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公开(公告)号：US3860666A
公开(公告)日：1975-01-14
申请号：US29970672
申请日：1972-10-24
Applicant: DIAMOND SHAMROCK CORP
Inventor： BECKERS NORMAN L
Abstract: In a process for the production of perchloroethylene in an alumina-containing fluid bed reactor, the addition to the reaction gases, prior to an anhydrous quenching step, of a preferentially hydrochlorinatable ethylenically unsaturated chlorinated hydrocarbon reduces the tendency of the trichloroethylene also contained in the reaction gases to hydrochlorinate forming unsymmetrical tetrachloroethane.
Abstract translation: 在含氧化铝流化床反应器中生产全氯乙烯的方法中，在无水淬火步骤之前，加入优选可氢化烯属不饱和氯化烃的反应气体降低了反应中所含的三氯乙烯的倾向 气体形成不对称四氯乙烷的氢氯化物。
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公开(公告)号：US3900524A
公开(公告)日：1975-08-19
申请号：US46936074
申请日：1974-05-13
Applicant: DIAMOND SHAMROCK CORP
Inventor： BECKERS NORMAN L
CPC classification number: C23G5/0289 , C07C17/42 , C07C19/03
Abstract: Methylene chloride stabilized by admixture with diisopropylamine, N-methyl pyrrole, butylene oxide and propylene oxide. The composition is useful in metal degreasing.
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公开(公告)号：US3898195A
公开(公告)日：1975-08-05
申请号：US46933374
申请日：1974-05-13
Applicant: DIAMOND SHAMROCK CORP
Inventor： BECKERS NORMAN L
CPC classification number: C23G5/0289 , C07C17/42 , C07C19/03
Abstract: Methylene chloride stabilized by admixture with diisopropylamine, N-methyl pyrrole, butylene oxide, propylene oxide, methyl acetate, acetone, tertiary amylenes, and methyl alcohol. The composition is useful in metal degreasing.
Abstract translation: 通过与二异丙胺，N-甲基吡咯，环氧丁烷，环氧丙烷，乙酸甲酯，丙酮，叔戊烯和甲醇的混合而稳定的二氯甲烷。 该组合物可用于金属脱脂。
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公开(公告)号：US3887628A
公开(公告)日：1975-06-03
申请号：US33536373
申请日：1973-02-23
Applicant: DIAMOND SHAMROCK CORP
Inventor： BECKERS NORMAN L
CPC classification number: C23G5/0288 , C07C17/42 , C07C19/03
Abstract: Organic epoxides in admixture with methylene chloride have been found to prevent degradation of methylene chloride in the presence of metals, metal halides, combinations thereof, and aromatic compounds, which react with methylene chloride in the presence of said metals, metal halides and combinations thereof. Reactions of aliphatic organic compounds with said metals, metal halides and combinations thereof to form products which result in deterioration of methylene chloride are also inhibited. A method for vapor degreasing metals by using the stabilized methylene chloride is described.
Abstract translation: 已经发现与二氯甲烷混合的有机环氧化物防止在金属，金属卤化物，其组合和芳族化合物的存在下二氯甲烷的降解，所述金属，金属卤化物，和二氯甲烷在所述金属，金属卤化物及其组合的存在下与二氯甲烷反应。 脂族有机化合物与所述金属，金属卤化物及其组合的反应形成产生二氯甲烷劣化的产物也受到抑制。 描述了通过使用稳定的二氯甲烷蒸汽除油金属的方法。
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公开(公告)号：US3873631A
公开(公告)日：1975-03-25
申请号：US46618374
申请日：1974-05-02
Applicant: DIAMOND SHAMROCK CORP
Inventor： BECKERS NORMAN L , ROWE EDWARD A
CPC classification number: C23G5/02887 , C07C17/42 , C07C19/05
Abstract: The tendency for methyl chloroform to decompose in the presence of metals, particularly aluminum, is inhibited by a stabilizer mixture comprising an epoxide, a nitroalkane and either propylene glycol mono-methyl ether, dioxepane or a mixture thereof.
Abstract translation: 甲基氯仿在金属，特别是铝的存在下分解的趋势被包含环氧化物，硝基烷烃和丙二醇单甲醚，二氧杂环庚烷或其混合物的稳定剂混合物抑制。
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Patent Agency Ranking
公开(公告)号：US3860665A
公开(公告)日：1975-01-14
申请号：US33536573
申请日：1973-02-23
Applicant: DIAMOND SHAMROCK CORP
Inventor： BECKERS NORMAN L
Abstract: Tetrahydrofuran and optionally propylene oxide in admixture with methylene chloride have been found to prevent degradation of methylene chloride in the presence of metals, metal halides, combinations thereof, and aromatic compounds, which react with methylene chloride in the presence of said metals, metal halides and combinations thereof. Reactions of aliphatic organic compounds with said metals, metal halides and combinations thereof to form products which result in deterioration of methylene chloride are also inhibited. A method for vapor degreasing metals by using the stabilized methylene chloride is described.
Abstract translation: 已经发现四氢呋喃和任选的环氧丙烷与二氯甲烷混合，以防止金属，金属卤化物，其组合和芳族化合物在二氯甲烷存在下在所述金属，金属卤化物和 其组合。 脂族有机化合物与所述金属，金属卤化物及其组合的反应也可以抑制导致二氯甲烷劣化的产物。 描述了通过使用稳定的二氯甲烷蒸汽除油金属的方法。
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公开(公告)号：US3923912A
公开(公告)日：1975-12-02
申请号：US33498573
申请日：1973-02-23
Applicant: DIAMOND SHAMROCK CORP
Inventor： BECKERS NORMAN L
CPC classification number: C23G5/02874
Abstract: Ketones and optionally epoxides in admixture with methylene chloride have been found to prevent degradation of methylene chloride in the presence of metals, metal halides, combinations thereof, and aromatic compounds, which react with methylene chloride in the presence of said metals, metal halides and combinations thereof. Reactions of aliphatic organic compounds with said metals, metal halides and combinations thereof to form products which result in deterioration of methylene chloride are also inhibited. A method for vapor degreasing metals by using the stabilized methylene chloride is described.
Abstract translation: 已经发现酮和任选的与二氯甲烷混合的环氧化物在金属，金属卤化物，其组合和芳族化合物存在下防止二氯甲烷的降解，所述金属，金属卤化物，其组合和芳族化合物在所述金属，金属卤化物和组合物的存在下与二氯甲烷反应 其中。 脂族有机化合物与所述金属，金属卤化物及其组合的反应也可以抑制导致二氯甲烷劣化的产物。 描述了通过使用稳定的二氯甲烷蒸汽除油金属的方法。
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公开(公告)号：US3864408A
公开(公告)日：1975-02-04
申请号：US33536473
申请日：1973-02-23
Applicant: DIAMOND SHAMROCK CORP
Inventor： BECKERS NORMAN L
IPC: C11D7/26 , C07C17/00 , C07C17/42 , C07C19/03 , C07C67/00 , C11D7/30 , C11D7/50 , C23G5/028 , C07C17/40
CPC classification number: C23G5/0288 , C07C17/42 , C07C19/03
Abstract: Methyl acetate and optionally propylene oxide in admixture with methylene chloride have been found to prevent degradation of methylene chloride in the presence of metals, metal halides, combinations thereof, and aromatic compounds, which react with methylene chloride in the presence of said metals, metal halides and combinations thereof. Reactions of aliphatic organic compounds with said metals, metal halides and combinations thereof to form products which result in deterioration of methylene chloride are also inhibited. A method for vapor degreasing metals by using the stabilized methylene chloride is described.
Abstract translation: 已经发现乙酸甲酯和任选的环氧丙烷与二氯甲烷混合，以防止金属，金属卤化物，其组合和芳族化合物在二氯甲烷存在下在所述金属存在下，二氯甲烷的降解，金属卤化物 及其组合。 脂族有机化合物与所述金属，金属卤化物及其组合的反应也可以抑制导致二氯甲烷劣化的产物。 描述了通过使用稳定的二氯甲烷蒸汽除油金属的方法。
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公开(公告)号：US3862250A
公开(公告)日：1975-01-21
申请号：US33536673
申请日：1973-02-23
Applicant: DIAMOND SHAMROCK CORP
Inventor： BECKERS NORMAN L
CPC classification number: C23G5/02883 , C07C17/42 , C07C19/03
Abstract: Acetonitrile and optionally propylene oxide in admixture with methylene chloride have been found to prevent degradation of methylene chloride in the presence of metals, metal halides, combinations thereof, and aromatic compounds, which react with methylene chloride in the presence of said metals, metal halides and combinations thereof. Reactions of aliphatic organic compounds with said metals, metal halides and combinations thereof to form products which result in deterioration of methylene chloride are also inhibited. A method for vapor degreasing metals by using the stabilized methylene chloride is described.
Abstract translation: 已经发现乙腈和任选的环氧丙烷与二氯甲烷混合，以防止金属，金属卤化物，它们的组合和芳族化合物在二氯甲烷存在下在所述金属，金属卤化物和 其组合。 脂族有机化合物与所述金属，金属卤化物及其组合的反应也可以抑制导致二氯甲烷劣化的产物。 描述了通过使用稳定的二氯甲烷蒸汽除油金属的方法。
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公开(公告)号：US3682830A
公开(公告)日：1972-08-08
申请号：US3682830D
申请日：1970-07-13
Applicant: DIAMOND SHAMROCK CORP
Inventor： BECKERS NORMAN L
CPC classification number: C07C251/72 , C07C17/42 , C23G5/02883
Abstract: A CLASS OF HYDRAZONES, ALKOXYALDEHYDE HYDRAZONES, PARTICULARLY USEFUL AS STABILIZERS FOR CHLORINATED HYDROCARBONS, ARE DISCLOSED.
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