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1.
公开(公告)号:US11135575B2
公开(公告)日:2021-10-05
申请号:US15928690
申请日:2018-03-22
Applicant: Chevron U.S.A. Inc.
Inventor: Michael John Girgis , Huping Luo , Bong Kyu Chang , Hye-Kyung Cho Timken , Steven Xugi Song , Michael Sean Driver
IPC: C07C2/58 , B01J31/40 , B01J31/02 , B01J38/10 , C07C2/62 , C10L1/06 , C10G29/20 , C10G45/60 , C10G47/02 , C10G50/00 , B01J35/12 , C07C2/56
Abstract: We provide a process for regenerating a spent acidic ionic liquid, comprising contacting the spent acidic ionic liquid with hydrogen and without an addition of a hydrogenation catalyst; wherein a conjunct polymer content is decreased in the spent acidic ionic liquid to produce regenerated acidic ionic liquid. We also provide a process for making an alkylate gasoline blending component, comprising: a) alkylating a mixture of isoparaffins and olefins using an acidic ionic liquid and an alkyl halide or a hydrogen halide, wherein a conjunct polymer accumulates in a spent acidic ionic liquid; and b) feeding the spent acidic ionic liquid and a hydrogen, and without an addition of a hydrogenation catalyst, to a regeneration reactor operated under selected hydrogenation conditions to produce a regenerated acidic ionic liquid that is used for the alkylating, wherein the conjunct polymer in the regenerated acidic ionic liquid is decreased by at least 50 wt %.
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公开(公告)号:US20150133711A1
公开(公告)日:2015-05-14
申请号:US14597415
申请日:2015-01-15
Applicant: Chevron Phillips Chemical Company LP , Chevron U.S.A. Inc.
Inventor: Lei JI , Ai-Fu CHANG , Michael Sean Driver , Hye-Kyung Cho Timken
CPC classification number: C07C7/11 , B01D53/1462 , B01D53/1487 , B01D53/1493 , B01D53/229 , B01D53/526 , B01D2252/30 , B01D2256/22 , B01D2256/24 , B01D2257/304 , B01D2257/504 , B01D2257/7022 , C01B17/167 , C07C7/144 , C07C7/152 , Y02P20/152 , Y02P20/51 , Y02P20/542 , C07C11/04 , C07C11/09 , C07C9/04
Abstract: Disclosed are systems and methods which provide a process stream comprising a gaseous component, capture the gaseous component from the process stream by an ionic liquid solvent of a separator, and recover a captured gaseous component from the ionic liquid solvent in a regenerator. A second gaseous component from the process stream may be captured by the ionic liquid solvent of the separator, and the second gaseous component may be recovered from the ionic liquid solvent in the regenerator. Alternatively, the second gaseous component from the process stream may be uncaptured by the ionic liquid solvent, and the uncaptured second gaseous component may be recovered from a membrane unit.
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公开(公告)号:US10227274B2
公开(公告)日:2019-03-12
申请号:US14597415
申请日:2015-01-15
Applicant: Chevron Phillips Chemical Company LP , Chevron U.S.A. Inc.
Inventor: Lei Ji , Ai-Fu Chang , Michael Sean Driver , Hye-Kyung Cho Timken
Abstract: Disclosed are systems and methods which provide a process stream comprising a gaseous component, capture the gaseous component from the process stream by an ionic liquid solvent of a separator, and recover a captured gaseous component from the ionic liquid solvent in a regenerator. A second gaseous component from the process stream may be captured by the ionic liquid solvent of the separator, and the second gaseous component may be recovered from the ionic liquid solvent in the regenerator. Alternatively, the second gaseous component from the process stream may be uncaptured by the ionic liquid solvent, and the uncaptured second gaseous component may be recovered from a membrane unit.
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4.
公开(公告)号:US20180207629A1
公开(公告)日:2018-07-26
申请号:US15928690
申请日:2018-03-22
Applicant: Chevron U.S.A. Inc.
Inventor: Michael John Girgis , Huping Luo , Bong Kyu Chang , Hye-Kyung Timken , Steven Xugi Song , Michael Sean Driver
IPC: B01J31/40 , B01J35/12 , B01J38/10 , C10L1/06 , B01J31/02 , C07C2/62 , C10G29/20 , C10G50/00 , C10G47/02 , C10G45/60 , C07C11/16
CPC classification number: B01J31/40 , B01J31/0284 , B01J31/0298 , B01J35/12 , B01J38/10 , B01J2231/44 , C07C2/62 , C07C2531/02 , C10G29/205 , C10G45/60 , C10G47/02 , C10G50/00 , C10L1/06 , C10L2270/023 , C10L2290/12 , Y02P20/584 , C07C11/16
Abstract: We provide a process for regenerating a spent acidic ionic liquid, comprising contacting the spent acidic ionic liquid with hydrogen and without an addition of a hydrogenation catalyst; wherein a conjunct polymer content is decreased in the spent acidic ionic liquid to produce regenerated acidic ionic liquid. We also provide a process for making an alkylate gasoline blending component, comprising: a) alkylating a mixture of isoparaffins and olefins using an acidic ionic liquid and an alkyl halide or a hydrogen halide, wherein a conjunct polymer accumulates in a spent acidic ionic liquid; and b) feeding the spent acidic ionic liquid and a hydrogen, and without an addition of a hydrogenation catalyst, to a regeneration reactor operated under selected hydrogenation conditions to produce a regenerated acidic ionic liquid that is used for the alkylating, wherein the conjunct polymer in the regenerated acidic ionic liquid is decreased by at least 50 wt %.
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公开(公告)号:US09956552B2
公开(公告)日:2018-05-01
申请号:US15010168
申请日:2016-01-29
Applicant: Chevron U.S.A. Inc.
Inventor: Michael John Girgis , Huping Luo , Bong Kyu Chang , Hye-Kyung Timken , Steven Xugi Song , Michael Sean Driver
IPC: C07C2/58 , B01J31/40 , B01J31/02 , B01J38/10 , C07C2/62 , C10L1/06 , C10G29/20 , C10G45/60 , C10G47/02 , C10G50/00 , B01J35/12
CPC classification number: B01J31/40 , B01J31/0284 , B01J35/12 , B01J38/10 , B01J2231/44 , C07C2/62 , C07C2531/02 , C10G29/205 , C10G45/60 , C10G47/02 , C10G50/00 , C10L1/06 , C10L2270/023 , C10L2290/12 , Y02P20/584 , C07C11/16
Abstract: We provide a process for regenerating a spent acidic ionic liquid, comprising contacting the spent acidic ionic liquid with hydrogen and without an addition of a hydrogenation catalyst; wherein a conjunct polymer content is decreased in the spent acidic ionic liquid to produce regenerated acidic ionic liquid. We also provide a process for making an alkylate gasoline blending component, comprising: a) alkylating a mixture of isoparaffins and olefins using an acidic ionic liquid and an alkyl halide or a hydrogen halide, wherein a conjunct polymer accumulates in a spent acidic ionic liquid; and b) feeding the spent acidic ionic liquid and a hydrogen, and without an addition of a hydrogenation catalyst, to a regeneration reactor operated under selected hydrogenation conditions to produce a regenerated acidic ionic liquid that is used for the alkylating, wherein the conjunct polymer in the regenerated acidic ionic liquid is decreased by at least 50 wt %.
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公开(公告)号:US20170216827A1
公开(公告)日:2017-08-03
申请号:US15010168
申请日:2016-01-29
Applicant: Chevron U.S.A. Inc.
Inventor: Michael John Girgis , Huping Luo , Bong Kyu Chang , Hye-Kyung Timken , Steven Xugi Song , Michael Sean Driver
CPC classification number: B01J31/40 , B01J31/0284 , B01J35/12 , B01J38/10 , B01J2231/44 , C07C2/62 , C07C2531/02 , C10G29/205 , C10G45/60 , C10G47/02 , C10G50/00 , C10L1/06 , C10L2270/023 , C10L2290/12 , Y02P20/584 , C07C11/16
Abstract: We provide a process for regenerating a spent acidic ionic liquid, comprising contacting the spent acidic ionic liquid with hydrogen and without an addition of a hydrogenation catalyst; wherein a conjunct polymer content is decreased in the spent acidic ionic liquid to produce regenerated acidic ionic liquid. We also provide a process for making an alkylate gasoline blending component, comprising: a) alkylating a mixture of isoparaffins and olefins using an acidic ionic liquid and an alkyl halide or a hydrogen halide, wherein a conjunct polymer accumulates in a spent acidic ionic liquid; and b) feeding the spent acidic ionic liquid and a hydrogen, and without an addition of a hydrogenation catalyst, to a regeneration reactor operated under selected hydrogenation conditions to produce a regenerated acidic ionic liquid that is used for the alkylating, wherein the conjunct polymer in the regenerated acidic ionic liquid is decreased by at least 50 wt %.
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