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    HYPERBRANCHED ETHYLENE-BASED OLIGOMERS
    4.
    发明申请
    HYPERBRANCHED ETHYLENE-BASED OLIGOMERS 审中-公开
    超乙烯基乙烯基低聚物

    公开(公告)号：WO2014209927A1

    公开(公告)日：2014-12-31

    申请号：PCT/US2014/043754

    申请日：2014-06-24

    Applicant: DOW GLOBAL TECHNOLOGIES LLC

    Inventor： ARRIOLA, Daniel J. ,  BAILEY, Brad C. ,  KLOSIN, Jerzy ,  LYSENKO, Zenon ,  ROOF, Gordon R. ,  SMITH, Austin J.

    IPC: C07C2/32 ,  C08F4/64 ,  B01J31/22

    CPC classification number: B01J31/2239 ,  B01J2231/20 ,  B01J2531/0241 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  C08F110/02 ,  C08F4/64193 ,  C08F2500/02

    Abstract: A process to prepare a relatively inexpensive utility fluid comprises contacting together ethylene and a coordination-insertion catalyst and, optionally, an alpha-olefin, in a continuously-fed backmixed reactor zone under conditions such that a mixture of a hyperbranched oligomer and a branched oligomer is formed. The hyperbranched oligomer has an average of at least 1.5 methine carbons per oligomer molecule, and at least 40 methine carbons per one-thousand total carbons, and at least 40 percent of the methine carbons is derived from the ethylene, and the average number of carbons per molecule is from 25 to 100, and at least 25 percent of the hyperbranched oligomer molecules has a vinyl group and can be separated from the branched oligomer, which has an average number of carbons per molecule of up to 20. The coordination-insertion catalyst is characterized as having an ethylene/octene reactivity ratio up to 20 and a kinetic chain length up to 20 monomer units.

    Abstract translation: 制备相对廉价的实用流体的方法包括在连续供给的反混混合反应器区域中将乙烯和配位插入催化剂和任选的α-烯烃在一起使得超支化低聚物和支链低聚物的混合物 形成了。 超支化低聚物每个低聚物分子平均具有至少1.5个次甲基碳，每千个总碳中至少有40个次甲基碳，至少40％的次甲基碳源自乙烯，平均碳数 每个分子为25至100，并且至少25％的超支化低聚物分子具有乙烯基并且可以与支化低聚物分离，其具有每分子平均碳数高达20个。配位插入催化剂 其特征在于具有高达20的乙烯/辛烯反应性比和至多20个单体单元的动力链长度。

    NON-CYCLOPENTADIENYL-BASED CHROMIUM CATALYSTS FOR OLEFIN POLYMERIZATION
    5.
    发明申请
    NON-CYCLOPENTADIENYL-BASED CHROMIUM CATALYSTS FOR OLEFIN POLYMERIZATION 审中-公开
    用于烯烃聚合的非环丙烯二酸的铬催化剂

    公开(公告)号：WO2012155022A1

    公开(公告)日：2012-11-15

    申请号：PCT/US2012/037462

    申请日：2012-05-11

    Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  CHRISTIANSON, Matthew D. ,  DE VRIES, Timothy S. ,  FROESE, Robert D. ,  OBER, Matthias S. ,  PATTON, Jasson T. ,  ROMER, Duane R. ,  ROOF, Gordon R. ,  SUN, Lixin ,  SZUROMI, Endre ,  THERIAULT, Curt N. ,  WELSH, Dean M. ,  WENZEL, Timothy T. ,  MORAN, Paul H.

    Inventor： CHRISTIANSON, Matthew D. ,  DE VRIES, Timothy S. ,  FROESE, Robert D. ,  OBER, Matthias S. ,  PATTON, Jasson T. ,  ROMER, Duane R. ,  ROOF, Gordon R. ,  SUN, Lixin ,  SZUROMI, Endre ,  THERIAULT, Curt N. ,  WELSH, Dean M. ,  WENZEL, Timothy T. ,  MORAN, Paul H.

    IPC: C07F11/00 ,  C08F4/69 ,  C08F4/60

    CPC classification number: C08F4/78 ,  C07F11/00 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/06 ,  C08F4/69112 ,  C08F210/16 ,  C08F2500/15

    Abstract: Provided is a non-cyclopentadienyl-based chromium-ligand complex, preferably a chromium-ligand complex of formula (J): LCr(R A ) m (D) k (J), wherein L is a non-Cp monoanionic ligand; Cr (chromium) is in a formal oxidation state of +3 or +2; when Cr formally is Cr +3 , either m is 1 and R A is hydrocarbylene (a hydrocarbylene chromium-ligand complex of formula (J)) or m is 2 and each R A independently is hydrocarbyl (a dihydrocarbyl chromium-ligand complex of formula (J)), wherein each hydrocarbyl or hydrocarbylene of R A independently is unsubstituted or substituted by from 1 to 5 R AS ; each R AS independently is a neutral aprotic heteroalkyl, neutral aprotic heterocycloalkyl, neutral aprotic heteroaryl, or neutral aprotic aryl; when Cr formally is Cr +2 , m is 1 and R A is hydrocarbyl (a hydrocarbyl chromium-ligand complex of formula (J)); k is an integer of 0 or 1; D is absent when k is 0 or D is a neutral ligand when k is 1; wherein the chromium-ligand complex of formula (J) is overall neutral and lacks a cyclopentadienyl-based (Cp-based) moiety. Also provided is a chromium catalyst comprising or prepared from the complex. Also provided is a process of making the catalyst and a process employing the chromium catalyst for polymerizing the olefin monomer, especially a straight chain 1-alkene, to prepare the polyolefin, especially a partially chain-straightened poly( 1-alkene) or olefin block copolymer. Further provided is the partially chain- straightened poly( 1-alkene) or olefin block copolymer prepared thereby. Also provided is a high throughput workflow.

    Abstract translation: 提供非环戊二烯基铬配体络合物，优选式（J）的铬 - 配体络合物：LCr（RA）m（D）k（J），其中L是非-C 1单阴离子配体; Cr（铬）处于+3或+2的正式氧化态; 当Cr正式为Cr + 3时，m为1，RA为亚烃基（式（J））的亚烃基铬 - 配体配合物）或m为2，各RA独立地为烃基（式（J）的二烃基铬 - 配体络合物 ）），其中RA的各个烃基或亚烃基独立地未被取代或被1至5个RAS取代; 每个RAS独立地是中性非质子杂烷基，中性非质子杂环烷基，中性非质子杂芳基或中性非质子性芳基; 当Cr正式为Cr + 2时，m为1，RA为烃基（式（J））的烃基铬 - 配体络合物）; k是0或1的整数; 当k为0时，D不存在，或当k为1时D为中性配体; 其中式（J）的铬配体络合物是总体中性的，并且缺少基于环戊二烯基的（Cp-基）部分。 还提供了包含或由络合物制备的铬催化剂。 还提供了制备催化剂的方法和使用铬催化剂聚合烯烃单体，特别是直链1-烯烃的方法，以制备聚烯烃，特别是部分链改性的聚（1-烯烃）或烯烃嵌段 共聚物。 进一步提供由其制备的部分链直链化的聚（1-烯烃）或烯烃嵌段共聚物。 还提供了高吞吐量的工作流程。

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