METHOD OF MAKING SILOXANE COMPOSITIONS

    公开(公告)号:CA2062333C

    公开(公告)日:2003-11-11

    申请号:CA2062333

    申请日:1992-03-05

    Abstract: A method of making a dispersion of a high viscosity siloxane in a volatile, especially cyclic siloxane, comprises first dispersing organopolysiloxanes having at least 2 Si-OR groups, wherein R is H or alkyl in a volatile siloxane and adding a catalyst which is either a phosphonitrile halide having the general formula [X(PX2=N)n PX3]+[MX(v-y+1)R t]-, or a hetero- geneous catalyst selected from Li, Mg, Ca, Sr or Ba hydroxide, Na or K borate or phosphate, Rb or Cs carbonate or carboxylates of Rb or Cs wherein M is an element having an electronegativity of from 1.0 to 2.0, R is alkyl, X is halide, n is 1 to 6, v is the valence of M and t is from 0 to (v-1).

    METHOD OF MAKING SILOXANE COMPOSITIONS

    公开(公告)号:CA2062333A1

    公开(公告)日:1992-09-15

    申请号:CA2062333

    申请日:1992-03-05

    Abstract: A method of making a dispersion of a high viscosity siloxane in a volatile, especially cyclic siloxane, comprises first dispersing organopolysiloxanes having at least 2 Si-OR groups, wherein R is H or alkyl in a volatile siloxane and adding a catalyst which is either a phosphonitrile halide having the general formula ¢X(PX2=N)nPX3!+¢MX(v-t+1)Rt!-, or a heterogeneous catalyst selected from Li, Mg, Ca, Sr or Ba hydroxide, Na or K borate or phosphate, Rb or Cs carbonate or carboxylates of Rb or Cs wherein M is an element having an electronegativity of from 1.0 to 2.0, R is alkyl, X is halide, n is 1 to 6, v is the valence of M and t is from 0 to (v-1).

    POLYSILOXANES AND THEIR PREPARATION
    3.
    发明申请
    POLYSILOXANES AND THEIR PREPARATION 审中-公开
    多硅氧烷及其制备

    公开(公告)号:WO03016380A2

    公开(公告)日:2003-02-27

    申请号:PCT/EP0209821

    申请日:2002-08-12

    CPC classification number: C08G77/26 C08G77/08

    Abstract: An amino-functional polysiloxane is prepared by reacting an aminosilane (A) which contains an aminoalkyl group and at least one alkoxy group bonded to Si with a carboxylic acid and a silanol-functional polysiloxane (B). The aminosilane (A) is partially converted into its carboxylate salt which acts as a catalyst for the siloxane condensation polymerization reaction between (A) and (B).

    Abstract translation: 氨基官能聚硅氧烷通过使含有氨基烷基和至少一个与Si键合的烷氧基的氨基硅烷(A)与羧酸和硅烷醇官能聚硅氧烷(B)反应来制备。 氨基硅烷(A)部分转化为其羧酸盐,其用作(A)和(B)之间的硅氧烷缩聚反应的催化剂。

    4.
    发明专利
    未知

    公开(公告)号:DE69211189T2

    公开(公告)日:1996-11-07

    申请号:DE69211189

    申请日:1992-03-04

    Abstract: A method of making a dispersion of a high viscosity siloxane in a volatile, especially cyclic siloxane, comprises first dispersing organopolysiloxanes having at least 2 Si-OR groups, wherein R is H or alkyl in a volatile siloxane, and adding a catalyst which is either a phosphonitrile halide having the general formula [X(PX2=N)nPX3] [MX(v-t+1)Rt] , or a heterogeneous catalyst, selected from Li, Mg, Ca, Sr or Ba hydroxide, Na or K borate or phosphate, Rb or Cs carbonate, or carboxylates of Rb or Cs, wherein M is an element having an electronegativity of from 1.0 to 2.0, R is alkyl, X is halide, n is 1 to 6, v is the valence of M and t is from 0 to (v-1).

    5.
    发明专利
    未知

    公开(公告)号:DE69211189D1

    公开(公告)日:1996-07-11

    申请号:DE69211189

    申请日:1992-03-04

    Abstract: A method of making a dispersion of a high viscosity siloxane in a volatile, especially cyclic siloxane, comprises first dispersing organopolysiloxanes having at least 2 Si-OR groups, wherein R is H or alkyl in a volatile siloxane, and adding a catalyst which is either a phosphonitrile halide having the general formula [X(PX2=N)nPX3] [MX(v-t+1)Rt] , or a heterogeneous catalyst, selected from Li, Mg, Ca, Sr or Ba hydroxide, Na or K borate or phosphate, Rb or Cs carbonate, or carboxylates of Rb or Cs, wherein M is an element having an electronegativity of from 1.0 to 2.0, R is alkyl, X is halide, n is 1 to 6, v is the valence of M and t is from 0 to (v-1).

    6.
    发明专利
    未知

    公开(公告)号:ES2088097T3

    公开(公告)日:1996-08-01

    申请号:ES92301836

    申请日:1992-03-04

    Abstract: A method of making a dispersion of a high viscosity siloxane in a volatile, especially cyclic siloxane, comprises first dispersing organopolysiloxanes having at least 2 Si-OR groups, wherein R is H or alkyl in a volatile siloxane, and adding a catalyst which is either a phosphonitrile halide having the general formula [X(PX2=N)nPX3] [MX(v-t+1)Rt] , or a heterogeneous catalyst, selected from Li, Mg, Ca, Sr or Ba hydroxide, Na or K borate or phosphate, Rb or Cs carbonate, or carboxylates of Rb or Cs, wherein M is an element having an electronegativity of from 1.0 to 2.0, R is alkyl, X is halide, n is 1 to 6, v is the valence of M and t is from 0 to (v-1).

    7.
    发明专利
    未知

    公开(公告)号:ES2062322T3

    公开(公告)日:1994-12-16

    申请号:ES90300646

    申请日:1990-01-22

    Applicant: DOW CORNING

    Abstract: A process for the production of an organosilicon condensation product which comprises contacting (A) at least one organosilicon compound having in the molecule at least one silicon-bonded hydroxyl group, the organic substituents being selected from monovalent hydrocarbon groups having from 1 to 14 carbon atoms and monovalent substituted hydrocarbon groups having from 1 to 10 carbon atoms in which the substituents are selected from amino, halogen, mercapto, hydroxyl, amido and ester, with (B) a hydroxide selected from the group consisting of magnesium, calcium, strontium and barium hydroxides.

    PROCESS FOR THE PRODUCTION OF ORGANOSILICON COMPOUNDS

    公开(公告)号:CA2044696A1

    公开(公告)日:1991-12-29

    申请号:CA2044696

    申请日:1991-06-14

    Applicant: DOW CORNING

    Inventor: WESTALL STEPHEN

    Abstract: Process for the production of organosiloxanes comprising contacting (A) at least one organosilicon compound having in the molecule at least one silanol group, the organic substituents being selected from monovalent hydrocarbon groups having from 1 to 14 carbon atoms and monovalent substituted hydrocarbon groups having from 1 to 10 carbon atoms, with (B) one or more compounds selected from rubidium carbonate, cesium carbonate and carboxylates of rubidium and cesium.

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