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1.
公开(公告)号:WO2004096744A2
公开(公告)日:2004-11-11
申请号:PCT/US2004012246
申请日:2004-04-22
Applicant: DOW GLOBAL TECHNOLGIES INC , LYSENKO ZENON , MORRISON DONALD L , BABB DAVID A , BUNNING DONALD L , DERSTINE CHRISTOPHER W , GILCHRIST JAMES H , JOUETT RAY H , KANEL JEFFREY S , OLSON KURT D , PENG WEI-JUN , PHILLIPS JOE D , ROESCH BRIAN M , SANDERS AARON W , SCHROCK ALAN K , THOMAS P J
Inventor: LYSENKO ZENON , MORRISON DONALD L , BABB DAVID A , BUNNING DONALD L , DERSTINE CHRISTOPHER W , GILCHRIST JAMES H , JOUETT RAY H , KANEL JEFFREY S , OLSON KURT D , PENG WEI-JUN , PHILLIPS JOE D , ROESCH BRIAN M , SANDERS AARON W , SCHROCK ALAN K , THOMAS P J
IPC: C07C67/31 , C07C67/347 , C07C69/675 , C07C69/716 , C07C69/732 , C07C69/738 , C08G18/40 , C08G18/48 , C07C45/00
CPC classification number: C08G18/4891 , C07C67/31 , C07C67/347 , C07C69/675 , C07C69/716 , C07C69/732 , C07C69/738 , C08G18/4072 , C08G18/4804 , C08G18/4841 , C08G2101/0008 , C08G2101/005 , C08G2101/0083
Abstract: An aldehyde composition derived by hydroformylation of a transesterified seed oil and containing a mixture of formyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoformyl, greater than about 1 to less than about 65 percent diformyl, and greater than about 0.1 to less than about 10 percent triformyl-substituted fatty acids or fatty acid esters, and having a diformyl to triformyl weight ratio of greater than about 5/1; preferably, greater than about 3 to less than about 20 percent saturates; and preferably, greater than about 1 to less than about 20 percent unsaturates. An alcohol composition derived by hydrogenation of the aforementioned aldehyde composition, containing a mixture of hydroxymethyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoalcohol {mono(hydroxymethyl)}, greater than about 1 to less than about 65 percent diol {di(hydroxymethyl)}, greater than about 0.1 to less than about 10 percent triol, tri(hydroxmethyl)-substituted fatty acids or fatty acid esters; preferably greater than about 3 to less than about 35 percent saturates; and preferably, less than about 10 percent unsaturates. The alcohol composition can be converted into an oligomeric polyol for use in the manufacture of polyurethane slab stock flexible foams.
Abstract translation: 通过酯交换种子油的加氢甲酰化衍生的醛组合物,并含有具有以下重量组成的甲酰取代的脂肪酸或脂肪酸酯的混合物:大于约10至小于约95%的单甲基,大于约1至少 并且具有大于约65%的二甲酰基和大于约0.1至小于约10%的三甲酰基取代的脂肪酸或脂肪酸酯,并且具有大于约5/1的二甲酰基 - 三甲酰基重量比; 优选大于约3至小于约20%的饱和物; 并且优选大于约1至小于约20%的不饱和度。 通过上述醛组合物的氢化衍生的醇组合物,其含有羟甲基取代的脂肪酸或具有以下重量组成的脂肪酸酯的混合物:大于约10至小于约95%的一元醇(单(羟甲基)}, 大于约1至小于约65%的二醇{二(羟甲基)},大于约0.1至小于约10%的三醇,三(羟甲基)取代的脂肪酸或脂肪酸酯; 优选大于约3至小于约35%的饱和物; 并且优选小于约10%的不饱和物。 醇组合物可以转化成用于制造聚氨酯板坯柔性泡沫的低聚多元醇。
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2.
公开(公告)号:UA86019C2
公开(公告)日:2009-03-25
申请号:UAA200510101
申请日:2004-04-22
Applicant: DOW GLOBAL TECHNOLGIES INC
Inventor: LYSENKO ZENON , BABB DAVID A , JOUETT RAY , PHILLIPS JOE D , SCHROCK ALAN K , THOMAS P J , KANEL JEFFREY S , MORRISON DONALD L , BUNNING DONALD L , DERSTINE CHRISTOPHER W , GILCHRIST JAMES H , SANDERS AARON W , OLSON KURT D , PENG WEI-JUN , ROESCH BRIAN M
IPC: C07C47/00 , C07C45/00 , C07C67/00 , C07C67/31 , C07C67/347 , C07C69/00 , C07C69/675 , C07C69/716 , C07C69/732 , C07C69/738 , C08G18/40 , C08G18/48
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