公开(公告)号：CA2030280A1

公开(公告)日：1991-06-15

申请号：CA2030280

申请日：1990-11-19

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： COYLE CATHERINE L ,  GREANEY MARK A ,  STIEFEL EDWARD I ,  FRANCIS JAMES N ,  BELTZER MORTON

IPC: C10M135/14 ,  C10M159/18 ,  C10N10/12 ,  C10N20/02 ,  C10N30/06 ,  C10N30/12 ,  C10M139/06

Abstract: In accordance with this invention, there is provided a lubricating composition comprising a major amount of an oil of lubricating viscosity and a minor amount of an additive having the formula Mo2L4 wherein L is a ligand selected from xanthates and mixtures thereof and, in particular, xanthates having a sufficient number of carbon atoms to render the additive soluble in the oil. In general, the xanthate ligand, L, will have from about 1 to 30 carbon atoms.

公开(公告)号：CA1250590A

公开(公告)日：1989-02-28

申请号：CA488020

申请日：1985-08-02

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： PAN WIE-HIN ,  STIEFEL EDWARD I

IPC: C07F11/00

Abstract: This invention relates to (disulfido)tris(N,Nsubstituted dithiocarbamato)Mo(V) complexes. More particularly, this invention relates to compounds of the formula MoS2(S2CNR2)3 which are mononuclear, eightcoordinate, neutral Mo(V) complexes containing only eight sulfur atoms in the Mo coordination sphere. R is hydrogen, an alkyl, aryl, cycloalkyl group or mixture thereof. Preferably all of the R's are the same and are alkyl groups. These compounds are useful as lubricant additives.

公开(公告)号：CA1207126A

公开(公告)日：1986-07-08

申请号：CA453023

申请日：1984-04-27

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： STIEFEL EDWARD I ,  PAN WIE-HIN ,  MCKENNA STEPHEN

IPC: C01G51/00 ,  C07F9/54 ,  C07F15/06 ,  C01G39/06 ,  C07F11/00

Abstract: Compositions of the formula ¢(Catn)!3/n ¢Co(MoS4)2! wherein Cat is a mono, di or trivalent cation and n is l, 2 or 3, respectively, have been prepared in non-aqueous media. The ¢Co(MoS4)2!3- anion has the general structure Cat is preferably an alkyl substituted quaternary ammonium compound.

公开(公告)号：CA2102434A1

公开(公告)日：1992-11-25

申请号：CA2102434

申请日：1992-04-27

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： COYLE CATHERINE L ,  FARINA SCOTT A ,  STIEFEL EDWARD I ,  GREANEY MARK A

IPC: C07F11/00

Abstract: The present invention is predicated on the discovery that Mo(III) containing compounds will react with salts of a 1,1-dithioacid to form: Mo4S4L6. Accordingly, there is provided a method for preparing compounds of the formula Mo4S4L5 wherein L is a 1,1-dithioacid ligand comprising: contacting an Mo(III) containing compound with the salt of a 1,1-dithioacid at temperatures and for a time sufficient to form the Mo4S4L6 compound. Preferably, the Mo(III) containing compound is dissolved in an organic solvent and the solution is heated at temperatures above about 25 .degree.C up to the boiling point of the solvent and, preferably, at temperatures in the range of about 25 .degree.C to about 250 .degree.C.

公开(公告)号：MX165110B

公开(公告)日：1992-10-26

申请号：MX2660684

申请日：1984-07-27

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： PAN WIE-HIN ,  HO TEH C ,  STIEFEL EDWARD I ,  CHIANELLI RUSSELL R

IPC: B01J21/04 ,  B01J23/85 ,  B01J27/049 ,  B01J31/02 ,  B01J31/34 ,  C10G45/08 ,  B01J27/02 ,  B01J31/12

公开(公告)号：CA2036783A1

公开(公告)日：1991-09-13

申请号：CA2036783

申请日：1991-02-21

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： COYLE CATHERINE L ,  GREANEY MARK A ,  STIEFEL EDWARD I

IPC: C10M135/14 ,  C10N10/12 ,  C10N20/02 ,  C10N30/06 ,  C10M159/18 ,  C07F11/00 ,  C07C329/12

Abstract: In accordance with this invention, there is provided a lubricating composition comprising a major amount of an oil of lubricating viscosity and a minor amount of an additive having the formula MoL4 wherein L is a ligand selected from thioxanthates and mixtures thereof and, in particular, thioxanthates having a sufficient number of carbon atoms to render the additive soluble in the oil. In general, the thioxanthate ligand, L, will have from about 2 to about 30 carbon atoms.

公开(公告)号：CA1218981A

公开(公告)日：1987-03-10

申请号：CA459875

申请日：1984-07-27

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： HO TEH C ,  PAN WIE-HIN ,  STIEFEL EDWARD I ,  CHIANELLI RUSSELL R

IPC: B01J21/04 ,  B01J23/85 ,  B01J27/049 ,  B01J31/02 ,  B01J31/34 ,  C10G45/08

Abstract: Hydrocarbon feeds are upgraded by contacting a feed, at a elevated temperature and in the presence of hydrogen, with either a bulk or supported, selfpromoted catalyst formed by compositing a porous, refractory inorganic oxide, support with one or more complex salts selected from the group consisting of (NR4)2¢M(WS4)2!, (NR4)x ¢M(moS4)2! and mixtures thereof wherein R is one or more alkyl groups, aryl groups or mixture thereof, wherein promoter metal M is covalently bound in the anion and is Ni, Co or Fe and wherein x is 2 if M is Ni and x is 3 if M is Co or Fe and heating said composite in a non-oxidizing atmosphere in the presence of sulfur and hydrogen and a hydrocarbon to form said supported catalyst. The bulk catalysts are formed in the absence of a support material.

公开(公告)号：CA2124191A1

公开(公告)日：1993-06-10

申请号：CA2124191

申请日：1992-11-23

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： GORUN SERGIU M ,  GREANEY MARK A ,  COX DONALD M ,  CHIANELLI RUSSELL R ,  STIEFEL EDWARD I

IPC: C01B31/02 ,  C25B1/00 ,  C25B1/14 ,  C25B3/00 ,  H01M4/58 ,  H01M4/583 ,  H01M4/587 ,  C01B31/00

Abstract: 2124191 9311067 PCTABS00022 The present invention relates to new compositions of matter having the formula AnCx, wherein A is a monovalent cation and Cx is a fullerene anion, preferably wherein x is equal to 60 and 70. The present invention also relates to a process for preparing the composition by applying an electrical potential to a non-aqueous solution of a fullerene and a salt containing a monovalent cation. The present invention also relates to a method for electrochemically generating fulleride salts as a solution in other hydrocarbons. The present invention also relates to a method for electrochemically preparing solid fulleride salts. The compositions may be used as electrode material in reversible electrochemical cells, superconductors, spin labels, magnetic thermometers, organic, and polymer precursors.

公开(公告)号：CA2102631A1

公开(公告)日：1992-11-21

申请号：CA2102631

申请日：1992-05-08

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： COYLE CATHERINE L ,  GUZI PETER J ,  HALBERT THOMAS R ,  STIEFEL EDWARD I

IPC: C07F11/00

Abstract: The present invention provides an improved method for preparing compounds of the formula Mo4S4L6 comprising: contacting a compound having the formula Mo2S4L2, wherein L is a 1,1- dithioacid ligand, with a reducing agent having a reduction potential sufficient to reduce Mo(V) to lower oxidation states, especially to Mo(III) and Mo(IV), at a temperature and for a time sufficient to form the Mo4S4L6 compound. Preferably, the Mo2S4L2 compound is dissolved in an organic solvent along with the reducing agent and the solution is heated at temperatures above 25 .degree.C, up to the boiling point of the solvent and, more preferably, at temperatures in the range of from about 50 .degree.C to about 250 .degree.C.