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公开(公告)号:WO0185831A3
公开(公告)日:2002-05-23
申请号:PCT/US0114179
申请日:2001-05-03
Applicant: DOW CHEMICAL CO , LADIKA MLADEN , FIBIGER RICHARD F , CHOU CHAI JING , BALAZS ANNA C
Inventor: LADIKA MLADEN , FIBIGER RICHARD F , CHOU CHAI-JING , BALAZS ANNA C
CPC classification number: C08L23/02 , C08K9/08 , C08L23/10 , C08L23/36 , C08L2666/04
Abstract: A nanocomposite material containing several necessary components. The first component is from 98.9 to 70 parts by weight of a bulk polymer, the bulk polymer being a non-polar polymer, such as polyethylene or polypropylene. The second component is from 1 to 30 parts by weight of a cation exchanging multi-layered silicate material, such as acid or quaternary ammonium treated montmorillonite or sepiolite, dispersed in the bulk polymer, the cation exchanging multi-layered silicate material having a plurality of anionic sites, the multi-layered silicate material being exfoliated to one, two, three, four and more than four layer units, the number percent of the one, two, three and four layer units being greater than the number percent of the more than four layer units. The third component is from 0.1 to 10 parts by weight of an organic cation, such as polyethylene or polypropylene terminated by an amine group, the organic cation having a pendent polymer chain, the polymer of the pendent polymer chain being miscible with the bulk polymer, the average molecular weight of the pendent polymer chain being more than 3000. The nanocomposite material is made by blending the molten bulk polymer with the cation exchanging multi-layered silicate material and the organic cation.
Abstract translation: 纳米复合材料含有几种必需组分。 第一组分为98.9至70重量份的本体聚合物,本体聚合物为非极性聚合物,例如聚乙烯或聚丙烯。 第二组分为1至30重量份的阳离子交换多层硅酸盐材料,例如分散在本体聚合物中的酸或季铵处理的蒙脱石或海泡石,阳离子交换多层硅酸盐材料具有多个 阴离子位点,多层硅酸盐材料被剥离成一个,两个,三个,四个和四个以上的层单元,一个,两个,三个和四个层单元的数量百分比大于超过 四层单位。 第三组分为0.1至10重量份的有机阳离子,例如由胺基封端的聚乙烯或聚丙烯,有机阳离子具有侧链聚合物链,所述侧链聚合物链的聚合物可与本体聚合物混溶, 侧链聚合物链的平均分子量大于3000.纳米复合材料通过将熔融的本体聚合物与阳离子交换多层硅酸盐材料和有机阳离子共混制成。
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公开(公告)号:US5416148B1
公开(公告)日:1999-03-02
申请号:US30403694
申请日:1994-09-09
Applicant: DOW CHEMICAL CO
Inventor: FARAH HANI , LAUGHNER MICHAEL K , CHOU CHAI-JING , HUGHES MORGAN M
IPC: C08J5/18 , C08L23/04 , C08L25/08 , C08L51/04 , C08L55/02 , C08L67/02 , C08L69/00 , C08F8/00 , C08K3/10
CPC classification number: C08L69/00 , C08L23/00 , C08L2666/02
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公开(公告)号:DE69708605T2
公开(公告)日:2002-08-01
申请号:DE69708605
申请日:1997-02-20
Applicant: DOW CHEMICAL CO
Inventor: KARANDE V , CHOU CHAI-JING , SOLC H , SUH W
Abstract: This invention relates to a polymer foam prepared by dispersing an organophilic multi-layered material into a melt comprising an olefinic or styrenic polymer having polar functionality so that at least a portion of the polymer intercalates between layers of the particles; and expanding the polymer with a blowing agent under such condition to form the polymer foam. The organophilic multi-layered material can also be dispersed into an olefinic or styrenic monomer, which can then be polymerized to form a polymer melt prior to, or along with the foaming step.
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公开(公告)号:AT209666T
公开(公告)日:2001-12-15
申请号:AT97906696
申请日:1997-02-20
Applicant: DOW CHEMICAL CO
Inventor: KARANDE SEEMA V , CHOU CHAI-JING , SOLC JITKA H , SUH KYUNG W
Abstract: This invention relates to a polymer foam prepared by dispersing an organophilic multi-layered material into a melt comprising an olefinic or styrenic polymer having polar functionality so that at least a portion of the polymer intercalates between layers of the particles; and expanding the polymer with a blowing agent under such condition to form the polymer foam. The organophilic multi-layered material can also be dispersed into an olefinic or styrenic monomer, which can then be polymerized to form a polymer melt prior to, or along with the foaming step.
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公开(公告)号:AU1812300A
公开(公告)日:2000-06-05
申请号:AU1812300
申请日:1999-11-04
Applicant: DOW CHEMICAL CO
Inventor: CHOU CHAI-JING , GARCIA-MEITIN EDDY I
IPC: C08J3/20 , C08K9/04 , C08K9/08 , C08L101/00
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公开(公告)号:PL328862A1
公开(公告)日:1999-03-01
申请号:PL32886297
申请日:1997-12-22
Applicant: DOW CHEMICAL CO
Inventor: ANDERSON KENNETH , WHITE JERRY E , CHOU CHAI-JING , POLANSKY CHRISTINE A
IPC: C08J5/18 , B29C70/06 , C08G59/42 , C08G59/50 , C08J9/00 , C08K3/34 , C08K9/04 , C08K13/06 , C08L63/00 , C08L67/00 , C08L71/00 , C09C3/10 , C09D163/00 , C09D167/00 , C09D171/00 , C09J163/00 , C09J167/00 , C09J171/00
Abstract: PCT No. PCT/US97/23861 Sec. 371 Date Aug. 5, 1998 Sec. 102(e) Date Aug. 5, 1998 PCT Filed Dec. 22, 1997 PCT Pub. No. WO98/29491 PCT Pub. Date Jul. 9, 1998A polymer composite comprising a hydroxy-phenoxyether or polyester polymer matrix having dispersed therein layers of an inorganic material derived from a multilayered inorganic material having organophilic properties. The dispersion of the multilayered inorganic material in the polymer matrix is such that an increase in the average interlayer spacing of the layered inorganic material occurs. This increase in interlayer spacing occurs to a significant extent resulting in the formation of a nanocomposite. The polymers are preferably derived from a diglycidyl ether or ester or an epihalohydrin and a dinucleophile such as a dicarboxylic acid, a difunctional amine, a bisphenol or a sulfonamide. As the organophilic inorganic material clay minerals modified with organic ammonium compounds are used.
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公开(公告)号:PL328459A1
公开(公告)日:1999-02-01
申请号:PL32845997
申请日:1997-02-20
Applicant: DOW CHEMICAL CO
Inventor: KARANDE SEEMA V , CHOU CHAI-JING , SOLC JITKA H , SUH KYUNG W
Abstract: This invention relates to a polymer foam prepared by dispersing an organophilic multi-layered material into a melt comprising an olefinic or styrenic polymer having polar functionality so that at least a portion of the polymer intercalates between layers of the particles; and expanding the polymer with a blowing agent under such condition to form the polymer foam. The organophilic multi-layered material can also be dispersed into an olefinic or styrenic monomer, which can then be polymerized to form a polymer melt prior to, or along with the foaming step.
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公开(公告)号:CZ9802735A3
公开(公告)日:1999-01-13
申请号:CZ273598
申请日:1997-12-22
Applicant: DOW CHEMICAL CO
Inventor: ANDERSON KENNETH W , WHITE JERRY E , CHOU CHAI-JING , POLANSKY CHRISTINE A
IPC: C08J5/18 , B29C70/06 , C08G59/42 , C08G59/50 , C08J9/00 , C08K3/34 , C08K9/04 , C08K13/06 , C08L63/00 , C08L67/00 , C08L71/00 , C09C3/10 , C09D163/00 , C09D167/00 , C09D171/00 , C09J163/00 , C09J167/00 , C09J171/00 , C08L79/02 , C08L81/10
CPC classification number: C09D167/00 , C08G59/42 , C08G59/50 , C08K3/34 , C08K9/04 , C08L71/00 , C08L2666/58 , C09J167/00 , C08L67/00 , C08L63/00
Abstract: PCT No. PCT/US97/23861 Sec. 371 Date Aug. 5, 1998 Sec. 102(e) Date Aug. 5, 1998 PCT Filed Dec. 22, 1997 PCT Pub. No. WO98/29491 PCT Pub. Date Jul. 9, 1998A polymer composite comprising a hydroxy-phenoxyether or polyester polymer matrix having dispersed therein layers of an inorganic material derived from a multilayered inorganic material having organophilic properties. The dispersion of the multilayered inorganic material in the polymer matrix is such that an increase in the average interlayer spacing of the layered inorganic material occurs. This increase in interlayer spacing occurs to a significant extent resulting in the formation of a nanocomposite. The polymers are preferably derived from a diglycidyl ether or ester or an epihalohydrin and a dinucleophile such as a dicarboxylic acid, a difunctional amine, a bisphenol or a sulfonamide. As the organophilic inorganic material clay minerals modified with organic ammonium compounds are used.
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公开(公告)号:AU2132297A
公开(公告)日:1997-09-10
申请号:AU2132297
申请日:1997-02-20
Applicant: DOW CHEMICAL CO
Inventor: KARANDE SEEMA V , CHOU CHAI-JING , SOLC JITKA H , SUH KYUNG W
Abstract: This invention relates to a polymer foam prepared by dispersing an organophilic multi-layered material into a melt comprising an olefinic or styrenic polymer having polar functionality so that at least a portion of the polymer intercalates between layers of the particles; and expanding the polymer with a blowing agent under such condition to form the polymer foam. The organophilic multi-layered material can also be dispersed into an olefinic or styrenic monomer, which can then be polymerized to form a polymer melt prior to, or along with the foaming step.
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公开(公告)号:AU2132097A
公开(公告)日:1997-09-10
申请号:AU2132097
申请日:1997-02-20
Applicant: DOW CHEMICAL CO
Inventor: NICHOLS KEVIN L , CHOU CHAI-JING
IPC: C08K3/00 , C08K9/04 , C08K9/06 , C08L101/00
Abstract: A polymer composite comprises a polymer matrix having, dispersed therein, layers of an inorganic material derived from a multilayered inorganic material such as clay intercalated with an inorganic intercalant. The multilayered inorganic material may also be intercalated with an organic material.
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