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    DENTAL ADHESIVE COMPOSITION
    1.
    发明申请
    DENTAL ADHESIVE COMPOSITION 审中-公开
    牙膏组合物

    公开(公告)号：WO2003070198A1

    公开(公告)日：2003-08-28

    申请号：PCT/US2003/001106

    申请日：2003-01-14

    Applicant: DENTSPLY INTERNATIONAL INC.

    Inventor： KLEE, Joachim, E. ,  LEHMANN, Uwe ,  WALZ, Uwe

    IPC: A61K6/093

    CPC classification number: B82Y30/00 ,  A61K6/0008 ,  A61K6/0023 ,  C08L83/10

    Abstract: A composition including nanoparticles each having an acidic polymerizable siloxane moiety. For example, a hydrolysis stable, self-etching, self-priming dental adhesive composition including 90 to 10 percent by weight of an aqueous phase, and 10 to 90 percent by weight of acidic polymerizable nanoparticles. The acidic poylmerizable nanoparticles are obtainable by hydrolysis of a mixture containing one or more hydrolyzable organosilicon compounds wherein (i) at least a portion of the hydrolyzable organisilicon compounds contains one or more polymerizable groups and (ii) at least a portion of the hydrolyzable organisilicon compounds contain one or more acidic moieties.

    Abstract translation: 包含各自具有酸性可聚合硅氧烷部分的纳米颗粒的组合物。 例如，水解稳定的自蚀刻自吸牙科粘合剂组合物，其包含90至10重量％的水相和10至90重量％的酸性可聚合纳米颗粒。 酸性可溶性纳米颗粒可通过水解含有一种或多种可水解有机硅化合物的混合物获得，其中至少一部分可水解的有机硅化合物含有一个或多个可聚合基团，和至少一部分可水解的有机硅化合物含有一个或多个 酸性部分。

    LIGHT-POLYMERIZABLE DENTAL COMPOSITION CONTAINING AN INHIBITOR
    2.
    发明申请
    LIGHT-POLYMERIZABLE DENTAL COMPOSITION CONTAINING AN INHIBITOR 审中-公开
    含有抑制剂的光聚合牙本质组合物

    公开(公告)号：WO2002085974A1

    公开(公告)日：2002-10-31

    申请号：PCT/US2002/011978

    申请日：2002-04-16

    Applicant: DENTSPLY INTERNATIONAL INC. ,  KLEE, Joachim, E. ,  WALZ, Uwe

    Inventor： KLEE, Joachim, E. ,  WALZ, Uwe

    IPC: C08K5/01

    CPC classification number: B82Y30/00 ,  A61K6/083 ,  A61K6/09 ,  C08L75/16 ,  C08L33/00

    Abstract: Light-polymerizable dental composition comprising (i) a polymerizable monomer component, (ii) a light-sensitive polymerization initiator, (iii) an inhibitor, (iv) optionally a filler and/or pigment, and (v) optionally a solvent, characterized in that the inhibitor is a substituted fullerene compound present in an amount suitable for improving light stability of the dental composition.

    Abstract translation: 光聚合性牙科用组合物，其包含（i）可聚合单体组分，（ii）光敏聚合引发剂，（iii）抑制剂，（iv）任选的填料和/或颜料，和（v）任选的溶剂， 因为抑制剂是以适于改善牙齿组合物的光稳定性的量存在的取代的富勒烯化合物。

    ONE-PART SELF-PRIMING DENTAL ADHESIVE
    3.
    发明申请
    ONE-PART SELF-PRIMING DENTAL ADHESIVE 审中-公开
    一部分自我补贴牙膏

    公开(公告)号：WO2003013444A1

    公开(公告)日：2003-02-20

    申请号：PCT/US2002/025005

    申请日：2002-08-06

    Applicant: DENTSPLY INTERNATIONAL INC.

    Inventor： KLEE, Joachim, E. ,  WALZ, Uwe

    IPC: A61K6/00

    CPC classification number: A61K6/0023 ,  Y10S522/908 ,  C08L33/00

    Abstract: A dental adhesive composition for bonding dental restoratives to dentin and enamel provides a one-part self-etching, self-priming dental adhesive composition having hydrolysis stable polymerizable acidic adhesive monomers.

    Abstract translation: 用于将牙科修复剂粘合到牙质和牙釉质上的牙科粘合剂组合物提供具有水解稳定的可聚合酸性粘合剂单体的一部分自蚀刻自吸牙科粘合剂组合物。

    SILOXANE CONTAINING MACROMONOMERS AND DENTAL COMPOSITES THEREOF
    4.
    发明申请
    SILOXANE CONTAINING MACROMONOMERS AND DENTAL COMPOSITES THEREOF 审中-公开
    含硅氧烷的大分子单体及其牙科复合材料

    公开(公告)号：WO2001008639A1

    公开(公告)日：2001-02-08

    申请号：PCT/US2000/020348

    申请日：2000-07-26

    Applicant: DENTSPLY INTERNATIONAL INC.

    Inventor： KLEE, Joachim, E. ,  WALZ, Uwe ,  FIEDLER, Jürgen ,  MÜLHAUPT, Rolf ,  FREY, Holger ,  MÜH, Ekkehardt

    IPC: A61K6/093

    CPC classification number: C07F7/1836 ,  A61K6/093 ,  C08L83/04

    Abstract: The invention concerns macromonomers of a molecular weight of at least M ≥ 500 g/mol containing siloxane groups. The macromonomers are usable as polymerizable monomers in a dental/medical composite comprising further at least a polymerizable monomer, an organic or inorganic acid or an acidic monomer, a stabilizer, an iniator, pigments and an organic or inorganic filler. The dental/medical composite is usable as a dental restorative material for filling and restoring teeth, making inlays and onlays, for artificial teeth, for sealing and surface modification materials, usable as temporary crown and bridge material. Furthermore, the macromonomers are usable for filler surface modification, as precursors for siloxane condensation products or as precursor for preparation of nanoparticles containing active polymerizable moieties.

    Abstract translation: 本发明涉及含有硅氧烷基团的分子量至少M≥500g/ mol的大分子单体。 大分子单体可用作牙科/医用复合材料中的可聚合单体，所述复合材料还包含至少一种可聚合单体，有机或无机酸或酸性单体，稳定剂，引发剂，颜料和有机或无机填料。 牙科/医用复合材料可用作牙齿修复材料，用于填充和修复牙齿，制作用于人造牙齿的嵌体和嵌体，用于密封和表面改性材料，可用作临时牙冠和牙桥材料。 此外，大分子单体可用于填料表面改性，作为硅氧烷缩合产物的前体或用作制备含有活性可聚合部分的纳米粒子的前体。

    POLYMERIZABLE COMPOUNDS AND COMPOSITIONS
    6.
    发明申请
    POLYMERIZABLE COMPOUNDS AND COMPOSITIONS 审中-公开
    可聚合的化合物和组合物

    公开(公告)号：WO1996019179A1

    公开(公告)日：1996-06-27

    申请号：PCT/US1995016527

    申请日：1995-12-18

    Applicant: DENTSPLY INTERNATIONAL INC.

    Inventor： DENTSPLY INTERNATIONAL INC. ,  KLEE, Joachim, E. ,  WALZ, Uwe

    IPC: A61K06/083

    CPC classification number: C08L67/07 ,  C08G63/52 ,  A61K6/0017 ,  C08L33/08 ,  C08L33/10 ,  C08L33/14 ,  A61K6/0023 ,  A61K6/083

    Abstract: An esterified macromonomer within the scope of general formula (I), wherein Z is an organic moiety, R1 is hydrogen or a substituted or unsubstituted alkyl having from 1 to 12 carbon atoms, oxyalkyl having from 1 to 12 carbon atoms, alkenyl having from 2 to 12 carbon atoms, cycloalkyl having from 5 to 12 carbon atoms, aryl having from 6 to 12 carbon atoms or aralkyl having from 7 to 12 carbon atoms, each E independently is a hydroxil group, an organic ester moiety or an inorganic ester containing moiety and at least one E is an ester containing moiety, n and m each independently is an integer from 2 to 12. The esterified macromonomer is obtainable by esterification of at least a portion of the -OH groups of a macromonomer having at least one terminal double bond with at least one derivative of an inorganic or organic acid which introduces pendant groups exhibiting at least one acid moiety selected from the group consisting of -COOH, -PO3H2, -SO3H, -BO2H or salts thereof. The number of the acid moieties is chosen such that a polymer obtained by polymerizing those monomers has an adhesive strength to dentine of at least 2 MPa.

    Abstract translation: 在通式（I）的范围内的酯化的大分子单体，其中Z是有机部分，R 1是氢或具有1至12个碳原子的取代或未取代的烷基，具有1至12个碳原子的烷氧基，具有2个 至12个碳原子，具有5至12个碳原子的环烷基，具有6至12个碳原子的芳基或具有7至12个碳原子的芳烷基，每个E独立地为羟基，有机酯部分或含无机酯的部分 并且至少一个E是含酯部分，n和m各自独立地是2至12的整数。酯化的大分子单体可通过至少一部分具有至少一个末端双键的大分子单体的-OH基团的酯化获得 与引入具有至少一个选自-COOH，-PO 3 H 2，-SO 3 H，-BO 2 H的酸部分的侧基或其盐的至少一种无机或有机酸的衍生物键合。 选择酸部分的数目使得通过聚合这些单体获得的聚合物对牙本质的粘合强度至少为2MPa。

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