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公开(公告)号：WO2013096631A1
公开(公告)日：2013-06-27
申请号：PCT/US2012/070970
申请日：2012-12-20
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： CLARK, Thomas P. , SPINNEY, Heather , MACDONALD, Jason , CUMMINS, Clark , KLOSIN, Jerzy , BRIGGS, John
CPC classification number: B01J31/2295 , B01J31/0231 , B01J31/2409 , B01J31/2452 , B01J2231/321 , B01J2231/4288 , B01J2531/822 , C07C29/09 , C07C51/48 , C07F9/5027 , C07F9/65517 , C07C57/04
Abstract: A catalytic system for reductive carbonylation of an alcohol that includes a rhodium complex, an iodide-containing catalyst promoter, and a supporting phosphorus-containing bidentate ligand for the rhodium complex containing at least one aromatic substituent covalently attached to at least one phosphorus of the supporting phosphorus-containing bidentate ligand in an ortho position with an alkoxy substituent or an aryloxy substituent.
Abstract translation: 一种用于还原羰基化醇的催化体系，其包括铑络合物，含碘化物的催化剂促进剂和用于含有至少一个芳香族取代基的铑络合物的支持含磷二齿配体，所述芳族取代基共价连接至至少一个支持的磷的芳族取代基 邻位的含磷二齿配位体与烷氧基取代基或芳氧基取代基。
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公开(公告)号：WO2014039551A1
公开(公告)日：2014-03-13
申请号：PCT/US2013/058054
申请日：2013-09-04
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： ARROWOOD, Tina , MACDONALD, Jason
IPC: C07D241/04 , C07D295/04
CPC classification number: C07D295/088 , B01J27/232 , B01J31/0225 , B01J31/0244 , B01J31/16 , C07D241/04 , C07D295/04 , Y02P20/582
Abstract: A process for selectively preparing dihydroxyethyl piperazine by reacting hydroxyethyloxazolidinone with an acid catalyst wherein the selectivity of hydroxyethyloxazolidinone to dihydroxyethyl piperazine is at least 55%.
Abstract translation: 羟基乙基恶唑烷酮与酸催化剂反应选择性制备二羟乙基哌嗪的方法，其中羟乙基恶唑烷酮对二羟基乙基哌嗪的选择性至少为55％。
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公开(公告)号：EP2401077A1
公开(公告)日：2012-01-04
申请号：EP10707162.3
申请日：2010-02-25
Applicant: Dow Global Technologies LLC
Inventor： ARROWOOD, Tina , MACDONALD, Jason , OCCHIELLO, Ernesto , ELOWE, Paul
CPC classification number: B01J31/2243 , B01J21/08 , B01J31/1633 , B01J31/2252 , B01J2231/34 , B01J2231/349 , B01J2531/0216 , B01J2531/0252 , B01J2531/845 , C07C41/03 , C07C41/44 , C07C43/13
Abstract: A process of contacting an alkylene oxide with 2-methoxy-1-propanol (PM1) in the presence of an oligomeric Schiff base metal complex catalyst is disclosed. Further, a process involving contacting an alkylene oxide with an alkyl alcohol using an oligomeric Schiff base metal complex as a catalyst is also disclosed. Additionally, novel compositions which can be used as catalysts in processes involving the contacting of an alkyl alcohol with an alkylene oxide are also disclosed.
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4.发明公开
公开(公告)号：EP2401075A1
公开(公告)日：2012-01-04
申请号：EP10705968.5
申请日：2010-02-25
Applicant: Dow Global Technologies LLC
Inventor： ARROWOOD, Tina , NICKIAS, Peter , DEGROOT, Marty , VERRAL, Daniel , ELOWE, Paul , MACDONALD, Jason , FLICK, Derrick, W.
CPC classification number: B01J31/2243 , B01J21/08 , B01J31/1633 , B01J31/2252 , B01J2231/34 , B01J2231/349 , B01J2531/0216 , B01J2531/0252 , B01J2531/845 , C07C41/03 , C07C41/44 , C07C43/13
Abstract: A process of contacting an alkylene oxide with 2-methoxy-1-propanol (PM1) in the presence of an oligomeric Schiff base metal complex catalyst is disclosed. Further, a process involving contacting an alkylene oxide with an alkyl alcohol using an oligomeric Schiff base metal complex as a catalyst is also disclosed. Additionally, novel compositions which can be used as catalysts in processes involving the contacting of an alkyl alcohol with an alkylene oxide are also disclosed.
Abstract translation: 公开了在低聚希夫碱金属配合物催化剂存在下使烯化氧与2-甲氧基-1-丙醇（PM1）接触的方法。 此外，还公开了使用低聚希夫碱金属络合物作为催化剂使烯化氧与烷基醇接触的方法。 此外，还公开了可用作烷烃与环氧烷接触的方法中的催化剂的新型组合物。
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Patent Agency Ranking
公开(公告)号：EP2401313A1
公开(公告)日：2012-01-04
申请号：EP10705966.9
申请日：2010-02-25
Applicant: Dow Global Technologies LLC
Inventor： CARLBERG, Philip , YOUNG, Thomas , ARROWOOD, Tina , OCCHIELLO, Ernesto , ELOWE, Paul , MACDONALD, Jason
IPC: C08G59/04
CPC classification number: C08G65/38 , C08G2650/56
Abstract: A process comprising contacting a polyhydric phenol or a polyaliphatic alcohol with an epihalohydrin in the presence of a catalyst comprising a Schiff base metal complex is disclosed.
Abstract translation: 公开了一种包括在包含希夫碱金属络合物的催化剂存在下使多元酚或聚脂族醇与表卤代醇接触的方法。
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公开(公告)号：EP2401076A1
公开(公告)日：2012-01-04
申请号：EP10705969.3
申请日：2010-02-25
Applicant: Dow Global Technologies LLC
Inventor： ARROWOOD, Tina , MACDONALD, Jason
CPC classification number: B01J31/2243 , B01J21/08 , B01J31/1633 , B01J31/2252 , B01J2231/34 , B01J2231/349 , B01J2531/0216 , B01J2531/0252 , B01J2531/845 , C07C41/03 , C07C41/44 , C07C43/13
Abstract: A process of contacting an alkylene oxide with 2-methoxy-1-propanol (PM1) in the presence of an oligomeric Schiff base metal complex catalyst is disclosed. Further, a process involving contacting an alkylene oxide with an alkyl alcohol using an oligomeric Schiff base metal complex as a catalyst is also disclosed. Additionally, novel compositions which can be used as catalysts in processes involving the contacting of an alkyl alcohol with an alkylene oxide are also disclosed.
Abstract translation: 公开了在低聚Schiff碱金属配合物催化剂存在下使烯化氧与2-甲氧基-1-丙醇（PM1）接触的方法。 此外，还公开了使用低聚Schiff碱金属配合物作为催化剂使烯化氧与烷基醇接触的方法。 另外，还公开了可用作催化剂的新型组合物，该方法涉及烷基醇与烯化氧的接触。
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公开(公告)号：EP2401074A1
公开(公告)日：2012-01-04
申请号：EP10705967.7
申请日：2010-02-25
Applicant: Dow Global Technologies LLC
Inventor： ARROWOOD, Tina , FLICK, Derrick , ELOWE, Paul , MACDONALD, Jason
CPC classification number: B01J31/2243 , B01J21/08 , B01J31/1633 , B01J31/2252 , B01J2231/34 , B01J2231/349 , B01J2531/0216 , B01J2531/0252 , B01J2531/845 , C07C41/03 , C07C41/44 , C07C43/13
Abstract: A process of contacting an alkylene oxide with 2-methoxy-1-propanol (PM1) in the presence of an oligomeric Schiff base metal complex catalyst is disclosed. Further, a process involving contacting an alkylene oxide with an alkyl alcohol using an oligomeric Schiff base metal complex as a catalyst is also disclosed. Additionally, novel compositions which can be used as catalysts in processes involving the contacting of an alkyl alcohol with an alkylene oxide are also disclosed.
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公开(公告)号：EP2892883B1
公开(公告)日：2016-10-26
申请号：EP13780242.7
申请日：2013-09-04
Applicant: Dow Global Technologies LLC
Inventor： ARROWOOD, Tina , MACDONALD, Jason
IPC: C07D241/04 , C07D295/04
CPC classification number: C07D295/088 , B01J27/232 , B01J31/0225 , B01J31/0244 , B01J31/16 , C07D241/04 , C07D295/04 , Y02P20/582
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公开(公告)号：EP2892883A1
公开(公告)日：2015-07-15
申请号：EP13780242.7
申请日：2013-09-04
Applicant: Dow Global Technologies LLC
Inventor： ARROWOOD, Tina , MACDONALD, Jason
IPC: C07D241/04 , C07D295/04
CPC classification number: C07D295/088 , B01J27/232 , B01J31/0225 , B01J31/0244 , B01J31/16 , C07D241/04 , C07D295/04 , Y02P20/582
Abstract: A process for selectively preparing dihydroxyethyl piperazine by reacting hydroxyethyloxazolidinone with an acid catalyst wherein the selectivity of hydroxyethyloxazolidinone to dihydroxyethyl piperazine is at least 55%.
Abstract translation: 通过使羟乙基恶唑烷酮与酸催化剂反应选择性制备二羟乙基哌嗪的方法，其中羟乙基恶唑烷酮对二羟乙基哌嗪的选择性至少为55％。
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