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    AQUEOUS EMULSION
    3.
    发明申请
    AQUEOUS EMULSION 审中-公开
    水乳液

    公开(公告)号：WO2011073417A1

    公开(公告)日：2011-06-23

    申请号：PCT/EP2010/070136

    申请日：2010-12-17

    Applicant: DSM IP Assets B.V. ,  NABUURS, Tijs ,  OVERBEEK, Gerardus Cornelis ,  STUBBS, Jeffrey

    Inventor： NABUURS, Tijs ,  OVERBEEK, Gerardus Cornelis ,  STUBBS, Jeffrey

    IPC: C08F265/04 ,  C08F267/06 ,  C08L35/02

    CPC classification number: C09D135/02 ,  C08F212/08 ,  C08F220/18 ,  C08F222/14 ,  C08F265/04 ,  C08F267/06 ,  C08F2220/1808 ,  C08F2220/1825 ,  C08F2220/1833 ,  C08L35/02 ,  Y10T428/31935 ,  C08L2666/04 ,  C08L2666/02

    Abstract: The invention relates to an aqueous emulsion comprising at least a vinyl polymer, said vinyl polymer comprising: a) 45 to 99 wt% of itaconate ester monomers having formula (I), wherein R and R' are independently an alkyl or an aryl group; b) 0.1 to 15 wt% of ionic or potentially ionic unsaturated monomers; c) 0 to 54 wt% of unsaturated monomers, different from a) and b); and 0.9 to 54.9 wt% by weight of total monomers of a chaser monomer composition added subsequently and polymerised after the polymerisation of monomers a), b) and c); wherein a) + b) + c) and the chaser monomer composition add up to 100 %; and wherein the aqueous emulsion contains less than 0.5 wt% free itaconate ester monomers of formula I based on the total weight of the aqueous emulsion.

    Abstract translation: 本发明涉及包含至少一种乙烯基聚合物的水乳液，所述乙烯基聚合物包含：a）45至99重量％的具有式（I）的衣康酸酯单体，其中R和R'独立地为烷基或芳基; b）0.1至15重量％的离子或潜在的离子不饱和单体; c）0至54重量％的不饱和单体，不同于a）和b）; 和0.9至54.9重量％的随后加入的追踪单体组合物的单体的总量，并且在单体a），b）和c）的聚合之后聚合。 其中a）+ b）+ c）和所述追踪单体组合物总计高达100％; 并且其中基于所述水性乳液的总重量，所述水性乳液含有小于0.5重量％的式I的游离的衣康酸酯单体。

    USE OF A POLYMER COMPOSITION
    4.
    发明申请
    USE OF A POLYMER COMPOSITION 审中-公开
    聚合物组合物的使用

    公开(公告)号：WO2013113938A1

    公开(公告)日：2013-08-08

    申请号：PCT/EP2013/052174

    申请日：2013-02-04

    Applicant: DSM IP ASSETS B.V.

    Inventor： NABUURS, Tijs ,  OVERBEEK, Gerardus Cornelis ,  STUBBS, Jeffrey ,  GEBHARD, Matthew Stewart

    IPC: C08L35/02 ,  C08F222/14 ,  A61K8/81 ,  C09D135/02

    CPC classification number: C08F222/12 ,  A61K8/8152 ,  A61K8/8158 ,  A61K2800/10 ,  A61Q19/00 ,  C08F220/10 ,  C08F222/14 ,  C08F2220/1825 ,  C08L33/12 ,  C08L35/02 ,  C08F220/14 ,  C08F220/06

    Abstract: There is described use of a biorenewable copolymers in one or more of: in a topical and/or personal care composition, as a binder for toner, as an encapsulating agent for a colorant, as a hybrid colorant, as additive for sheet moulding compounds, as a plastic pigment, as a filler for composite materials such as concrete, as a filler for coatings and/or waxes; and/or as a spacer in a display; where the biorenewable copolymer comprises (a) at least 8. 5 wt-% preferably >=20 wt-% of a higher itaconate diester (preferably dibutyl itaconate -DBI); (b) less than 23 wt-% acid monomer but also sufficient to have an acid value less than 150 mg KOH/g of polymer, (c) optionally with less than 50 wt-% of other itaconate monomers, and (d) optionally less than 77 wt-%of other monomers not (a) to (c). The DBI may be biorenewable. One embodiment is an aqueous dispersion of vinyl sequential polymer of two phases: A) 40 to 90 wt-% of a vinyl polymer A with Tg from -50 to 30°C; and B) 10 to 60 wt-% of a vinyl polymer B with Tg from 50 to 130°C; where DBI is used to prepare A and/or B and polymer A has from 0.1 to 10 wt-% of at least one acid-functional olefinically unsaturated monomer.

    Abstract translation: 描述了在局部和/或个人护理组合物中作为调色剂的粘合剂，作为着色剂的包封剂，作为混合着色剂的片剂模塑化合物的添加剂中的一种或多种的生物可再生共聚物的用途， 作为塑料颜料，作为复合材料如混凝土的填料，作为涂料和/或蜡的填料; 和/或作为显示器中的间隔物; 其中生物可再生共聚物包含（a）至少8.5重量％，优选> = 20重量％的较高的衣康酸二酯（优选二丁基衣康酸酯-DBI）; （b）小于23重量％的酸单体，但也足以使酸值小于150mg KOH / g的聚合物，（c）任选地含有少于50重量％的其它衣康酸酯单体，和（d）任选地 不超过77重量％的其它单体（a）至（c）。 DBI可能是biorenewable。 一个实施方案是两相的乙烯基连续聚合物的水分散体：A）40至90重量％的Tg为-50至30℃的乙烯基聚合物A; 和B）10至60重量％的Tg为50至130℃的乙烯基聚合物B; 其中DBI用于制备A和/或B，聚合物A具有0.1至10重量％的至少一种酸官能的烯属不饱和单体。

    AQUEOUS POLYMER EMULSION
    7.
    发明申请
    AQUEOUS POLYMER EMULSION 审中-公开
    水性聚合物乳液

    公开(公告)号：WO2016128574A1

    公开(公告)日：2016-08-18

    申请号：PCT/EP2016/053084

    申请日：2016-02-12

    Applicant: DSM IP ASSETS B.V.

    Inventor： NABUURS, Tijs ,  STUBBS, Jeffrey ,  DE BONT, Johannes Hendrikus ,  OVERBEEK, Gerardus Cornelis

    IPC: C08F222/14 ,  C09D135/02

    CPC classification number: C08F222/14 ,  C08F220/06 ,  C08F2220/1858 ,  C09D135/02 ,  C08F220/14

    Abstract: The present invention relates to an aqueous polymer emulsion comprising at least 30 wt.% of a vinyl copolymer (A), said vinyl copolymer comprising: (I) from 10 to 90 wt.% of 2-octyl acrylate monomer; (II)from 10 to 90 wt.% of at least one itaconate ester monomer according to formula (1), in which A and B may be different or the same and A and B are independently methyl or ethyl; and (III) from 0 to 80 wt.% of ethylenically unsaturated monomer other than (I) and (II); whereby the summed amount of (I), (II) and (III) is 100 wt.% and whereby the amount of vinyl copolymer (A) is given relative to the total weight amount of the polymers present in the emulsion.

    Abstract translation: 本发明涉及包含至少30重量％的乙烯基共聚物（A）的水性聚合物乳液，所述乙烯基共聚物包含：（I）10至90重量％的丙烯酸2-辛基酯单体; （II）10至90重量％的至少一种根据式（1）的衣康酸酯单体，其中A和B可以不同或相同，A和B独立地是甲基或乙基; 和（III）0至80重量％的除（I）和（II）之外的烯属不饱和单体; 其中（I），（II）和（III）的总量为100重量％，由此相对于存在于乳液中的聚合物的总重量，给出乙烯基共聚物（A）的量。

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