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    COMPOSITIONS OF EPOXYSILANE EMULSION ADDITIVES IN WATERBASED REACTIVE POLYMER DISPERSIONS AND METHODS OF PREPARATION
    1.
    发明公开
    COMPOSITIONS OF EPOXYSILANE EMULSION ADDITIVES IN WATERBASED REACTIVE POLYMER DISPERSIONS AND METHODS OF PREPARATION 失效
    在反应性聚合物分散体环氧硅烷乳化添加剂的的组成水基和方法及其

    公开(公告)号：EP0868476A4

    公开(公告)日：2001-04-18

    申请号：EP96933214

    申请日：1996-10-02

    Applicant: CROMPTON CORP

    Inventor： OSTERHOLTZ FREDERICK D ,  POHL ERIC R ,  CHEN MING J ,  CHAVES ANTONIO

    IPC: C08K5/54 ,  C08K5/15 ,  C08K5/5435 ,  C08L83/06 ,  C08L101/00 ,  C09D133/06 ,  C09D183/06 ,  C09D201/00

    CPC classification number: C08K5/5435 ,  C09D133/064 ,  C09D183/06 ,  C08L2666/28 ,  C08L2666/04

    Abstract: The present invention provides stable epoxy silane emulsions and methods for the preparation of a stable epoxy-silane emulsions comprising: (I) a water insoluble or slightly soluble epoxysilane; (II) an emulsifier; (III) water; and (IV) a water dispersible polymer containing a functional group with an active hydrogen. Also provided are two part systems such that an epoxysilane emulsion comprising components (I)-(III) are combined and the component (IV) may be added upon use of components (I) to (III). Moreover, additional components (V), such as catalysts and pH buffers may be added. Said compositions may be used for, among other things, coatings, adhesives and sealants. The water dispersible or slightly soluble epoxy functional silane for use herein are of the general structure R1aR2bSi(OR3)4-a-b where R1 is an epoxy substituted alkyl or aralkyl group, where the alkyl may have from four to thirty carbon atoms, R3 is an alkyl or alkoxy-substituted alkyl, aryl or aralkyl group having from two to ten carbon atoms, R2 is an alkyl group or alkoxy substituted alkyl, aryl or aralkyl group having from one to ten carbon atoms, a is one to three, and b is zero to two, with the proviso that a+b is 1, 2, or 3. R?1, R2, and R3¿ group may be cyclic, branched or linear.

    4.
    发明专利
    未知

    公开(公告)号：AT264369T

    公开(公告)日：2004-04-15

    申请号：AT96932359

    申请日：1996-10-02

    Applicant: CROMPTON CORP

    Inventor： CHEN MING J ,  OSTERHOLTZ FREDERICK D

    IPC: C08L83/04 ,  C08K5/57 ,  C08L43/04 ,  C08L101/10 ,  C09D143/04 ,  C09D183/04 ,  C09D201/10

    Abstract: Curable composition comprising a stable, water dispersible, curable polymer containing a sterically hindered alkoxylated silane group at 0.1 to 75 weight percent of the total composition; a water dispersible or water soluble, hydrolytically stable organometallic catalyst, at 0.1 to 10 weight percent of the total composition; and water at 99.8 to 24.9 weight percent of the total composition are taught herein. These compositions are useful as adhesives, sealants and paints. The compositions have improved properties including solvent resistance, adhesion, hardness, abrasion resistance and mar resistance. Particular catalysts for use herein include dihydroxy bis [2-hydroxypropanato (2-)-O ,O ] titanate mixed titanium ortho ester complexes, acetylacetonate chelate, bis(ethyl-3-oxobutanolato-O ,O ) bis(2-propanolato) titanium, alkanolamine complex of titanium and mercaptoalcohol, mercaptide or sulfide forms of diorganotins having either a Sn-S or Sn=S bond.

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