloration which customarily develops when lead-free and cadmium-free glass frits are applied to substrates employing an organic vehicle and which are thereafter fired to fuse the frit particles into a glaze. The grayish hue results from a carbonaceous residue left upon thermally decomposing the organic vehicle. The inventive method comprises five general elements: (a) glass frit particles of a desired composition are prepared; (b) a coating of an organic compound containing at least one sulfur oxide group as an oxidizing agent is adsorbed on the surface of the particles; (c) the coated particles are mixed with an organic vehicle; (d) that mixture is coated onto a surface of a substrate; and (e) that coated substrate is fired to fuse the frit particles into a glaze, the oxidizing agent eliminating the carbonaceous residue left upon thermal decomposition of the organic vehicle.

    7.
    发明专利
    未知

    公开(公告)号:DE69011806T2

    公开(公告)日:1995-04-06

    申请号:DE69011806

    申请日:1990-10-18

    Applicant: CORNING INC

    Abstract: There is disclosed a sintered, alpha-cordierite solid solution glass-ceramic body in which the properties of coefficient of thermal expansion and modulus of rupture are stabilized and controlled by using a combination of two dopants in the glass during sintering and crystallization. There is further disclosed the method of producing such bodies, and controlling such properties, through the use of the two dopants.

    ADDITIVES FOR LEAD-FREE FRITS
    9.
    发明专利

    公开(公告)号:CA2076827C

    公开(公告)日:2004-02-24

    申请号:CA2076827

    申请日:1992-08-25

    Applicant: CORNING INC

    Abstract: This invention is drawn to a method for eliminating the grayish discoloration which customarily develops when lead-free and cadmium-free glass frits are applied to substrates employing an organic vehicle and which are thereafter fired to fuse the frit particles into a glaze. The grayish hue results from a carbonaceous residue left upon thermally decomposing the organic vehicle. The inventive method comprises five general elements: (a) glass frit particles of a desired composition are prepared; (b) a coating of an organic compound containing at least one sulfur oxide group as an oxidizing agent is adsorbed on the surface of the particles; (c) the coated particles are mixed with an organic vehicle; (d) that mixture is coated onto a surface of a substrate; and (e) that coated substrate is fired to fuse the frit particles into a glaze, the oxidizing agent eliminating the carbonaceous residue left upon thermal decomposition of the organic vehicle.

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