公开(公告)号：DE69711380D1

公开(公告)日：2002-05-02

申请号：DE69711380

申请日：1997-06-26

Applicant: ESSILOR INT

Inventor： MARCHIN BRIGITTE ,  BAUDE DOMINIQUE ,  VAIRON JEAN-PIERRE ,  DOURGES MARINE-ANNE ,  CHAUMONT PHILIPPE ,  STEINER JOEL

IPC: G02C7/04 ,  C07C49/796 ,  C07C49/84 ,  C07F7/18 ,  C08F2/46 ,  C08F2/50 ,  C08G77/38 ,  C08L83/04 ,  C08L83/05 ,  C08L83/07 ,  G02B1/04

Abstract: This invention pertains to a process for the manufacture of a hydrophilic polymeric product, consisting in causing a material comprising a crosslinked silicone polymer matrix and photoinitiator groups dispersed and immobilized within the polymer matrix to swell in a swelling solution comprising a solvent for swelling the crosslinked silicone polymer of the matrix of the material, a photopolymerizable hydrophilic monomer and optionally a crosslinking agent and a proton- or electron-donating coinitiator compound, when the material comprises photoactivable photoinitiator groups and does not comprise proton- or electron-donating coinitiator groups causing the photopolymerizable hydrophilic monomer to diffuse into the swollen material, and polymerizing, by irradiation, the photopolymerizable hydrophilic monomer.

公开(公告)号：AT215112T

公开(公告)日：2002-04-15

申请号：AT97930600

申请日：1997-06-26

Applicant: ESSILOR INT

Inventor： MARCHIN BRIGITTE ,  BAUDE DOMINIQUE ,  VAIRON JEAN-PIERRE ,  DOURGES MARINE-ANNE ,  CHAUMONT PHILIPPE ,  STEINER JOEL

IPC: G02C7/04 ,  C07C49/796 ,  C07C49/84 ,  C07F7/18 ,  C08F2/46 ,  C08F2/50 ,  C08G77/38 ,  C08L83/04 ,  C08L83/05 ,  C08L83/07 ,  G02B1/04

Abstract: This invention pertains to a process for the manufacture of a hydrophilic polymeric product, consisting in causing a material comprising a crosslinked silicone polymer matrix and photoinitiator groups dispersed and immobilized within the polymer matrix to swell in a swelling solution comprising a solvent for swelling the crosslinked silicone polymer of the matrix of the material, a photopolymerizable hydrophilic monomer and optionally a crosslinking agent and a proton- or electron-donating coinitiator compound, when the material comprises photoactivable photoinitiator groups and does not comprise proton- or electron-donating coinitiator groups causing the photopolymerizable hydrophilic monomer to diffuse into the swollen material, and polymerizing, by irradiation, the photopolymerizable hydrophilic monomer.