公开(公告)号：JP2003081930A

公开(公告)日：2003-03-19

申请号：JP2002249578

申请日：2002-08-28

Applicant: Degussa Ag ,  デグサ アクチエンゲゼルシャフト

Inventor： ROOS MARTIN ,  THIELE GEORGE FRIEDRICH ,  KRISSMANN JOERG ,  STEVERMUER GUNTER ,  PETER ERNST ESSER ,  THOMAS SCHIFFER

IPC: C07B61/00 ,  C07C249/08 ,  C07C249/14 ,  C07C251/44

CPC classification number: C07C249/14 ,  C07C2601/18 ,  C07C2601/20 ,  C07C251/44

Abstract: PROBLEM TO BE SOLVED: To develop a continuous aftertreatment method for oximization of a ketone such as a cycloalkane containing advantageously 8-20 carbon atoms, with which a catalyst is separated after the reaction, an oxime is separated from a reaction mixture, reaction water is separated from a solvent, a remaining alcohol is returned and in the operation, a product does not precipitate as a solid during the aftertreatment process.
SOLUTION: A three component solvent system which comprises firstly one or a plurality of organic liquids perfectly or excellently miscible with water, for example, particularly an alcohol or an organic solvent partially miscible with water and an alcohol and has a boiling point higher than those of water and the alcohol is used. The miscibility gap of the three component solvent system by fluctuation of water content is utilized for extraction.
COPYRIGHT: (C)2003,JPO

Abstract translation: 要解决的问题：为了开发一种连续的后处理方法，用于使含有有利地8-20个碳原子的环烷烃的酮的肟化反应，在反应后分离出催化剂，将肟与反应混合物分离，反应水为 与溶剂分离，返回剩余的醇，并且在操作中，产物在后处理过程中不会以固体形式沉淀。 解决方案：三组分溶剂系统，其包括与水完全或优异混溶的第一种或多种有机液体，例如特别是与水和醇部分混溶的醇或有机溶剂，并且沸点高于 使用水和酒精。 采用三组分溶剂体系通过含水量波动的混合间隙进行萃取。

公开(公告)号：JP2000212106A

公开(公告)日：2000-08-02

申请号：JP2000014850

申请日：2000-01-24

Applicant: DEGUSSA

Inventor： PETER ERNST ESSER ,  THOMAS SCHIFFER ,  GUENZEL BERND DR ,  OENBRINK GEORG

IPC: B01J31/26 ,  C07B61/00 ,  C07C27/12 ,  C07C29/52 ,  C07C35/02 ,  C07C35/20 ,  C07C35/205 ,  C07C45/33 ,  C07C49/29 ,  C07C49/385 ,  C07C49/413

Abstract: PROBLEM TO BE SOLVED: To provide a production process for cyclic alcohols and cyclic ketones of 7-16 carbon atoms. SOLUTION: A cycloalkane of 7-16 carbon atoms is oxidized with an oxygen- containing gas in the presence of a slightly soluble transition metal catalyst in the group of 6-12 of the periodic table (for example, a transition metal complex, a transition metal complex salt or transition metal salt, particularly a transition metal phthalocyanine of substituted transition metal phthalocyanine) in the presence of a boron compound, particularly an acid of boron.

公开(公告)号：JP2003176259A

公开(公告)日：2003-06-24

申请号：JP2002249051

申请日：2002-08-28

Applicant: DEGUSSA

Inventor： ROOS MARTIN ,  THIELE GEORG FRIEDRICH ,  STEVERMUER GUNTER ,  KUPPINGER FRANZ-FELIX DR ,  PETER ERNST ESSER ,  THOMAS SCHIFFER

IPC: B01D9/02 ,  B01D61/36 ,  B01D71/28 ,  B01D71/40 ,  B01D71/70 ,  C07C249/08 ,  C07C249/14 ,  C07C251/44 ,  C07C251/48

Abstract: PROBLEM TO BE SOLVED: To provide a method for a post treatment of a reaction mixture formed by performing an ammoxime formation of a ketone with hydrogen peroxide and ammonia by using a catalyst containing titanium in a homogeneous solution, including the separation of the catalyst, selective separation of an oxime formed in the ammoxime formation, sending out of the reaction water and return of a solvent as partial processes. SOLUTION: This post treating process has at least one membrane separation process. It is possible to perform the reaction even if the reaction ratio of the ketone is insufficient or even in the presence of a dissolved salt. COPYRIGHT: (C)2003,JPO