NITROXIDE COMPOUNDS FOR MINIMIZING SCORCH IN CROSSLINKABLE COMPOSITIONS
    1.
    发明申请
    NITROXIDE COMPOUNDS FOR MINIMIZING SCORCH IN CROSSLINKABLE COMPOSITIONS 审中-公开
    用于使可交联组合物中的氧化最小化的氧化物化合物

    公开(公告)号:WO2008045718B1

    公开(公告)日:2008-07-17

    申请号:PCT/US2007080143

    申请日:2007-10-02

    CPC classification number: C08F2/38 C08F4/00 C08K5/0025 C08K5/3435

    Abstract: Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy- tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.

    Abstract translation: 在可交联聚合物例如EPDM的自由基交联过程中,通过在熔融加工和交联之前将防焦烧量的衍生物,优选醚,酯或氨基甲酸酯衍生物,TEMPO化合物 例如4-羟基 - 四烃基哌啶-1-氧基。 本发明的焦化抑制剂如果不是更好,其性能与它们的4-羟基 - 四烃基哌啶-1-氧基对应物在类似的聚合物组合物中以及在类似的焦化抑制和最终交联度条件下相似,但表现出较小的挥发性和 聚合物组合物内的迁移较少。

    NITROXIDE COMPOUNDS FOR MINIMIZING SCORCH IN CROSSLINKABLE COMPOSITIONS
    4.
    发明申请
    NITROXIDE COMPOUNDS FOR MINIMIZING SCORCH IN CROSSLINKABLE COMPOSITIONS 审中-公开
    用于在可交换组合物中最小化分光光度的硝化物化合物

    公开(公告)号:WO2008045718A3

    公开(公告)日:2008-06-05

    申请号:PCT/US2007080143

    申请日:2007-10-02

    CPC classification number: C08F2/38 C08F4/00 C08K5/0025 C08K5/3435

    Abstract: Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy- tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.

    Abstract translation: 在可交联聚合物(例如EPDM)的自由基交联期间,通过在熔融加工和交联焦烧抑制量的TEMPO化合物的衍生物,优选醚,酯或氨基甲酸酯衍生物的交联之前引入聚合物中,焦烧被抑制 ,例如4-羟基 - 四氢环丁基哌啶-1-基。 在类似的聚合物组合物中和在类似的条件下,在焦烧抑制和最终交联度方面,本发明的焦烧抑制剂也优于它们的4-羟基 - 四烃基哌啶-1-氧基对应物,但是表现出较小的挥发性, 聚合物组合物内迁移少。

    ELECTRONIC DEVICE MODULE COMPRISING POLYOLEFIN COPOLYMER
    5.
    发明申请
    ELECTRONIC DEVICE MODULE COMPRISING POLYOLEFIN COPOLYMER 审中-公开
    包含聚烯烃共聚物的电子器件模块

    公开(公告)号:WO2008036708A3

    公开(公告)日:2008-05-08

    申请号:PCT/US2007078846

    申请日:2007-09-19

    Abstract: An electronic device module comprising: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) a polyolefin copolymer with at least one of (a) a density of less than about 0.90 g/cc, (b) a 2% secant modulus of less than about 150 megaPascal (mPa) as measured by ASTM D-882-02), (c) a melt point of less than about 95C, (d) an a-olefin content of at least about 15 and less than about 50 wt% based on the weight of the polymer, (e) a Tg of less than about -35C, and (f) a SCBDI of at least about 50, (2) optionally, free radical initiator, e.g., a peroxide or azo compound, or a photoinitiator, e.g., benzophenone, and (3) optionally, a co-agent. Typically, the polyolefin copolymer is an ethylene/a-olefin copolymer. Optionally, the polymeric material can further comprise a vinyl silane and/or a scorch inhibitor, and the copolymer can remain uncrosslinked or be crosslinked.

    Abstract translation: 一种电子设备模块,包括:A.至少一个电子设备,例如太阳能电池和B.与所述电子设备的至少一个表面紧密接触的聚合材料,所述聚合材料包含(1)聚烯烃共聚物, (a)小于约0.90g / cc的密度,(b)通过ASTM D-882-02测量的小于约150兆帕(mPa)的2%割线模量中的至少一个),(c) 熔点低于约95℃,(d)基于聚合物重量,α-烯烃含量为至少约15重量%且小于约50重量%,(e)Tg小于约-35℃,( f)至少约50的SCBDI,(2)任选的自由基引发剂,例如过氧化物或偶氮化合物,或光引发剂,例如二苯甲酮,和(3)任选的助剂。 通常,聚烯烃共聚物是乙烯/α-烯烃共聚物。 任选地,聚合物材料还可以包含乙烯基硅烷和/或焦烧抑制剂,并且共聚物可以保持未交联或交联。

    COMPOSITIONS USEFUL FOR PREPARING FOAMED ARTICLES FROM LOW MELT INDEX RESINS
    8.
    发明申请
    COMPOSITIONS USEFUL FOR PREPARING FOAMED ARTICLES FROM LOW MELT INDEX RESINS 审中-公开
    用于从低熔体指数树脂制备泡沫制品的组合物

    公开(公告)号:WO2009085814A3

    公开(公告)日:2009-12-17

    申请号:PCT/US2008087149

    申请日:2008-12-17

    CPC classification number: C08J9/08 C08J9/0014 C08J9/10 C08J2201/03 C08J2323/16

    Abstract: Foamed articles are prepared from a composition comprising a low MI polymer, e.g., an ethylene/alpha-olefin copolymer with a density of less than 0,91 g/cc and an MI of less than 3 g/10 min, a chemical blowing agent, e.g., azodicarbonamide, a scorch inhibitor, e.g, a TEMPO compound, and, optionally, a free radical initiator, e.g., peroxide. If the composition does not comprise a free radical initiator, then it is exposed to a source of free radicals before and/or during the foaming process, e.g., e-beam or UV-light. The composition is compounded and foamed using conventional process equipment and conditions.

    Abstract translation: 发泡制品由包含低MI聚合物,例如密度小于0.91g / cc和MI小于3g / 10min的乙烯/α-烯烃共聚物的组合物制备,化学发泡剂 ,例如偶氮二甲酰胺,焦烧抑制剂,例如TEMPO化合物,和任选的自由基引发剂,例如过氧化物。 如果组合物不包含自由基引发剂,则其在发泡过程之前和/或期间暴露于自由基源,例如电子束或UV光。 使用常规工艺设备和条件将组合物复合并发泡。

    10.
    发明专利
    未知

    公开(公告)号:BRPI0715572A2

    公开(公告)日:2013-07-02

    申请号:BRPI0715572

    申请日:2007-10-09

    Abstract: The present invention is an article of construction formed from an article adhesively-bonded to a layering material through (a) reactive coupling of a functionalized nitroxide or (b) the adhesion of components in a polymer matrix made from or containing a polymer, an organic peroxide, and a functionalized nitroxide. The initial article may be expanded. It may also be polar or nonpolar. Similarly, the layering material may be polar or nonpolar. Other embodiments of the present invention are described, including other articles and methods for preparing the articles. The useful articles of the present invention include shoe outsoles and midsoles, paints, overmolded articles, weather stripping, gaskets, profiles, belts, hoses, tubes, durable goods, tires, construction panels, leisure and sports equipment foams, energy management foams, acoustic management foams, insulation foams, other foams, automotive parts (including bumper fascias, vertical panels, soft thermoplastic polyolefin skins, and interior trim), toys, supported films (including single-ply and co-extruded films), glass laminations, leather articles (synthetic and natural), personal health care and hygiene articles, other metal laminates, wood composites, automotive belts, hoses, tubes, conveyor belts, footwear, sporting goods, and filled articles.

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