公开(公告)号：EP0723967A1

公开(公告)日：1996-07-31

申请号：EP96100214.4

申请日：1996-01-09

Applicant: ELF ATOCHEM NORTH AMERICA, INC.

Inventor： Silverman, Gary S. ,  Tseng, Kenneth K.S. ,  Uhm, Haewon L.

IPC: C07F9/141 ,  C09D5/16 ,  C08F30/04 ,  A01N57/12

CPC classification number: C07F9/1417 ,  A01N25/10 ,  C08F30/04 ,  C09D5/1625 ,  C09D5/1637

Abstract: Compounds of formula (I) are disclosed:

wherein L 1 is a main group atom, L 2 is a neutral ligand, M is a transition element or a metal element of Group 13, 14, 15, or 16 of the Periodic Table, x is the number of coordination sites of M, R 1 is a polymerizable group, R 2 , R 3 , and R 4 are ligands, and R 5 is an anionic ligand. The compounds or monomers of formula (I) are capable of conversion to polymers by combination with one or more other known monomers, such as methyl methacrylate. Such polymers can then be added as a binder in a paint formulation to make marine antifouling coating compositions. Also described is a method to prevent fouling on surfaces wherein a composition containing a metal complex compound of formula (II):

wherein M, x, L 2 , n, and R 4 have the same meaning as in formula (I), is applied to the surface susceptible to fouling.

Abstract translation: 公开了式（I）的化合物：其中L 1是主要原子的CHEM，L 2是中性配体，M是第13,14,15或15或15位的过渡元素或金属元素 16，x是M的配位点数，R 1是可聚合基团，R 2，R 3和R 4是配体，R 5是 阴离子配体。 式（I）的化合物或单体可以通过与一种或多种其它已知的单体如甲基丙烯酸甲酯的组合转化成聚合物。 然后可以将这样的聚合物作为粘合剂加入到油漆配方中以制备海洋防污涂料组合物。 还描述了一种防止在表面上结垢的方法，其中含有式（II）的金属络合物的组合物：其中M，x，L 2，n和R 4具有与下式 式（I），适用于容易污染的表面。

公开(公告)号：EP0723967B1

公开(公告)日：2001-04-11

申请号：EP96100214.4

申请日：1996-01-09

Applicant: ELF ATOCHEM NORTH AMERICA, INC.

Inventor： Silverman, Gary S. ,  Tseng, Kenneth K.S. ,  Uhm, Haewon L.

IPC: C07F9/141 ,  C09D5/16 ,  C08F30/04 ,  A01N57/12

CPC classification number: C07F9/1417 ,  A01N25/10 ,  C08F30/04 ,  C09D5/1625 ,  C09D5/1637