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    RING-OPENING POLYMERIZATION METHOD AND ACTIVATED CARBON CATALYST FOR RING-OPENING POLYMERIZATION
    1.
    发明公开
    RING-OPENING POLYMERIZATION METHOD AND ACTIVATED CARBON CATALYST FOR RING-OPENING POLYMERIZATION 有权
    RINGÖFFNUNGSPOLYMERISIERUNGSVERFAHREN与活性炭催化剂的开环聚合

    公开(公告)号：EP1857485A4

    公开(公告)日：2008-12-31

    申请号：EP06712996

    申请日：2006-02-03

    Applicant: DAICEL CHEM ,  HOKOKU CORP

    Inventor： ENDO TOSHIO ,  TAGUCHI TETSURO ,  FUJIYOSHI KEIJI

    IPC: C08G65/10 ,  C08G59/68

    CPC classification number: C08G59/68 ,  B01J21/18 ,  C08G59/1455 ,  C08G65/10

    Abstract: A polyglycidol, polyglycidol alkyl ether, polyglycidol alkyl ester or the like is obtained by reacting an oxirane compound represented by the general formula (1) below such as glycidol in the presence of an activated carbon powder, if necessary, using an initiator such as a polyhydric alcohol, aliphatic alcohol or aliphatic carboxylic acid. [Chemical formula 1] (1) (In the formula, R1 and R2 may be the same as or different from each other and respectively represent an H, a branched or straight chain alkyl group having 1-30 carbon atoms, an aryl group or a functional group expressed as -CH2-M (wherein M represents an OH, F, Cl, Br or -OR3 (wherein R3 represents an alkyl group having 1-20 carbon atoms, an allyl group or an aryl group)).) By this method, an object compound can be obtained in high quality with high yield, and the catalyst can be separated easily.

    POLYGLYCEROLS, POLYGLYCEROL/FATTY ACID ESTER, AND PROCESSES FOR PRODUCING THESE
    3.
    发明公开
    POLYGLYCEROLS, POLYGLYCEROL/FATTY ACID ESTER, AND PROCESSES FOR PRODUCING THESE 有权
    多晶硅，多晶硅，多晶硅

    公开(公告)号：EP1568677A4

    公开(公告)日：2006-06-28

    申请号：EP03811954

    申请日：2003-11-28

    Applicant: DAICEL CHEM

    Inventor： ENDO TOSHIO ,  OMORI HIDETOSHI

    IPC: C07C41/03 ,  C07C43/13 ,  C07C69/33 ,  C08G65/22 ,  C08G65/28 ,  C08G65/332 ,  C08G65/34 ,  C07B61/00 ,  C07C67/08

    CPC classification number: C08G65/34 ,  C07C41/03 ,  C07C43/135 ,  C07C69/33 ,  C08G65/22 ,  C08G65/3322

    Abstract: Polyglycerols significantly reduced in the content of polyglycerols having a cyclic structure formed by the removal of a water molecule from the polyglycerol molecule; and a polyglycerol/fatty acid ester having excellent surface activity. Two moles or more of glycidol and a catalyst are gradually added to and reacted with 1 mol of glycerol to obtain polyglycerols in which the ratio of the sum of polygylcerols (1) to the sum of polyglycerols having a cyclic structure (2) is (70% or more)/(30% or less) (the total of both is 100 wt.%) in terms of intensity ratio as determined by liquid chromatography/mass spectrometry and which have an average degree of polymerization of 2 or higher. Reacting the polyglycerols with a fatty acid gives the corresponding polyglycerol/fatty acid ester.

    Abstract translation: 本发明涉及通过从聚甘油分子除去水分子形成的具有环状结构的聚甘油含量显着降低的聚甘油和具有优异表面活性的聚甘油的脂肪酸酯。 将2摩尔以上的缩水甘油和催化剂依次加入到1摩尔甘油中以进行反应，得到聚甘油，其中具有环状结构的Ätotal聚甘油（1）Ü至to总聚甘油（2）的比例为Ä70％或 根据液相色谱/质谱法确定的强度比，更多/Ä30％或更少（两者的总和是100重量％）; 平均聚合度“n”为2以上。 聚甘油与脂肪酸的反应提供了相应的聚甘油的脂肪酸酯。

    6.
    发明专利
    未知

    公开(公告)号：DE69026902D1

    公开(公告)日：1996-06-13

    申请号：DE69026902

    申请日：1990-10-11

    Applicant: DAICEL CHEM

    Inventor： ENDO TOSHIO ,  MURAI TAKAAKI ,  FUJII TATSUMI

    IPC: C08F299/02 ,  C08G18/44 ,  C08G18/81 ,  C08G64/02 ,  C08G18/67 ,  C08G18/71

    Abstract: A polycarbonate polyol composition which can be used to prepare polycarbonate(meth)acrylate and urethane(meth)acrylate compositions is obtained by the ester interchange reaction of a polycarbonate diol composition with a triol and/or tetraol. The (meth)acrylate compositions have excellent photo and electron beam curability and the cured layers prepared therefrom have excellent heat resistance under moisture conditions.

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