公开(公告)号：EP0593936A1

公开(公告)日：1994-04-27

申请号：EP93115443.9

申请日：1993-09-24

Applicant: ELF ATOCHEM NORTH AMERICA, INC.

Inventor： MacLeay, Ronald E. ,  Kmiec, Jennifer P. ,  Stein, Daryl L.

IPC: C07D249/20 ,  C08K5/3475 ,  C07D401/12 ,  C07F7/18 ,  C08K5/54

CPC classification number: C07D249/20 ,  C08K5/3475

Abstract: This invention relates to novel UV absorbers, their methods of preparation, their use in stabilizing polymers and polymers so stabilized against the degradative effects of UV light. The novel compounds of formula I are oxamides which are substituted on one or both nitrogens with
a 2-hydroxy-3-(2H-benzotriazol-2-yl)benzyl group. The 2-hydroxy-3-(2H-benzotriazol-2-yl)benzyl groups are efficient UV absorbing groups and the oxamide group contributes additional light stabilizing, heat stabilizing and metal complexing properties to the compounds. The compounds have low-volatility and are especially useful as UV stabilizers for engineering resins processed at high temperatures.

Abstract translation: 本发明涉及新的UV吸收剂，它们的制备方法，它们在稳定聚合物和聚合物中的用途，以抵抗UV光的降解作用。 式I的新化合物是在一个或两个氮与2-羟基-3-（2H-苯并三唑-2-基）苄基上取代的酰胺。 2-羟基-3-（2H-苯并三唑-2-基）苄基是有效的UV吸收基团，并且草酰胺基团赋予化合物额外的光稳定性，热稳定性和金属络合性质。 该化合物具有低挥发性，并且特别适用于在高温下加工的工程树脂的UV稳定剂。

公开(公告)号：EP0667339B1

公开(公告)日：1998-05-06

申请号：EP95101689.8

申请日：1995-02-08

Applicant: ELF ATOCHEM NORTH AMERICA, INC.

Inventor： Sanchez, Jose ,  Palys, Leonard H. ,  Stein, Daryl L. ,  Yormick, John S.

IPC: C07C409/20

CPC classification number: C07C409/40 ,  C07C409/16 ,  C07C409/20 ,  C07C409/22 ,  C07C409/38 ,  C08F4/36

公开(公告)号：EP0667339A1

公开(公告)日：1995-08-16

申请号：EP95101689.8

申请日：1995-02-08

Applicant: ELF ATOCHEM NORTH AMERICA, INC.

Inventor： Sanchez, Jose ,  Palys, Leonard H. ,  Stein, Daryl L. ,  Yormick, John S.

IPC: C07C409/20

CPC classification number: C07C409/40 ,  C07C409/16 ,  C07C409/20 ,  C07C409/22 ,  C07C409/38 ,  C08F4/36

Abstract: Novel unsaturated peroxide compositions of Structure A,
are disclosed where the R-Q- grouping contains a polymerizable carbon-carbon double bound, i.e. R is, inter alia, alkyl of 1 to 18 carbons; Q is, inter alia,
where -(X-Ri) shows the point of attachment of the X-R 1 group and (R)- shows the point of attachment of the R group to the Q diradical and R 2 and R 3 include hydrogen; -X- includes a direct bond and -R 1 is a peroxide-containing radical, e.g.,
wherein R 6 , R 7 , R 8 and R 9 are, inter alia, alkyl of 1 to 4 carbons and R 10 includes t-alkyl of 4 to 12 carbons. Further, polymeric peroxide compositions derived from them and their uses are disclosed.

Abstract translation: 公开了结构A，R-Q-X-R1A的新型不饱和过氧化物组合物，其中R-Q-分组含有可聚合碳 - 碳双键，即R特别是1至18个碳原子的烷基; Q特别是，其中 - （X-R1）表示X-R1基团的连接点，（R） - 表示R基团与Q二价基团的连接点，R 2表示 和R 3包括氢; -X-包括直接键，-R1是含过氧化物的基团，例如，其中R 6，R 7，R 8和R 9尤其是1至4个碳的烷基，R 10包括4至 12个碳。 此外，公开了衍生自它们的聚合物过氧化物组合物及其用途。