公开(公告)号：WO2006103371A2

公开(公告)日：2006-10-05

申请号：PCT/FR2006050272

申请日：2006-03-29

Applicant: ESSILOR INT ,  GUERRET OLIVIER ,  JAFFRENNOU BORIS ,  LESARTRE NOEMIE ,  MECHIN FRANCOISE ,  PASCAULT JEAN-PIERRE

Inventor： GUERRET OLIVIER ,  JAFFRENNOU BORIS ,  LESARTRE NOEMIE ,  MECHIN FRANCOISE ,  PASCAULT JEAN-PIERRE

CPC classification number: C08L75/04 ,  C08G2270/00 ,  C08L33/08 ,  G02B1/041 ,  C08L33/00 ,  C08L2666/04

Abstract: The invention relates to a polymerisable liquid mixture comprising: (a) a polymerisable thermosetting composition which is a precursor by polymerisation of a first thermoset polymer material, said composition containing at least one polythiol and/or one polyol, preferably a polythiol, and at least one polyiso(thio)cyanate; and (b) a second polymer material solubilised in the aforementioned polymerisable thermosetting composition, whereby the second material (i) contains at least one block copolymer comprising at least two polymer blocks A and B, namely an elastomer block A and a hydrophilic block B, and, following polymerisation of the polymerisable mixture, (ii) forms domains which are rich in elastomer block A and which are dispersed throughout the first material, said domains being smaller than 80 nanometers and preferably smaller than 50 nanometers. The invention also relates to a transparent article having improved toughness, which is produced by means of polymerisation of the above-mentioned polymerisable mixture, comprising an alloy of a first thermoset polymer material forming the matrix of said article and of a second polymer material which is dispersed throughout said first material. The aforementioned articles have improved resistance to impact and to crack propagation. The invention is suitable for use in ophthalmic optics.

Abstract translation: 本发明涉及一种可聚合液体混合物，其包含：（a）可聚合热固性组合物，其是通过第一热固性聚合物材料的聚合的前体，所述组合物含有至少一种多硫醇和/或一种多元醇，优选多硫醇，并且至少 一种多异（硫）氰酸酯; 并且（b）溶解在上述可聚合的热固性组合物中的第二聚合物材料，其中第二材料（i）含有至少一种包含至少两个聚合物嵌段A和B的嵌段共聚物，即弹性体嵌段A和亲水嵌段B， 并且在可聚合混合物聚合之后，（ii）形成富含弹性体嵌段A并且分散在整个第一材料中的畴，所述畴小于80纳米，优选小于50纳米。 本发明还涉及具有改进的韧性的透明制品，其通过上述可聚合混合物的聚合制备，其包含形成所述制品的基质的第一热固性聚合物材料和第二聚合物材料的合金，所述第二聚合物材料是 分散在所述第一材料中。 上述制品具有改善的抗冲击性和抗裂纹性。 本发明适用于眼科镜片。

公开(公告)号：AT416392T

公开(公告)日：2008-12-15

申请号：AT06726287

申请日：2006-03-29

Applicant: ESSILOR INT

Inventor： GUERRET OLIVIER ,  JAFFRENNOU BORIS ,  LESARTRE NOEMIE ,  MECHIN FRANCOISE ,  PASCAULT JEAN-PIERRE

IPC: G02B1/04

Abstract: The invention relates to a polymerisable liquid mixture comprising: (a) a polymerisable thermosetting composition which is a precursor by polymerization of a first thermoset polymer material, said composition containing at least one polythiol and/or one polyol, preferably a polythiol, and at least one polyiso(thio)cyanate; and (b) a second polymer material solubilized in the aforementioned polymerisable thermosetting composition, whereby the second material (i) contains at least one block copolymer comprising at least two polymer blocks A and B, namely an elastomer block A and a hydrophilic block B, and, following polymerization of the polymerisable mixture, (ii) forms domains which are rich in elastomer block A and which are dispersed throughout the first material, said domains being smaller than 80 nanometers and preferably smaller than 50 nanometers. The invention also relates to a transparent article having improved toughness, which is produced by means of polymerization of the above-mentioned polymerisable mixture, comprising an alloy of a first thermoset polymer material forming the matrix of said article and of a second polymer material which is dispersed throughout said first material. The aforementioned articles have improved resistance to impact and to crack propagation. The invention is suitable for use in ophthalmic optics.

公开(公告)号：FR2883880B1

公开(公告)日：2007-05-11

申请号：FR0550847

申请日：2005-03-31

Applicant: ESSILOR INT

Inventor： GUERRET OLIVIER ,  JAFFRENNOU BORIS ,  LESARTRE NOEMIE ,  MECHIN FRANCOISE ,  PASCAULT JEAN PIERRE

IPC: C08L75/04 ,  C08G18/72 ,  C08L53/02 ,  G02B1/04 ,  G02C7/02

Abstract: The invention relates to a polymerisable liquid mixture comprising: (a) a polymerisable thermosetting composition which is a precursor by polymerization of a first thermoset polymer material, said composition containing at least one polythiol and/or one polyol, preferably a polythiol, and at least one polyiso(thio)cyanate; and (b) a second polymer material solubilized in the aforementioned polymerisable thermosetting composition, whereby the second material (i) contains at least one block copolymer comprising at least two polymer blocks A and B, namely an elastomer block A and a hydrophilic block B, and, following polymerization of the polymerisable mixture, (ii) forms domains which are rich in elastomer block A and which are dispersed throughout the first material, said domains being smaller than 80 nanometers and preferably smaller than 50 nanometers. The invention also relates to a transparent article having improved toughness, which is produced by means of polymerization of the above-mentioned polymerisable mixture, comprising an alloy of a first thermoset polymer material forming the matrix of said article and of a second polymer material which is dispersed throughout said first material. The aforementioned articles have improved resistance to impact and to crack propagation. The invention is suitable for use in ophthalmic optics.

公开(公告)号：FR2883880A1

公开(公告)日：2006-10-06

申请号：FR0550847

申请日：2005-03-31

Applicant: ESSILOR INT

Inventor： GUERRET OLIVIER ,  JAFFRENNOU BORIS ,  LESARTRE NOEMIE ,  MECHIN FRANCOISE ,  PASCAULT JEAN PIERRE

IPC: C08L75/04 ,  C08G18/72 ,  C08L53/02 ,  G02B1/04 ,  G02C7/02

Abstract: La présente invention a pour objet un mélange polymérisable liquide comprenant (a) une composition polymérisable thermodurcissable, précurseur par polymérisation d'un premier matériau polymère thermodurci, ladite composition comprenant au moins un polythiol et/ou un polyol, préférentiellement un polythiol, et au moins un polyiso(thio)cyanate, (b) un second matériau polymère solubilisé dans ladite composition polymérisable thermodurcissable, ledit second matériau (i) comprenant au moins un copolymère à blocs comprenant au moins deux blocs polymériques A et B, ledit bloc A étant un bloc élastomère et ledit bloc B étant un bloc hydrophile et (ii) formant, après polymérisation du mélange polymérisable, des domaines riches en bloc élastomère A dispersés au sein du premier matériau, lesdits domaines étant de dimensions inférieures à 80 nanomètres, de préférence inférieures à 50 nanomètres. La présente invention a également pour objet un article transparent à ténacité améliorée fabriqué par polymérisation du mélange polymérisable ci-dessus, comprenant un alliage d'un premier matériau polymère thermodurci constituant la matrice dudit article, et d'un second matériau polymère dispersé au sein dudit premier matériau. Ces articles présentent une meilleure résistance aux chocs et à la propagation de fissures. Application à l'optique ophtalmique.

公开(公告)号：DE602006004035D1

公开(公告)日：2009-01-15

申请号：DE602006004035

申请日：2006-03-29

Applicant: ESSILOR INT

Inventor： GUERRET OLIVIER ,  JAFFRENNOU BORIS ,  LESARTRE NOEMIE ,  MECHIN FRANCOISE ,  PASCAULT JEAN-PIERRE

IPC: G02B1/04

Abstract: The invention relates to a polymerisable liquid mixture comprising: (a) a polymerisable thermosetting composition which is a precursor by polymerization of a first thermoset polymer material, said composition containing at least one polythiol and/or one polyol, preferably a polythiol, and at least one polyiso(thio)cyanate; and (b) a second polymer material solubilized in the aforementioned polymerisable thermosetting composition, whereby the second material (i) contains at least one block copolymer comprising at least two polymer blocks A and B, namely an elastomer block A and a hydrophilic block B, and, following polymerization of the polymerisable mixture, (ii) forms domains which are rich in elastomer block A and which are dispersed throughout the first material, said domains being smaller than 80 nanometers and preferably smaller than 50 nanometers. The invention also relates to a transparent article having improved toughness, which is produced by means of polymerization of the above-mentioned polymerisable mixture, comprising an alloy of a first thermoset polymer material forming the matrix of said article and of a second polymer material which is dispersed throughout said first material. The aforementioned articles have improved resistance to impact and to crack propagation. The invention is suitable for use in ophthalmic optics.