公开(公告)号：WO2007143201A1

公开(公告)日：2007-12-13

申请号：PCT/US2007/013158

申请日：2007-06-04

Applicant: E. I. DU PONT DE NEMOURS AND COMPANY ,  HERRON, Norman ,  WANG, Ying ,  PETROV, Viacheslav, A. ,  GUIDRY, Mark, A. ,  MERLO, Jeffrey, A. ,  DOBBS, Kerwin, D.

Inventor： HERRON, Norman ,  WANG, Ying ,  PETROV, Viacheslav, A. ,  GUIDRY, Mark, A. ,  MERLO, Jeffrey, A. ,  DOBBS, Kerwin, D.

IPC: C09K11/06 ,  H05B33/14 ,  C07F15/00 ,  H01L51/00

CPC classification number: C09K11/06 ,  C09K2211/1029 ,  C09K2211/185 ,  H05B33/14

Abstract: There are provided compounds of Formulae I and II: where: n is 1, 2 or 3; p is 0,1 or 2; the sum of n + p is 3; R 1 R 2 , R 3 and R 4 are each independently H, F, alkyl, (trialkylsilyl, triarylsilyl, aryl or substituted aryl. R 5 and R 7 are each independently alkyl or aryl; and R 6 is H or afkyl. R 8 is H, F, or alkyl There are also provided electronic devices containing such compounds.

Abstract translation: 提供式I和II的化合物：其中：n为1,2或3; p为0,1或2; n + p的和为3; R 1，R 2，R 3和R 4各自独立地为H，F，烷基，（三烷基甲硅烷基， 三芳基甲硅烷基，芳基或取代的芳基R 5和R 7各自独立地为烷基或芳基; R 6为H或烷基， SUP> 8是H，F或烷基还提供含有这些化合物的电子装置。

公开(公告)号：WO2015061198A1

公开(公告)日：2015-04-30

申请号：PCT/US2014/061311

申请日：2014-10-20

Applicant: E. I. DU PONT DE NEMOURS AND COMPANY

Inventor： HERRON, Norman ,  WU, Weishi ,  GAO, Weiying ,  DOGRA, Kalindi ,  DIAMOND, Samuel, R. ,  WEBER, Juergen ,  GUIDRY, Mark, A.

IPC: C07D209/82 ,  C07C211/54 ,  C09K11/06 ,  H01L51/50

CPC classification number: H01L51/006 ,  C07C211/61 ,  C07C2603/40 ,  C07D207/325 ,  C07D209/86 ,  C07D235/20 ,  C07D263/32 ,  C07D307/52 ,  C07D307/91 ,  C07D333/20 ,  C07D333/76 ,  C07D405/14 ,  C07D519/00 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1022 ,  C09K2211/1029 ,  H01L51/0052 ,  H01L51/0054 ,  H01L51/0058 ,  H01L51/0061 ,  H01L51/0072 ,  H01L51/5012

Abstract: There is provided a compound having Formula (I). In the formula: R 1 , R 1a , R2, and R 2a are the same or different and are H, D, F, CN, alkyl, fluoroalkyl, aryl, heteroaryl, silyl, deuterated alkyl, deuterated partially-fluorinated alkyl, deuterated aryl, deuterated heteroaryl, deuterated silyl, alkoxy, aryloxy, fluoroalkoxy, siloxane, siloxy, deuteroalkoxy, deuteroaryloxy, deuterofluoroalkoxy, deuterosiloxane, or deuterosiloxy, with the proviso that at least one of R 1 and R 1a is heteroaryl or deuterated heteroaryl; R 3 , R3 a , R 4 , R 4a , R 5 , and R 6 are the same or different at each occurrence and are D, F, CN, alkyl, fluoroalkyl, aryl, heteroaryl, silyl, deuterated alkyl, deuterated partially- fluorinated alkyl, deuterated aryl, deuterated heteroaryl, deuterated silyl, alkoxy, aryloxy, fluoroalkoxy, siloxane, siloxy, deuteroalkoxy, deuteroaryloxy, deuterofluoroalkoxy, deuterosiloxane, or deuterosiloxy, where adjacent groups selected from R 3 , R 3a , R 4 , and R 4a can be joined together to form a fused ring; R 7 is the same or different at each occurrence and is alkyl, aryl, or deuterated analogs thereof, where two alkyl R 7 groups can be joined together to make a cycloalkyi spiro ring, and where two R 7 phenyl groups can be joined to form a spiro fluorene group; a and b are the same or different and are 0 or 1, with the proviso that a + b ≥ 1; x is an integer of 0- 3; y is an integer of 0-4; and z is an integer of 0-5.

Abstract translation: 提供具有式（I）的化合物。 式中R1，R1a，R2和R2a相同或不同，为H，D，F，CN，烷基，氟代烷基，芳基，杂芳基，甲硅烷基，氘化烷基，氘化部分氟化烷基，氘化芳基，氘化 杂芳基，氘代甲硅烷基，烷氧基，芳氧基，氟代烷氧基，硅氧烷，甲硅烷氧基，氘代烷氧基，氘代氧基，氘代氟烷氧基，氘代硅氧烷或氘代甲硅烷氧基，条件是R 1和R 1a中的至少一个是杂芳基或氘代杂芳基; D，F，CN，烷基，氟烷基，芳基，杂芳基，甲硅烷基，氘代烷基，氘代部分氟化烷基，氘化芳基， 氘代杂芳基，氘代甲硅烷基，烷氧基，芳氧基，氟代烷氧基，硅氧烷，甲硅烷氧基，氘代烷氧基，氘代氧基，氘代氟烷氧基，氘代硅氧烷或氘代甲硅氧基，其中相邻的选自R3，R3a，R4和R4a的基团可以连接在一起形成稠环; R7在每次出现时相同或不同，为烷基，芳基或氘代类似物，其中两个烷基R7基团可以连接在一起形成环烷基螺环，并且其中两个R7苯基可以连接形成螺芴 组; a和b相同或不同，为0或1，条件是a +b≥1; x是0-3的整数; y是0-4的整数; z为0-5的整数。

公开(公告)号：WO2012087961A2

公开(公告)日：2012-06-28

申请号：PCT/US2011/065894

申请日：2011-12-19

Applicant: E. I. DU PONT DE NEMOURS AND COMPANY ,  DOBBS, Kerwin, D. ,  FENNIMORE, Adam ,  GAO, Weiying ,  GUIDRY, Mark, A. ,  HERRON, Norman ,  RADU, Nora, Sabina ,  ROSSI, Gene, M. ,  SCHUMACHER, Gabriel, C.

Inventor： DOBBS, Kerwin, D. ,  FENNIMORE, Adam ,  GAO, Weiying ,  GUIDRY, Mark, A. ,  HERRON, Norman ,  RADU, Nora, Sabina ,  ROSSI, Gene, M. ,  SCHUMACHER, Gabriel, C.

IPC: C09K11/06 ,  H05B33/14 ,  H01L51/50 ,  H01L51/05

CPC classification number: H01L51/5024 ,  C09K11/06 ,  C09K2211/1059 ,  H01L51/0067 ,  H01L51/0072 ,  H01L51/0074 ,  H01L51/0566 ,  H01L51/5012 ,  H01L2251/5384 ,  H05B33/14

Abstract: This invention relates to a composition including (a) a dopant, (b) a first host having at least one unit of Formula I, and (c) a second host compound. Formula I has the structure INSERT FORMULA I HERE In Formula I: Ar 1 , Ar 2 , and Ar 3 are the same or different and are H, D, or aryl groups. At least two of Ar 1 , Ar 2 , and Ar 3 are aryl and none of Ar 1 , Ar 2 , and Ar 3 includes an indolocarbazole moiety.

Abstract translation: 本发明涉及包含（a）掺杂剂的组合物，（b）具有至少一个式I单元的第一主体和（c）第二主体化合物。 式I具有结构式I式在式I中：Ar 1，Ar 2和Ar 3相同或不同，为H，D或芳基。 Ar1，Ar2和Ar3中的至少两个是芳基，Ar1，Ar2和Ar3都不包括吲哚并咔唑部分。

公开(公告)号：WO2012087960A1

公开(公告)日：2012-06-28

申请号：PCT/US2011/065889

申请日：2011-12-19

Applicant: E. I. DU PONT DE NEMOURS AND COMPANY ,  DOBBS, Kerwin, D. ,  FENNIMORE, Adam ,  GAO, Weiying ,  GUIDRY, Mark, A. ,  HERRON, Norman ,  RADU, Nora, Sabina ,  ROSSI, Gene, M. ,  SCHUMACHER, Gabriel, C.

Inventor： DOBBS, Kerwin, D. ,  FENNIMORE, Adam ,  GAO, Weiying ,  GUIDRY, Mark, A. ,  HERRON, Norman ,  RADU, Nora, Sabina ,  ROSSI, Gene, M. ,  SCHUMACHER, Gabriel, C.

IPC: C07D251/24 ,  C07D401/10 ,  C07D401/14 ,  C07D403/10 ,  C07D409/10 ,  H05B33/12

CPC classification number: H01L51/0074 ,  C07D251/24 ,  C07D401/10 ,  C07D401/14 ,  C07D403/10 ,  C07D409/10 ,  C09K11/06 ,  H01L51/0072 ,  H01L51/0545

Abstract: There is provided a compound having at least one unit of Formula I (Formula I should be inserted here) where Ar 1 , Ar 2 , and Ar 3 are the same or different and have Formula II (Formular II should be inserted here) In Formula II: R 1 is the same or different at each occurrence and is D, alkyl, or silyl, or adjacent R 1 groups can be joined together to form a 6-membered fused aromatic ring; Q is the same or different at each occurrence and is phenyl, naphthyl, substituted naphthyl, an N,O,S heterocycle, or a deuterated analog thereof; a is an integer from 1 5; b is an integer from 0-5, with the proviso that when b = 5, c = 0; and c is an integer from 0-4. In the compound not all Ar 1 , Ar 2 , and Ar 3 are the same.

Abstract translation: 提供了具有至少一个式I单元的化合物（式I应该在此插入），其中Ar1，Ar2和Ar3相同或不同并具有式II（式II应该插入）在式II中：R1 在每次出现时相同或不同，为D，烷基或甲硅烷基，或相邻的R 1基团可以连接在一起形成6元稠合芳环; Q在每次出现时相同或不同，为苯基，萘基，取代萘基，N，O，S杂环或其氘代类似物; a是从1 5的整数; b是0-5的整数，条件是当b = 5时，c = 0; c是0-4的整数。 在化合物中，不是全部Ar1，Ar2和Ar3都相同。

公开(公告)号：WO2012082743A1

公开(公告)日：2012-06-21

申请号：PCT/US2011/064654

申请日：2011-12-13

Applicant: E. I. du Pont de Nemours and Company ,  GAO, Weiying ,  HERRON, Norman ,  GUIDRY, Mark, A.

Inventor： GAO, Weiying ,  HERRON, Norman ,  GUIDRY, Mark, A.

IPC: C09K11/06 ,  H05B33/14

CPC classification number: H01L51/0058 ,  C07D209/82 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0072 ,  H01L51/44 ,  H01L51/5012 ,  H01L2251/552 ,  H05B33/10

Abstract: There is provided an electroactive compound having Formula I In the formula: Ar 1 , Ar 2 , and Ar 3 are the same or different and are aryl groups; R 1 is the same or different at each occurrence and is D, alkyl or aryl; a is an integer from 0-4. The compound has a LUMO level deeper than -2.3 eV and a band gap of at least 2.9 eV.

Abstract translation: 提供具有式I的电活性化合物在式中：Ar 1，Ar 2和Ar 3相同或不同，为芳基; R1在每次出现时相同或不同，为D，烷基或芳基; a是0-4的整数。 该化合物具有比-2.3eV更深的LUMO能级和至少2.9eV的带隙。

公开(公告)号：WO2010075379A2

公开(公告)日：2010-07-01

申请号：PCT/US2009/069184

申请日：2009-12-22

Applicant: E. I. DU PONT DE NEMOURS AND COMPANY ,  HERRON, Norman ,  GUIDRY, Mark, A. ,  ROSTOVTSEV, Vsevolod ,  GAO, Weiying ,  WANG, Ying ,  SHEN, Yulong ,  MERLO, Jeffrey, A.

Inventor： HERRON, Norman ,  GUIDRY, Mark, A. ,  ROSTOVTSEV, Vsevolod ,  GAO, Weiying ,  WANG, Ying ,  SHEN, Yulong ,  MERLO, Jeffrey, A.

IPC: A01H1/00 ,  C12N15/29 ,  C07H21/04

CPC classification number: C07D471/04 ,  C07D201/00 ,  C07D471/16 ,  H01L51/0061 ,  H01L51/0072 ,  H01L51/5012 ,  H01L51/5024 ,  H01L51/5052 ,  H01L51/5072 ,  H01L2251/5384

Abstract: There is provided an organic electronic device having an anode, a hole injection layer, a photoactive layer, an electron transport layer, and a cathode. At least one of the photoactive layer and the electron transport layer includes a compound having Formula I where: R 1 is the same or different and can be phenyl, biphenyl, naphthyl, naphthylphenyl, triphenylamino, or carbazolylphenyl; and one of the following conditions is met: (i) R 2 = R 3 and is H, phenyl, biphenyl, naphthyl, naphthylphenyl, arylanthracenyl, phenanthryl, triphenylamino, or carbazolylphenyl; or (ii) R 2 is H or phenyl; and R 3 is phenyl, biphenyl, naphthyl, naphthylphenyl, arylanthracenyl, phenanthryl, triphenylamino, and carbazolylphenyl; When both R 1 are phenyl, R 2 and R 3 can be 2-naphthyl, naphthylphenyl, arylanthracenyl, 9-phenanthryl, triphenylamino, or m-carbazolylphenyl.

Abstract translation: 提供了具有阳极，空穴注入层，光活性层，电子传输层和阴极的有机电子器件。 光活性层和电子传输层中的至少一个包括具有式I的化合物，其中：R 1相同或不同，可以是苯基，联苯基，萘基，萘基苯基，三苯基氨基或咔唑基苯基; 满足以下条件之一：（i）R2 = R3，为H，苯基，联苯基，萘基，萘基苯基，芳基蒽基，菲基，三苯基氨基或咔唑基苯基; 或（ii）R 2为H或苯基; 联苯基，萘基，萘基苯基，芳基蒽基，菲基，三苯基氨基和咔唑基苯基; 当R 1都是苯基时，R 2和R 3可以是2-萘基，萘基苯基，芳基蒽基，9-菲基，三苯基氨基或间 - 咔唑基苯基。

公开(公告)号：WO2010071871A2

公开(公告)日：2010-06-24

申请号：PCT/US2009/068916

申请日：2009-12-21

Applicant: E. I. DU PONT DE NEMOURS AND COMPANY ,  HERRON, Norman ,  GAO, Weiying ,  FENNIMORE, Adam ,  GUIDRY, Mark, A.

Inventor： HERRON, Norman ,  GAO, Weiying ,  FENNIMORE, Adam ,  GUIDRY, Mark, A.

IPC: C09K11/06 ,  H01L51/50

CPC classification number: H01L51/006 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  H01L51/0072 ,  H01L51/5012 ,  H05B33/10 ,  H05B33/14

Abstract: This invention relates to anthracene derivatives that are useful in electroluminescent applications. It also relates to electronic devices in which the active layer includes such an anthracene derivative.

Abstract translation: 本发明涉及可用于电致发光应用的蒽衍生物。 它还涉及其中活性层包括这种蒽衍生物的电子器件。

公开(公告)号：EP2361009A2

公开(公告)日：2011-08-31

申请号：EP09835752.8

申请日：2009-12-22

Applicant: E. I. du Pont de Nemours and Company

Inventor： HERRON, Norman ,  GUIDRY, Mark, A. ,  ROSTOVTSEV, Vsevolod ,  GAO, Weiying ,  WANG, Ying ,  SHEN, Yulong ,  MERLO, Jeffrey, A.

IPC: A01H1/00 ,  C12N15/29 ,  C07H21/04

CPC classification number: C07D471/04 ,  C07D201/00 ,  C07D471/16 ,  H01L51/0061 ,  H01L51/0072 ,  H01L51/5012 ,  H01L51/5024 ,  H01L51/5052 ,  H01L51/5072 ,  H01L2251/5384

Abstract: There is provided an organic electronic device having an anode, a hole injection layer, a photoactive layer, an electron transport layer, and a cathode. At least one of the photoactive layer and the electron transport layer includes a compound having Formula I where: R
1 is the same or different and can be phenyl, biphenyl, naphthyl, naphthylphenyl, triphenylamino, or carbazolylphenyl; and one of the following conditions is met: (i) R
2 = R
3 and is H, phenyl, biphenyl, naphthyl, naphthylphenyl, arylanthracenyl, phenanthryl, triphenylamino, or carbazolylphenyl; or (ii) R
2 is H or phenyl; and R
3 is phenyl, biphenyl, naphthyl, naphthylphenyl, arylanthracenyl, phenanthryl, triphenylamino, and carbazolylphenyl; When both R
1 are phenyl, R
2 and R
3 can be 2-naphthyl, naphthylphenyl, arylanthracenyl, 9-phenanthryl, triphenylamino, or m-carbazolylphenyl.

公开(公告)号：EP2652084B1

公开(公告)日：2015-07-29

申请号：EP11809000.0

申请日：2011-12-13

Applicant: E. I. du Pont de Nemours and Company

Inventor： GAO, Weiying ,  HERRON, Norman ,  GUIDRY, Mark, A.

IPC: C09K11/06 ,  C07D209/82 ,  H01L51/00 ,  H01L51/44 ,  H01L51/50

CPC classification number: H01L51/0058 ,  C07D209/82 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0072 ,  H01L51/44 ,  H01L51/5012 ,  H01L2251/552 ,  H05B33/10

公开(公告)号：EP2197981A2

公开(公告)日：2010-06-23

申请号：EP08756403.5

申请日：2008-05-29

Applicant: E. I. Du Pont de Nemours and Company

Inventor： HERRON, Norman ,  GUIDRY, Mark, A. ,  ROSTOVTSEV, Vsevolod ,  NORTH, Victoria, J. ,  MERLO, Jeffrey, A. ,  DOGRA, Kalindi

IPC: C09K11/06 ,  H01L51/54

CPC classification number: C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  H01L51/0052 ,  H01L51/0058 ,  H01L51/006 ,  H01L51/0081 ,  H01L51/0084 ,  H01L51/5012 ,  H01L2251/308

Abstract: There is provided a green luminescent material having Formula I or Formula II; here R
1 and R
2 can be the same or different and can be hydrogen, alkoxy, tertiary alkyl, or cycloalkyl. R
3 and R
4 are the same or different and can be fluorine, aryl, or alkyl. There is also provided an organic electronic device containing the green luminescent material.