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公开(公告)号:IN192765B
公开(公告)日:2004-05-15
申请号:IN2461DE1995
申请日:1995-12-29
Applicant: COUNCIL SCIENT IND RES
Inventor: BASKARAN DURAIRAJ , SIVARAJ SWAMINATHAN
IPC: C08F4/10 , C08F4/56 , C08F120/12 , C08F120/14 , C08F120/06 , C08F4/00
Abstract: A process for the living anionic polymerization of alkyl(meth)acrylic monomers, involving polymerizing the monomers in the presence of an initiator comprising a carbanion and a metal or nonmetal salt of perchloric acid. The initiator has the formula (I): wherein R1=a linear or branched alkyl group having one to six carbon atoms, R2=a phenyl or alkyl group having one to six carbon atoms, R3=a phenyl or an ester group and M+ is an alkali, alkaline earth metal or quarternary ammonium cation containing 1-8 carbon atoms in an alkyl group thereof.