公开(公告)号：ID19959A

公开(公告)日：1998-08-27

申请号：ID980245

申请日：1998-02-23

Applicant: DAICEL CHEM

Inventor： NAKAI TORU ,  ASADA TAKESI

IPC: C08F2/38 ,  C08F4/00 ,  C08F4/32 ,  C08F2/00

Abstract: The present invention provides a process for producing a vinyl polymer characterized in that, in a radical polymerization of a vinyl monomer, a substituted hydroxylamine represented by a general formula: (in which R1 and R2 represent hydrogen, a (substituted) aliphatic hydrocarbon group having one or more carbon atom(s) or an aromatic hydrocarbon group) and/or a general formula: (in which R3 and R4 represent a (substituted) aliphatic hydrocarbon group having one or more carbon atom(s)) is added. A radically polymerized vinyl polymer having a high molecular weight and a restrained molecular weight distribution can be obtained by the process of the present invention, even under a polymerization condition at a high temperature. The present invention provides, therefore, a process enabling to produce vinyl polymers which promise to have practical properties such as appearance, mechanical properties and heat resistance useful as materials for various moldings and coatings. Thus, the industrial and technical value of the present invention is extremely high.

公开(公告)号：JP2010037309A

公开(公告)日：2010-02-18

申请号：JP2008205128

申请日：2008-08-08

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： NAKAI TORU ,  ITAYA AKIRA

IPC: C07D263/56 ,  C07B61/00

Abstract: PROBLEM TO BE SOLVED: To provide a method for industrially efficiently preparing a low-colored aminoaryl aminobenzazole compound with few steps and within a short time. SOLUTION: The method for preparing the aminoaryl aminobenzazole compound of formula (2) (wherein Ar 1 and Ar 2 are identical to or different from each other and are each a benzene ring or the like; and X is NH or the like) comprises reducing a nitroaryl nitrobenzazole compound of formula (1) (wherein Ar 1 , Ar 2 and X are as defined above) in the presence of an adsorbent, which is preferably activated carbon. COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 待解决的问题：提供一种在几小时内在短时间内工业上有效制备低色氨基芳基氨基苯甲腈化合物的方法。 解决方案：制备式（2）的氨基芳基氨基苯唑化合物（其中Ar 1 和Ar 2 的方法彼此相同或不同，各自 苯环等; X是NH等）包括还原式（1）的硝基芳基硝基吲唑化合物（其中Ar 1 ，Ar 2 ，X是 如上所述）在吸附剂存在下，其优选为活性炭。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：JP2008120690A

公开(公告)日：2008-05-29

申请号：JP2006302747

申请日：2006-11-08

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： SATO YASUSHI ,  NAKAI TORU ,  INOUE KEIZO

IPC: C07D317/20 ,  C07D317/22

Abstract: PROBLEM TO BE SOLVED: To provide a method for obtaining a fluorosulfonyl group- and hydroxy group-bearing cyclic acetal compound, which corresponds to a dehydration reaction product of a fluorosulfonyl group-bearing vicinal diol with a hydroxy group-bearing carbonyl compound, as a product containing no acids in a high yield by a simple operation.
SOLUTION: The manufacturing method of the fluorosulfonyl group- and hydroxy group-bearing cyclic acetal compound, which corresponds to a dehydration reaction product of a fluorosulfonyl group-bearing vicinal diol with a hydroxy group-bearing carbonyl compound, comprises a step for treating a crude cyclic acetal compound containing an acid with a base under a dehydrating condition. The hydroxy group-bearing carbonyl compound includes an α-hydroxycarbonyl compound.
COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 待解决的问题：提供一种获得含氟磺酰基和羟基的环状缩醛化合物的方法，其对应于含氟磺酰基的连二醇与含羟基的羰基化合物的脱水反应产物 作为通过简单的操作以高产率不含酸的产物。 解决方案：具有含氟磺酰基的连二醇与含羟基的羰基化合物的脱水反应产物相应的含氟磺酰基和羟基的环状缩醛化合物的制备方法包括： 在脱水条件下用碱处理含有酸的粗环状缩醛化合物。 含羟基的羰基化合物包括α-羟基羰基化合物。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2005298295A

公开(公告)日：2005-10-27

申请号：JP2004119538

申请日：2004-04-14

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： YOKONO TERUHISA ,  NAKAI TORU

IPC: C01G23/047

Abstract: PROBLEM TO BE SOLVED: To provide an easy, industrially efficient method for obtaining titanium oxide comprising a single crystal form from a mixture of titanium oxides with different crystal forms.
SOLUTION: In the method for refining the titanium oxide, the titanium oxide comprising the single crystal form is obtained by subjecting the mixture of titanium oxides with different crystal forms to a treatment with an alkaline hydrogen peroxide solution or sulfuric acid. The refining method includes methods for obtaining anatase type titanium oxide and rutile type titanium oxide by subjecting a mixture of anatase type titanium oxide and rutile type titanium oxide to treatment with the alkaline hydrogen peroxide solution and sulfuric acid, respectively.
COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供一种用于从具有不同晶体形式的氧化钛的混合物中获得包含单晶形式的氧化钛的简单且工业上有效的方法。 解决方案：在用于精制氧化钛的方法中，包含单晶形式的氧化钛是通过使具有不同晶体形式的氧化钛的混合物用碱性过氧化氢溶液或硫酸处理而获得的。 精炼方法包括通过使锐钛矿型氧化钛和金红石型氧化钛的混合物分别用碱性过氧化氢溶液和硫酸处理来获得锐钛矿型氧化钛和金红石型氧化钛的方法。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2005232137A

公开(公告)日：2005-09-02

申请号：JP2004046917

申请日：2004-02-23

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： NAKAI YASUTO ,  NAKAI TORU

IPC: C07C205/22 ,  C07C215/76

CPC classification number: Y02P20/55

Abstract: PROBLEM TO BE SOLVED: To provide a new crosslinkable ring-bearing nitro- or amino-phenol that is useful as a starting monomer or intermediate for more high heat-resistant and high functional polymer. SOLUTION: The crosslinkable ring-bearing nitro- or amino-phenol is represented by formula (1) (wherein ring A is a crosslinkable hydrocarbon ring which may be substituted, Ar is an aromatic ring group which may be substituted, X is nitro or amino group which may protected with a protecting group, n is an integer of 0 through 3, the hydroxy groups in the formula may be protected with a protecting group; the compound that has X groups bonding to individual Ars on the ortho position of the hydroxy groups is particularly preferred. Further, the compound where individual Ars bonding to the carbon atoms on the bridge head of the ring A is preferred). COPYRIGHT: (C)2005,JPO&NCIPI

Abstract translation: 要解决的问题：提供可用作起始单体或更高耐热和高功能聚合物的中间体的新型可交联环状硝基或氨基苯酚。 ＆lt; P＆gt;解决方案：可交联的含环氧基的硝基或氨基苯酚由式（1）表示（其中环A是可被取代的可交联的烃环，Ar是可被取代的芳环基团，X是 可以用保护基保护的硝基或氨基，n是0〜3的整数，式中的羟基可以被保护基保护;具有X基团的化合物与个体的Ar相邻， 特别优选羟基，此外，优选与环A的桥头上的碳原子结合的单个Ar的化合物）。 版权所有（C）2005，JPO＆NCIPI

公开(公告)号：JP2003081940A

公开(公告)日：2003-03-19

申请号：JP2001269136

申请日：2001-09-05

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： NAKAI TORU

IPC: C07C407/00 ,  C07B61/00 ,  C07C51/367 ,  C07C62/32 ,  C07C409/08 ,  C07C409/14

CPC classification number: Y02P20/55

Abstract: PROBLEM TO BE SOLVED: To obtain a condensed cyclic hydroperoxide or condensed cyclic alcohol in high selectivity from the corresponding condensed cyclic compound including an aromatic ring-condensed cycloalkane ring. SOLUTION: This condensed cyclic hydroperoxide where a hydroperoxy group is bound to one of the carbon atoms composing the cycloalkane ring is obtained by oxidizing with oxygen the corresponding condensed cyclic compound including the aromatic ring-condensed cycloalkane ring in the presence of an imide compound having a cyclic imido skeleton of formula (I) [where, X is an oxygen atom or OR group (R is H or a hydroxyl-protecting group)] and in the absence of any cobalt compound. The other condensed cyclic alcohol is obtained by reduction of the thus obtained condensed cyclic hydroperoxide.

Abstract translation: 待解决的问题：从包括芳族环稠合环烷烃环的相应稠合环状化合物以高选择性获得缩合环状氢过氧化物或缩合环状醇。 解决方案：通过在具有芳环稠合环烷烃环的酰亚胺化合物存在下，用氧气氧化相应的稠合环状化合物，得到氢过氧基与其中一个构成环烷烃环的一个碳原子结合的稠合环状氢过氧化物 式（I）的环状酰亚胺骨架[其中，X为氧原子或OR基（R为H或羟基保护基）]和不存在任何钴化合物。 通过还原所得的缩合环状氢过氧化物可以得到其它的缩合环状醇。

公开(公告)号：JP2003064067A

公开(公告)日：2003-03-05

申请号：JP2001257170

申请日：2001-08-28

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： SATO YASUSHI ,  NAKAI TORU

IPC: C07D301/06 ,  B01J31/38 ,  C07D303/04

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing an epoxy compound, by which the epoxy compound can efficiently be produced from the corresponding olefin in a simple operation under mild conditions.
SOLUTION: This method for producing the epoxy compound is characterized by oxidizing the corresponding olefin with molecular oxygen in the presence of an oxidation catalyst comprising titanium dioxide and an imide compound represented by formula (1) (R
1 and R
2 are each identically or differently H, a halogen atom, an alkyl or the like; R
1 and R
2 may be bound to each other to form a double bond, an aromatic ring, a non-aromatic ring, or the like; X is O or OH) and a primary or secondary alcohol. The titanium dioxide preferably contains at least anatase type titanium dioxide.
COPYRIGHT: (C)2003,JPO

Abstract translation: 要解决的问题：为了提供环氧化合物的制备方法，通过其可以在温和条件下的简单操作中由相应的烯烃有效地制备环氧化合物。 解决方案：该制备环氧化合物的方法的特征在于在包含二氧化钛和由式（1）表示的酰亚胺化合物的氧化催化剂存在下用分子氧氧化相应的烯烃（R 1和R 2是 各自相同或不同的H，卤素原子，烷基等; R 1和R 2可以彼此结合形成双键，芳香环，非芳香环等 ; X为O或OH）和伯醇或仲醇。 二氧化钛优选含有至少锐钛矿型二氧化钛。

公开(公告)号：JP2001261975A

公开(公告)日：2001-09-26

申请号：JP2000074107

申请日：2000-03-16

Applicant: DAICEL CHEM

Inventor： WAKITA NAOKI ,  NAKAI TORU

IPC: C08J3/20 ,  C08K3/08 ,  C08K7/04 ,  C08K7/06 ,  C08K7/14 ,  C08K9/02 ,  C08K9/04 ,  C08L101/00 ,  H01B1/22 ,  H01B1/24

Abstract: PROBLEM TO BE SOLVED: To obtain an electroconductive thermoplastic resin composition capable of providing a molded product excellent in electromagnetic wave shielding properties. SOLUTION: This electroconductive thermoplastic resin composition comprises (A) a thermoplastic resin, (B-1) electroconductive long fibers having 4-20 μm diameter and 4-30 mm length and (B-2) electroconductive staple fibers having 30-100 μm diameter and 1-5 mm length.

公开(公告)号：JPH09216978A

公开(公告)日：1997-08-19

申请号：JP2263996

申请日：1996-02-08

Applicant: DAICEL CHEM

Inventor： NAKAI TORU

IPC: C08L9/00 ,  C08F279/00 ,  C08F279/06 ,  C08L7/00 ,  C08L21/00 ,  C08L25/04 ,  C08L33/04 ,  C08L33/06 ,  C08L51/04

Abstract: PROBLEM TO BE SOLVED: To obtain a rubber-modified styrene resin composition excellent in the balance among strength, transparency and moldability. SOLUTION: This composition is a rubber-modified styrene resin composition wherein the continuous phase is a styrene copolymer (A) comprising 30-80wt.% styrene monomer component and 70-20wt.% at least either (meth)acrylic acid or an alkyl ester thereof and the disperse phase is a rubbery polymer (B) comprising 10-60wt.% styrene polymer and 90-40wt.% butadiene polymer in a weight ratio (A/B) of 98/2 to 70/30. The total weight of low-molecular-weight compounds having a weight-average molecular weight (in terms of polystyrene) as measured by gel permeation chromatography is 2.0% or below.

公开(公告)号：JP2008120692A

公开(公告)日：2008-05-29

申请号：JP2006302749

申请日：2006-11-08

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： SATO YASUSHI ,  MIZUSHIMA TAKAHIRO ,  NAKAI TORU ,  INOUE KEIZO

IPC: C07D301/12 ,  C07D303/34

Abstract: PROBLEM TO BE SOLVED: To provide a method for safely and industrially efficiently manufacturing in a high yield an epoxy compound bearing a halosulfonyl group from an unsaturated compound bearing a halosulfonyl group (sulfohalide group).
SOLUTION: The manufacturing method of the epoxy compound bearing a halosulfonyl group comprises oxidizing an unsaturated compound bearing a halosulfonyl group represented by formula (1) with an oxidizing agent to give the epoxy compound bearing a halosulfonyl group represented by formula (2), where the method comprises a step for subjecting the oxidizing agent remaining after oxidation of the unsaturated compound bearing a halosulfonyl compound with the oxidizing agent to a reduction treatment under a condition of pH of 9 or lower. In formula (1), A is an optionally substituted alkylene group or a bivalent group consisting of a plurality of optionally substituted alkylene groups each bonded via a linking group; R
1 -R
3 are each a hydrogen atom or an optionally substituted alkyl group; and X is a halogen atom.
COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 要解决的问题：提供一种从具有卤磺酰基（磺基卤化物基团）的不饱和化合物中以高产率安全和工业上有效地制备含有卤代磺酰基的环氧化合物的方法。 解决方案：具有卤代磺酰基的环氧化合物的制造方法包括用氧化剂氧化由式（1）表示的具有卤代磺酰基的不饱和化合物，得到带有由式（2）表示的卤代磺酰基的环氧化合物， 其中该方法包括在pH为9或更低的条件下使带有卤代磺酰基化合物的不饱和化合物在氧化后残留的氧化剂与氧化剂进行还原处理的步骤。 在式（1）中，A是任选取代的亚烷基或由多个任选取代的亚烷基组成的二价基团，各自通过连接基团键合; R 1〜R 3各自为氢原子或任选取代的烷基; X为卤素原子。 版权所有（C）2008，JPO＆INPIT