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公开(公告)号：US10557092B2
公开(公告)日：2020-02-11
申请号：US15643893
申请日：2017-07-07
Applicant: ExxonMobil Research and Engineering Company
Inventor： Jason T. Calla , Will G. Fisher, Jr. , Eric D. Joseck , Seth D. Fortney
Abstract: Systems and methods are provided for production of base stocks with a viscosity index of at least 120 and/or a sulfur content of 300 wppm or less and/or a kinematic viscosity at 100° C. of 3.0 cSt to 8.0 cSt by hydroconversion of a raffinate from aromatic extraction of a feed. The base stocks can further have a reduced content of 3+ ring naphthenes, such as 4.0 wt % or less, or 1.0 wt % or less. The base stocks can be produced by performing an elevated amount of feed conversion relative to 370° C. during hydroconversion of the raffinate, and optionally additional conversion during catalytic dewaxing of the hydroconverted raffinate. The base stocks can optionally be blended with additional base stocks and/or lubricant additives for production of lubricant compositions.
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公开(公告)号：US20170166827A1
公开(公告)日：2017-06-15
申请号：US15368888
申请日：2016-12-05
Applicant: ExxonMobil Research and Engineering Company
Inventor： Liezhong Gong , Corry S. Powers , Eric D. Joseck , Beatrice M. Gooding
CPC classification number: C10G73/02 , C10G21/00 , C10G45/00 , C10G45/02 , C10G45/58 , C10G73/42 , C10G2300/30 , C10M101/02 , C10M2203/1006 , C10N2220/022 , C10N2270/00 , G01N25/4866 , G01N33/2811 , G01N33/2823 , G01N33/2888 , G01N33/30
Abstract: Methods are provided for rapidly characterizing a feedstock being considered for lubricant base oil production in order to determine the viscosity index potential of the feedstock. It has unexpectedly been discovered that the DDVI value for a feedstock at a specified pour point can be predicted based on a) the feed distillate residual wax content at a temperature as determined by Differential Scanning Calorimetry, such as the feed distillate residual wax content at a temperature corresponding to the specified pour point temperature; b) the feed distillate refractive index; c) the feed distillate kinematic viscosity at a temperature, such as kinematic viscosity at 100° C.; and d) the distillate volume-averaged boiling point. Based on this unexpected correlation, the VI potential of a feedstock can be determined based on measurement of properties that can be performed on a time scale corresponding to one or a few days using a few milliliters of feedstock.
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公开(公告)号：US20140262957A1
公开(公告)日：2014-09-18
申请号：US13832534
申请日：2013-03-15
Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
Inventor： Liezhong Gong , Corry S. Powers , Helen S. Wellons , Tahmid I. Mizan , Eric D. Joseck , Steven Webster Levine
IPC: G01N33/30
CPC classification number: G01N33/30 , G01N33/2823
Abstract: Methods are provided for characterizing crude oils, crude fractions, or other potential feedstocks for forming lubricating base oils in order to determine the suitability of a feedstock for lubricating base oil production. One type of characterization is to determine the isoparaffin, naphthene, and/or aromatics contents of the distillate portion of a feedstock. A second characterization is to determine the viscosity index of a distillate portion of a feedstock after dewaxing the distillate portion to a target pour point.
Abstract translation: 提供了用于表征用于形成润滑基础油的原油，粗馏分或其它潜在原料的方法，以确定用于润滑基础油生产的原料的适用性。 一种类型的表征是确定原料的馏出物部分的异链烷烃，环烷烃和/或芳烃含量。 第二表征是确定将馏出物部分脱蜡至目标倾点之后的原料的馏出物部分的粘度指数。
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公开(公告)号：US20190039055A1
公开(公告)日：2019-02-07
申请号：US16038851
申请日：2018-07-18
Applicant: ExxonMobil Research and Engineering Company
Inventor： Stephen J. McCarthy , Paul Podsiadlo , Gary P. Schleicher , Timothy L. Hilbert , Teck-Mui Hoo , Eric D. Joseck
CPC classification number: B01J29/7461 , B01J8/0285 , B01J8/0442 , B01J8/0457 , B01J8/0496 , B01J21/04 , B01J23/42 , B01J23/44 , B01J29/043 , B01J29/068 , B01J29/74 , B01J29/90 , B01J35/0066 , B01J37/0018 , B01J37/08 , B01J37/10 , B01J37/18 , B01J38/02 , B01J38/06 , B01J38/10 , B01J2229/186 , B01J2229/36 , B01J2229/40 , B01J2229/42 , C10G45/00 , C10G45/62 , C10G45/64 , C10G65/02 , C10G65/16 , C10G2300/703
Abstract: Systems and methods are provided for activation of noble metal catalysts that are supported on siliceous supports. The activation method can include limiting the amount of water vapor pressure and/or the time of exposure to the water vapor pressure during heating of the catalyst at temperatures of 50° C. or less. This can be achieved by introducing heated gas into multiple reactors of a multi-reactor system at the same time. A suitable system for introducing heated gas into multiple reactors can correspond to a system with multiple heated hydrogen lines for delivery of heated hydrogen to a plurality of reactors within a multi-reactor system.
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公开(公告)号：US20180037829A1
公开(公告)日：2018-02-08
申请号：US15643893
申请日：2017-07-07
Applicant: ExxonMobil Research and Engineering Company
Inventor： Jason T. Calla , Will G. Fisher, JR. , Eric D. Joseck , Seth D. Fortney
Abstract: Systems and methods are provided for production of base stocks with a viscosity index of at least 120 and/or a sulfur content of 300 wppm or less and/or a kinematic viscosity at 100° C. of 3.0 cSt to 8.0 cSt by hydroconversion of a raffinate from aromatic extraction of a feed. The base stocks can further have a reduced content of 3+ ring naphthenes, such as 4.0 wt % or less, or 1.0 wt % or less. The base stocks can be produced by performing an elevated amount of feed conversion relative to 370° C. during hydroconversion of the raffinate, and optionally additional conversion during catalytic dewaxing of the hydroconverted raffinate. The base stocks can optionally be blended with additional base stocks and/or lubricant additives for production of lubricant compositions.
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Patent Agency Ranking
公开(公告)号：US20170211003A1
公开(公告)日：2017-07-27
申请号：US15381517
申请日：2016-12-16
Applicant: ExxonMobil Research and Engineering Company
Inventor： Corry S. Powers , Liezhong Gong , Nicole D. Vaughn , Beatrice M. Gooding , Kendall S. Fruchey , Eric D. Joseck , Marc Sonnentrucker
IPC: C10G69/02 , C10M101/02
CPC classification number: C10G69/02 , B01J23/88 , B01J23/888 , B01J29/06 , B01J35/1019 , B01J35/1061 , C10G11/18 , C10G45/58 , C10G65/02 , C10G65/04 , C10G65/12 , C10G67/0418 , C10G67/0445 , C10G69/04 , C10G2300/1048 , C10G2300/1074 , C10G2300/1077 , C10G2300/1096 , C10G2300/202 , C10G2300/301 , C10G2300/302 , C10G2400/10 , C10M101/02 , C10M2203/1006 , C10N2220/022 , C10N2220/023 , C10N2220/031 , C10N2230/74
Abstract: Methods are provided for upgrading disadvantaged feeds for use in lubricant base stock production. A disadvantaged feed can be upgraded by hydroprocessing the feed to form a hydroprocessed bottoms fraction. The hydroprocessed bottoms fraction can then be used as a feed for forming Group I and/or Group II lubricant base stocks, optionally in combination with a conventional feed for lubricant production. The remaining portions of the hydroprocessing effluent can optionally be used for FCC processing and/or for other conventional applications of naphtha and distillate fractions.
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公开(公告)号：US10583425B2
公开(公告)日：2020-03-10
申请号：US16038851
申请日：2018-07-18
Applicant: ExxonMobil Research and Engineering Company
Inventor： Stephen J. McCarthy , Paul Podsiadlo , Gary P. Schleicher , Timothy L. Hilbert , Teck-Mui Hoo , Eric D. Joseck
IPC: B01J37/10 , B01J37/08 , B01J29/74 , B01J29/068 , B01J8/04 , B01J38/10 , B01J38/06 , B01J29/90 , B01J35/00 , B01J38/02 , C10G65/16 , B01J8/02 , B01J29/04 , C10G45/64 , C10G45/62 , C10G45/00 , B01J21/04 , B01J23/42 , B01J23/44 , B01J37/00 , B01J37/18 , C10G65/02
Abstract: Systems and methods are provided for activation of noble metal catalysts that are supported on siliceous supports. The activation method can include limiting the amount of water vapor pressure and/or the time of exposure to the water vapor pressure during heating of the catalyst at temperatures of 50° C. or less. This can be achieved by introducing heated gas into multiple reactors of a multi-reactor system at the same time. A suitable system for introducing heated gas into multiple reactors can correspond to a system with multiple heated hydrogen lines for delivery of heated hydrogen to a plurality of reactors within a multi-reactor system.
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公开(公告)号：US10221367B2
公开(公告)日：2019-03-05
申请号：US15381517
申请日：2016-12-16
Applicant: ExxonMobil Research and Engineering Company
Inventor： Corry S. Powers , Liezhong Gong , Nicole D. Vaughn , Beatrice M. Gooding , Kendall S. Fruchey , Eric D. Joseck , Marc Sonnentrucker
IPC: C10G69/02 , C10G45/58 , C10G65/02 , C10G65/04 , C10G65/12 , C10G67/04 , C10G69/04 , C10M101/02 , C10G11/18 , B01J23/88 , B01J23/888 , B01J29/06 , B01J35/10
Abstract: Methods are provided for upgrading disadvantaged feeds for use in lubricant base stock production. A disadvantaged feed can be upgraded by hydroprocessing the feed to form a hydroprocessed bottoms fraction. The hydroprocessed bottoms fraction can then be used as a feed for forming Group I and/or Group II lubricant base stocks, optionally in combination with a conventional feed for lubricant production. The remaining portions of the hydroprocessing effluent can optionally be used for FCC processing and/or for other conventional applications of naphtha and distillate fractions.
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公开(公告)号：US10106751B2
公开(公告)日：2018-10-23
申请号：US15368888
申请日：2016-12-05
Applicant: ExxonMobil Research and Engineering Company
Inventor： Liezhong Gong , Corry S. Powers , Eric D. Joseck , Beatrice M. Gooding
IPC: C10G73/02 , C10G73/42 , G01N33/28 , G01N33/30 , C10M101/02 , C10G21/00 , C10G45/58 , C10G45/02 , C10G45/00 , G01N25/48 , C10M169/00
Abstract: Methods are provided for rapidly characterizing a feedstock being considered for lubricant base oil production in order to determine the viscosity index potential of the feedstock. It has unexpectedly been discovered that the DDVI value for a feedstock at a specified pour point can be predicted based on a) the feed distillate residual wax content at a temperature as determined by Differential Scanning Calorimetry, such as the feed distillate residual wax content at a temperature corresponding to the specified pour point temperature; b) the feed distillate refractive index; c) the feed distillate kinematic viscosity at a temperature, such as kinematic viscosity at 100° C.; and d) the distillate volume-averaged boiling point. Based on this unexpected correlation, the VI potential of a feedstock can be determined based on measurement of properties that can be performed on a time scale corresponding to one or a few days using a few milliliters of feedstock.
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公开(公告)号：US08992770B2
公开(公告)日：2015-03-31
申请号：US13832534
申请日：2013-03-15
Applicant: ExxonMobil Research and Engineering Company
Inventor： Liezhong Gong , Corry S. Powers , Helen S. Wellons , Tahmid I. Mizan , Eric D. Joseck , Steven Webster Levine
CPC classification number: G01N33/30 , G01N33/2823
Abstract: Methods are provided for characterizing crude oils, crude fractions, or other potential feedstocks for forming lubricating base oils in order to determine the suitability of a feedstock for lubricating base oil production. One type of characterization is to determine the isoparaffin, naphthene, and/or aromatics contents of the distillate portion of a feedstock. A second characterization is to determine the viscosity index of a distillate portion of a feedstock after dewaxing the distillate portion to a target pour point.
Abstract translation: 提供了用于表征用于形成润滑基础油的原油，粗馏分或其它潜在原料的方法，以确定用于润滑基础油生产的原料的适用性。 一种类型的表征是确定原料的馏出物部分的异链烷烃，环烷烃和/或芳烃含量。 第二表征是确定将馏出物部分脱蜡至目标倾点之后的原料的馏出物部分的粘度指数。
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