公开(公告)号：WO1997014674A1

公开(公告)日：1997-04-24

申请号：PCT/US1996016436

申请日：1996-10-16

Applicant: DENTSPLY INTERNATIONAL INC.

Inventor： DENTSPLY INTERNATIONAL INC. ,  KLEE, Joachem, E. ,  FREY, Holger ,  HOLTER, Dirk ,  MULHAUPT, Rolf

IPC: C07C255/54

CPC classification number: A61K6/0017 ,  A61K6/0023 ,  A61K6/0038 ,  A61K6/083 ,  A61K6/09 ,  C07C69/712 ,  C07C255/54 ,  C08F290/06 ,  C08F290/061 ,  C08F290/064 ,  C08G18/835 ,  C08G59/10 ,  C08G59/12 ,  C08G59/1466 ,  C08G59/1494 ,  C08G59/4292 ,  C08G63/52 ,  C08G2270/00 ,  C08L67/07 ,  C09K19/2028 ,  C09K19/3068 ,  C09K2019/0448 ,  C08L33/00 ,  C08L75/16 ,  C08L43/02

Abstract: Liquid crystalline (meth)acrylates of the invention include at least three rigid rod-like moieties. One of these moieties is comprised between the (meth)acrylate rests and further two moieties are bonded as side chains. The liquid crystalline (meth)acrylates polymerizable using redox initiators and/or photo intiators. The (meth)acrylates of the invention polymerize quantitative and with very low volume shrinkage of less than 2.5 percent. The invention provides a polymerizable compound within the scope of general formula (I). These compounds are used in dental compositions and methods of use thereof.

Abstract translation: 本发明的液晶（甲基）丙烯酸酯包括至少三个刚性的棒状部分。 这些部分之一包含在（甲基）丙烯酸酯基之间，另外两个部分作为侧链键合。 使用氧化还原引发剂和/或光引发剂可聚合的液晶（甲基）丙烯酸酯。 本发明的（甲基）丙烯酸酯聚合定量且具有小于2.5％的非常低的体积收缩率。 本发明提供在通式（I）的范围内的可聚合化合物。 这些化合物用于牙科用组合物及其使用方法中。

公开(公告)号：EP0861230B1

公开(公告)日：2002-01-02

申请号：EP96936465.2

申请日：1996-10-16

Applicant: DENTSPLY INTERNATIONAL, INC.

Inventor： KLEE, Joachim, E. ,  FREY, Holger ,  HOLTER, Dirk ,  MULHAUPT, Rolf

IPC: C07C255/54 ,  C09K19/20 ,  A61K6/083 ,  C07C69/708 ,  C09K19/30

CPC classification number: A61K6/0017 ,  A61K6/0023 ,  A61K6/0038 ,  A61K6/083 ,  A61K6/09 ,  C07C69/712 ,  C07C255/54 ,  C08F290/06 ,  C08F290/061 ,  C08F290/064 ,  C08G18/835 ,  C08G59/10 ,  C08G59/12 ,  C08G59/1466 ,  C08G59/1494 ,  C08G59/4292 ,  C08G63/52 ,  C08G2270/00 ,  C08L67/07 ,  C09K19/2028 ,  C09K19/3068 ,  C09K2019/0448 ,  C08L33/00 ,  C08L75/16 ,  C08L43/02

公开(公告)号：EP0967955A1

公开(公告)日：2000-01-05

申请号：EP98906494.4

申请日：1998-02-18

Applicant: DENTSPLY INTERNATIONAL, INC.

Inventor： KLEE, Joachim, E. ,  WALZ, Uwe ,  HOLTER, Dirk ,  BURGATH, Armin ,  FREY, Holger ,  MULHAUPT, Rolf

IPC: A61K6/083 ,  A61K6/087

CPC classification number: A61K6/083 ,  A61K6/087 ,  C08L63/00 ,  C08L33/00

Abstract: The invention describes a low shrinking polymerizable dental material, comprising a mixture of a polymerizable resin, a polymerizable monomer, a polymerization initiator and/or sensibilizer and a filler in a content of about 20 to about 85 percent. The volumetric shrinkage during polymerization is less than about 1.5 Vol.-%due to its rheopex behavior.

公开(公告)号：EP0861230A1

公开(公告)日：1998-09-02

申请号：EP96936465.0

申请日：1996-10-16

Applicant: DENTSPLY INTERNATIONAL, INC.

Inventor： KLEE, Joachem, E. ,  FREY, Holger ,  HOLTER, Dirk ,  MULHAUPT, Rolf

IPC: G02F1 ,  A61K6 ,  C07C69 ,  C07C255 ,  C08F290 ,  C08G18 ,  C08G59 ,  C08G63 ,  C08L67 ,  C09K19

CPC classification number: A61K6/0017 ,  A61K6/0023 ,  A61K6/0038 ,  A61K6/083 ,  A61K6/09 ,  C07C69/712 ,  C07C255/54 ,  C08F290/06 ,  C08F290/061 ,  C08F290/064 ,  C08G18/835 ,  C08G59/10 ,  C08G59/12 ,  C08G59/1466 ,  C08G59/1494 ,  C08G59/4292 ,  C08G63/52 ,  C08G2270/00 ,  C08L67/07 ,  C09K19/2028 ,  C09K19/3068 ,  C09K2019/0448 ,  C08L33/00 ,  C08L75/16 ,  C08L43/02

Abstract: Liquid crystalline (meth)acrylates of the invention include at least three rigid rod-like moieties. One of these moieties is comprised between the (meth)acrylate rests and further two moieties are bonded as side chains. The liquid crystalline (meth)acrylates polymerizable using redox initiators and/or photo intiators. The (meth)acrylates of the invention polymerize quantitative and with very low volume shrinkage of less than 2.5 percent. The invention provides a polymerizable compound within the scope of general formula (I). These compounds are used in dental compositions and methods of use thereof.