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公开(公告)号：JP2006312633A
公开(公告)日：2006-11-16
申请号：JP2006128431
申请日：2006-05-02
Applicant: Degussa Ag , デグサ アクチエンゲゼルシャフトDegussa AG
Inventor： KORTH KARSTEN , WOLF DORIT , SEEBALD STEFFEN DR , ALBERT PHILIPP , PIETER REIMUND , ALIG ALFRED
IPC: C07F7/08 , B01J23/62 , B01J23/652 , B01J23/755 , B01J27/02 , C07B61/00
CPC classification number: C07F7/1892
Abstract: PROBLEM TO BE SOLVED: To provide a method for reductively cleaving a bis(alkoxysilylorganyl)polysulfide, achieving at least an equivalent conversion rate under a more moderate temperature and/or pressure condition as compared with those of publicly known methods. SOLUTION: This method for producing a mercaptoorganyl(alkoxysilane) by hydrogenating the bis(alkoxysilylorganyl)polysulfide with hydrogen in the presence of at least 1 kind of an alcohol and a doped metal catalyst is characterized by using the doped metal catalyst containing at least 1 kind of a substance consisting of a group of iron, an iron compound, nickel, a nickel compound, platinum, a platinum compound, osmium, an osmium compound, ruthenium, a ruthenium compound, rhodium, a rhodium compound, iridium and an iridium compound and at least 1 kind of a doping component. COPYRIGHT: (C)2007,JPO&INPIT
Abstract translation: 要解决的问题：提供一种还原性裂解双（烷氧基甲硅烷基有机基）多硫化物的方法，与公知的方法相比，在更温和的温度和/或压力条件下达到至少等效的转化率。 解决方案：通过在至少1种醇和掺杂金属催化剂的存在下用氢气氢化双（烷氧基甲硅烷基有机基）多硫化物来制备巯基有机基（烷氧基硅烷）的方法的特征在于使用含有 至少1种由一组铁，铁化合物，镍，镍化合物，铂，铂化合物，锇，锇化合物，钌，钌化合物，铑，铑化合物，铱和铱组成的物质 铱化合物和至少1种掺杂成分。 版权所有（C）2007，JPO＆INPIT
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公开(公告)号：JP2007045823A
公开(公告)日：2007-02-22
申请号：JP2006214819
申请日：2006-08-07
Applicant: Degussa Ag , デグサ アクチエンゲゼルシャフトDegussa AG
Inventor： FRINGS ALBERT , JANSSENS LOUIS , LOTTER STEFAN , DESCHLER ULRICH , ALIG ALFRED
IPC: C07F7/18
CPC classification number: C07F7/1892
Abstract: PROBLEM TO BE SOLVED: To provide a process with which a mixture composed of an organosilicon compound and a solid can simply and inexpensively be post-treated. SOLUTION: The process for preparing the organosilicon compound represented by general formula (I): (R 1 R 2 R 3 SiR 4 ) 2 S x is carried out as follows. A halogenated alkoxysilane represented by general formula (II): R 1 R 2 R 3 SiR 4 X is reacted with an anhydrous polysulfide represented by general formula (III): M 2 S z and/or an anhydrous sulfide represented by general formula (IV): M 2 S and, as necessary, sulfur in an organic solvent. In the method, the organic solvent is separated from the resultant suspension and the obtained mixture containing the organosilicon compound represented by general formula (I) and a solid MX is then mixed with water containing at least one buffer to separate the formed phase. COPYRIGHT: (C)2007,JPO&INPIT
Abstract translation: 要解决的问题：提供一种由有机硅化合物和固体组成的混合物可以简单且廉价地进行后处理的方法。 解决方案：制备由通式（I）表示的有机硅化合物的方法：（R 1 SP 3 R 2） SP> 4 ）
2 S x 如下进行。 由通式（II）表示的卤代烷氧基硅烷：R 1和R 2相同，R 1， 与由通式（III）表示的无水多硫化物：和/或由通式（IV）表示的无水硫化物：M＆lt; SB＆gt; 2＆ / SB> S，根据需要在有机溶剂中含硫。 在该方法中，从得到的悬浮液中分离有机溶剂，然后将所得到的含有通式（I）表示的有机硅化合物和固体MX的混合物与含有至少一种缓冲液的水混合以分离形成的相。 版权所有（C）2007，JPO＆INPIT -
公开(公告)号：JP2010037340A
公开(公告)日：2010-02-18
申请号：JP2009177297
申请日：2009-07-30
Applicant: Evonik Degussa Gmbh , エボニック デグサ ゲーエムベーハーEvonik Degussa GmbH
Inventor： KORTH KARSTEN , KIEFER INGO , ALIG ALFRED , DESCHLER ULRICH , DROEGE HELMUT , KOENIGSTEIN STEFAN , SCHWAN STEPHANIE
IPC: C07F7/18
CPC classification number: C07F7/1892
Abstract: PROBLEM TO BE SOLVED: To provide a method for producing an organosilane of polysulfide, which method enables a high conversion rate in the case of good selectivity, makes unnecessary the use of a solid alkali metal sulfide hydrate, and allows an alkali metal hydroxide in a sulfuration source material.
SOLUTION: The method for producing an organosilane represented by general formula I includes reacting a (halogenated organyl)alkoxysilane represented by formula II with a water-containing alkali metal hydrogen sulfide, sulfur, and an alkali metal carbonate in an alcohol. In this method, the molar ratio of the (halogenated organyl)alkoxysilane represented by formula II to the alkali metal hydrogen sulfide is 1:0.40 to 1:0.75 and the molar ratio of the alkali metal hydrogen sulfide to the alkali metal carbonate is 1:0.5 to 1:1.5.
COPYRIGHT: (C)2010,JPO&INPITAbstract translation: 待解决的问题：为了提供一种生产多硫化物的有机硅烷的方法，该方法能够在选择性好的情况下实现高转化率，不需要使用固体碱金属硫化物水合物，并且允许碱金属 硫化源材料中的氢氧化物。 解决方案：由通式I表示的有机硅烷的制备方法包括使式II表示的（卤代有机基）烷氧基硅烷与含醇的碱金属硫化氢，硫和碱金属碳酸盐在醇中反应。 在该方法中，由式II表示的（卤代有机基）烷氧基硅烷与碱金属硫化氢的摩尔比为1:0.4〜1:0.75，碱金属硫化氢与碱金属碳酸盐的摩尔比为1： 0.5至1：1.5。 版权所有（C）2010，JPO＆INPIT
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公开(公告)号：JP2006077009A
公开(公告)日：2006-03-23
申请号：JP2005259002
申请日：2005-09-07
Applicant: Degussa Ag , デグサ アクチエンゲゼルシャフト
Inventor： KORTH KARSTEN , ALBERT PHILIPP , WOLF DORIT , SEEBALD STEFFEN DR , PIETER REIMUND , ALIG ALFRED
IPC: C07F7/18
CPC classification number: C07F7/1892
Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a mercaptorganyl(alkoxysilane) in high conversion through reductively splitting the corresponding bis(alkoxysilylorganyl) polysulfide without using any further antipoisening reagent such as water, an alcohol or hydrogen sulfide for a necessary metal catalyst. SOLUTION: The method for producing the mercaptorganyl(alkoxysilane) comprises hydrogenating the corresponding bis(alkoxysilylorganyl) polysulfide in the presence of a metal catalyst in a solvent at a temperature lower than 190°C under a pressure lower than 100 bar without addition of water, an alcohol or hydrogen sulfide. COPYRIGHT: (C)2006,JPO&NCIPI
Abstract translation: 要解决的问题：提供通过将相应的双（烷氧基甲硅烷基有机基）多硫化物还原分解而不使用任何进一步的反分解试剂如水，醇或硫化氢来进行高转化率制备巯基有机基（烷氧基硅烷）的方法，用于必要的 金属催化剂 解决方案：制备巯基有机基（烷氧基硅烷）的方法包括在金属催化剂存在下，在溶剂中，在不低于100巴的压力下，在低于190℃的温度下，在溶剂中氢化相应的双（烷氧基甲硅烷基有机基）多硫化物， 的水，酒精或硫化氢。 版权所有（C）2006，JPO＆NCIPI
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公开(公告)号：JP2002155092A
公开(公告)日：2002-05-28
申请号：JP2001212567
申请日：2001-07-12
Applicant: DEGUSSA
Inventor： ALIG ALFRED , BATZ-SOHN CHRISTOPH DR , DESCHLER ULRICH , MICHEL RUDOLF , MUNZENBERG JORG , SONNENSCHEIN RAYMUND DR , WILL WERNER , ZEZULK GERD RAINHARD , RUTZEIL KARL-HEINZ
Abstract: PROBLEM TO BE SOLVED: To provide one more method for producing an organosilylalkylpolysulfane with causing only a small amount of by-product to be abandoned. SOLUTION: This method for producing an organosilylalkylpolysulfane is characterized in that in a method for producing an organosilylalkylpolysulfane represented by general formula I (R1R2R3SiR4)2Sx (I), an organosilylalkylpolysulfane represented by general formula II (R1R2R3SiR4)2Sy (II) is reacted with an ionic sulfide represented by general formula III M+2S2- (III) and an organosilylalkyl halide represented by general formula (IV) R1R2 R3SiR4X (IV), the long-chain organosilylalkylpolysulfane represented by general formula II and the organosilylalkyl halide represented by general formula (IV) are initially introduced into the reaction vessel and the ionic sulfide represented by general formula III is added to the solution in several portions.
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Patent Agency Ranking
公开(公告)号：JP2006077008A
公开(公告)日：2006-03-23
申请号：JP2005259001
申请日：2005-09-07
Applicant: Degussa Ag , デグサ アクチエンゲゼルシャフト
Inventor： KORTH KARSTEN , ALBERT PHILIPP , WOLF DORIT , SEEBALD STEFFEN DR , PIETER REIMUND , ALIG ALFRED
IPC: C07F7/18
CPC classification number: C07F7/1892
Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a mercaptorganyl(alkoxysilane) in high conversion through reductively splitting the corresponding bis(alkoxysilylorganyl) polysulfide without using any further antipoisening reagent such as water, an alcohol or hydrogen sulfide for a necessary metal catalyst. SOLUTION: The method for producing the mercaptorganyl(alkoxysilane) comprises hydrogenating the corresponding bis(alkoxysilylorganyl) polysulfide in the presence of a metal catalyst at a temperature lower than 190°C under a pressure lower than 100 bar without addition of water, an alcohol or hydrogen sulfide. COPYRIGHT: (C)2006,JPO&NCIPI
Abstract translation: 要解决的问题：提供通过将相应的双（烷氧基甲硅烷基有机基）多硫化物还原分解而不使用任何进一步的反分解试剂如水，醇或硫化氢来进行高转化率制备巯基有机基（烷氧基硅烷）的方法，用于必要的 金属催化剂。 解决方案：制备巯基有机基（烷氧基硅烷）的方法包括在低于100巴的压力低于100巴的温度下，在金属催化剂存在下，在不加水的情况下，氢化相应的双（烷氧基甲硅烷基有机基）多硫化物， 酒精或硫化氢。 版权所有（C）2006，JPO＆NCIPI
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公开(公告)号：JP2004182594A
公开(公告)日：2004-07-02
申请号：JP2003404969
申请日：2003-12-03
Applicant: Degussa Ag , デグサ アクチエンゲゼルシャフト
Inventor： ALT CHRISTIAN HANS , GOELZ ANDREAS , ALIG ALFRED
CPC classification number: B01J2/16 , C01B17/38 , C01P2004/50 , C01P2004/60
Abstract: PROBLEM TO BE SOLVED: To provide a method for preparing an anhydrous alkali metal sulfide which forms a particulate product and no dust and performs better heat exchange or matter exchange compared to that in conventional methods.
SOLUTION: In the preparation method for the anhydrous alkali metal sulfide, a hydrated alkali metal sulfide is dried through fluidized bed spray granulation.
COPYRIGHT: (C)2004,JPO&NCIPI-
公开(公告)号：JP2004182592A
公开(公告)日：2004-07-02
申请号：JP2003404689
申请日：2003-12-03
Applicant: Degussa Ag , デグサ アクチエンゲゼルシャフト
Inventor： ALT CHRISTIAN HANS , GOELZ ANDREAS , ALIG ALFRED
CPC classification number: C01B17/38 , B01J2/04 , C01P2004/50 , C01P2004/60
Abstract: PROBLEM TO BE SOLVED: To provide a method for preparing an anhydrous alkali metal sulfide.
SOLUTION: A solution, a suspension or a dispersion of the alkali metal sulfide or its melt in its water of crystallization is dried through spray drying using a steam-loaded inert dry gas.
COPYRIGHT: (C)2004,JPO&NCIPIAbstract translation: 待解决的问题：提供一种制备无水碱金属硫化物的方法。 解决方案：使用蒸汽负载的惰性干燥气体通过喷雾干燥将碱金属硫化物或其熔体在其结晶水中的溶液，悬浮液或分散体干燥。 版权所有（C）2004，JPO＆NCIPI
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公开(公告)号：AT523516T
公开(公告)日：2011-09-15
申请号：AT09166242
申请日：2009-07-23
Applicant: EVONIK DEGUSSA GMBH
Inventor： KORTH KARSTEN , KIEFER INGO , ALIG ALFRED , DESCHLER ULRICH , DROEGE HELMUT , KOENIGSTEIN STEFAN , SCHWAN STEPHANIE
IPC: C07F7/18
Abstract: Preparation of organosilanes (I), comprises reacting (halogenoorganyl)alkoxysilane (II) with aqueous alkaline hydrogen sulfide, sulfur and alkali-carbonate in alcohol, where the molar ratio of (halogenoorganyl)alkoxysilane to alkaline hydrogen sulfide is 1:0.4 to 1:0.75 and the molar ratio of alkali-carbonate to alkaline hydrogen sulfide is 1:0.5 to 1:1.5. Preparation of organosilanes of formula ([((R) 2)(R 1>-O)Si-R 2>)] 2-S m) (I), comprises reacting (halogenoorganyl)alkoxysilane of formula ([((R) 2)(R 1>-O)Si-R 2>)]-X) (II) with aqueous alkaline hydrogen sulfide, sulfur and alkali-carbonate in alcohol, where the molar ratio of (halogenoorganyl)alkoxysilane to alkaline hydrogen sulfide is 1:0.4 to 1:0.75 and the molar ratio of alkali-carbonate to alkaline hydrogen sulfide is 1:0.5 to 1:1.5. R : 1-8C alkyl, 1-8C alkenyl, 1-8C aryl, 1-8C aralkyl or OR 1>; R 1>H, 1-24C monovalent alkyl or alkenyl, aryl, aralkyl, alkyl ether (-(C(R 3>) 2) y 1>-O-R 4>) or alkyl polyether (-C(R 3>) 2O) y 2>-R 4> or -(C(R 3>) 2-C(R 3>) 2-O) y 2>-R 4>); y 1>1-20; y 2>2-20; R 3>H or alkyl; R 4>optionally saturated, aromatic or mixed aliphatic/aromatic monovalent 1-30C hydrocarbon; R 2>optionally saturated aliphatic, aromatic or mixed aliphatic/aromatic divalent 1-30C hydrocarbon, which is optionally substituted with F, Cl, Br, I, SH, NH 2 or NHR 1>; m : average sulfur chain length of 1.5-4.5; and X : Cl, Br, F or I.
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公开(公告)号：AT423125T
公开(公告)日：2009-03-15
申请号：AT06117189
申请日：2006-07-14
Applicant: EVONIK DEGUSSA GMBH
Inventor： FRINGS ALBERT , JANSSENS LOUIS , LOTTER STEFAN , DESCHLER ULRICH , ALIG ALFRED
IPC: C07F7/18
Abstract: Preparation of organosilicon compound (I) comprises reacting halogenalkoxysilane (II) with a dry polysulfide (III) dry sulfide (IV) and optionally a sulfur in an organic solvent; removing the mixture containing (I) and the solid material with water containing at least a buffer from the organic solvent and separating the binding phase. Preparation of organosilicon compound (I) of formula ((R 1>R 2>R 3>SiR 4>) 2S x) comprises reacting halogenalkoxysilane compound (II) of formula (R 1>R 2>R 3>SiR 4>X) with a dry polysulfide compound (III) of formula (M 2S z) dry sulfide (IV) of formula (M 2S) and optionally a sulfur in an organic solvent; removing the mixture containing (I) and the solid material (MX) with water containing at least a buffer from the organic solvent and separating the binding phase. R 1>-R 3>alkyl, alkoxy (preferred) or aryl; R 4>1-30C-aliphatic/aromatic hydrocarbon; x : greater than 1; X : halogen atom; M : alkali cation, an ammonium or semi alkaline earth or zinc cation; and z : 2-8.
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