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公开(公告)号：US11819818B2
公开(公告)日：2023-11-21
申请号：US16947704
申请日：2020-08-13
Inventor： Chuansheng Bai , Jihad M. Dakka , Preeti Kamakoti , Aruna Ramkrishnan , Anjaneya S. Kovvali , Anita S. Lee
IPC: B01J23/80 , B01J29/46 , B01J35/02 , B01J37/04 , B01J37/08 , B01J37/10 , B01J37/00 , C07C41/01 , B01J37/12
CPC classification number: B01J29/46 , B01J23/80 , B01J35/023 , B01J35/026 , B01J37/0018 , B01J37/0027 , B01J37/0036 , B01J37/12 , C07C41/01
Abstract: A method of producing bifunctional catalysts by extrusion may include mixing an acid catalyst, a metal catalyst, optionally a binder, and a fluid to produce a dough; extruding the dough to form an extrudate; producing a powder from the extrudate; and calcining the powder to produce an acid/metal bifunctional catalyst. Such acid/metal bifunctional catalysts may be useful in, among other things, converting syngas to dimethyl ether in a single reactor.
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公开(公告)号：US12030032B2
公开(公告)日：2024-07-09
申请号：US17316713
申请日：2021-05-11
Inventor： Chuansheng Bai , Majosefina Cunningham , Patrick P. McCall , Hans Thomann , Jeannine Elizabeth Elliott , Vinh Nguyen
CPC classification number: B01J20/08 , B01D53/02 , B01J20/041 , B01J20/3007 , B01J20/3078 , B01J20/3204 , B01J20/3236 , B01D2253/1124 , B01D2257/504 , B01D2258/0283 , Y02C20/40
Abstract: The disclosure generally relates to CCS sorbents, particularly for CO2/H2O displacement desorption process. The sorbents include an aluminum oxide support that includes alkali metal salts within the support, in the form of pseudo alkali aluminate. The sorbents also include alkali metal salt impregnated on the support. The sorbents demonstrate improved CO2 loadings and better H2O/CO2 ratios, as well as improved stability. Compositions and methods of making are disclosed.
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3.发明授权公开(公告)号：US11850569B2
公开(公告)日：2023-12-26
申请号：US16889657
申请日：2020-06-01
Inventor： Jeannine Elizabeth Elliott , Robert James Copeland , Margarita Dubovik , Daniel P. Leta , Patrick P. McCall , Chuansheng Bai , Bruce A. DeRites
CPC classification number: B01J20/043 , B01J20/041 , B01J20/08 , B01J20/20 , B01J20/3204 , B01J20/3236 , B01J20/3466 , B01J20/3483 , B01J20/3491 , B01J2220/603 , B01J2220/606 , Y02C20/40
Abstract: Compositions and methods of preparing the compositions are disclosed for sorbents and other surfaces that can adsorb and desorb carbon dioxide. A sorbent or surface can include a metal compound such as an alkali or alkaline earth compound and a support. The sorbent can be prepared by several methods, including an incipient wetness technique. The sorbents have a CO2 adsorption and desorption profile. A sorbent having high levels of a metal compound and adsorbed CO2 is disclosed.
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公开(公告)号：US11691139B2
公开(公告)日：2023-07-04
申请号：US16947706
申请日：2020-08-13
Inventor： Chuansheng Bai , Majosefina Cunningham , Jihad M. Dakka , Preeti Kamakoti , Aruna Ramkrishnan , Anjaneya S. Kovvali , Anita S. Lee
IPC: B01J37/08 , B01J37/02 , B01J37/04 , C07C41/01 , B01J33/00 , B01J21/18 , B01J29/40 , B01J37/10 , B01J23/80
CPC classification number: B01J37/084 , B01J21/18 , B01J23/80 , B01J29/40 , B01J33/00 , B01J37/0219 , B01J37/0221 , B01J37/04 , B01J37/10 , C07C41/01
Abstract: A method of producing bifunctional catalyst systems that include a carbon-coated metal catalyst may comprise: coating a metal catalyst particle with a carbon-containing small molecule to produce a coated metal catalyst particle; carbonizing the carbon-containing small molecule on the coated metal catalyst particle to produce a carbon-coated metal catalyst particle; and mixing the carbon-coated metal catalyst particle with an acid catalyst particle to produce an acid/metal bifunctional catalyst system. Further, a method of producing bifunctional catalyst systems that include a carbon-coated acid catalyst may be similarly performed by coating a metal catalyst particle with a carbon-containing small molecule to produce a coated metal catalyst particle; carbonizing the carbon-containing small molecule on the coated metal catalyst particle to produce a carbon-coated metal catalyst particle; and mixing the carbon-coated metal catalyst particle with an acid catalyst particle to produce an acid/metal bifunctional catalyst system.
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Patent Agency Ranking
5.发明授权公开(公告)号：US11654421B2
公开(公告)日：2023-05-23
申请号：US16947701
申请日：2020-08-13
Inventor： Chuansheng Bai , Majosefina Cunningham , Jihad M. Dakka , Preeti Kamakoti , Aruna Ramkrishnan , Anjaneya S. Kovvali , Anita S. Lee
IPC: B01J23/80 , C07C41/01 , B01J37/04 , B01J37/03 , B01J37/30 , B01J37/00 , B01J37/08 , B01J37/34 , B01J37/06 , B01J37/02 , B01J37/18 , B01J35/00 , B01J35/02 , B01J35/10 , B01J21/18
CPC classification number: B01J23/80 , B01J21/18 , B01J35/0013 , B01J35/026 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/0036 , B01J37/0236 , B01J37/031 , B01J37/04 , B01J37/06 , B01J37/088 , B01J37/18 , B01J37/30 , B01J37/348 , C07C41/01
Abstract: Methods of producing metal catalysts can include mixing two or more metal salts and an aluminum salt in water to produce a metal catalyst precursor solution; mixing the metal catalyst precursor solution and an alkali metal buffer solution to produce a precipitate; ion exchanging the alkali metal in the precipitate for a non-alkali cation to produce a low-alkali metal precipitate comprising 3 wt % or less alkali metal by weight of the precipitate on a dry basis; producing a powder from the low-alkali metal precipitate; and calcining the powder to produce a metal catalyst. Such metal catalysts may be useful in producing bifunctional catalyst systems that are useful in, among other things, converting syngas to dimethyl ether in a single reactor.
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公开(公告)号：US12172151B2
公开(公告)日：2024-12-24
申请号：US18000735
申请日：2021-05-12
Inventor： Madelyn Stalzer , Joseph Gatt , Chuansheng Bai , Christopher Oliveri
IPC: B01J29/80 , B01J29/48 , B01J29/72 , B01J29/74 , B01J29/78 , B01J37/02 , B01J37/04 , B01J37/08 , B01J37/20 , B01J37/30 , C10G45/64 , C10G65/04
Abstract: Described herein are novel and inventive dewaxing processes that employ dewaxing catalysts which are co-extrusions of two different zeolites, particularly two different 10MR zeolites or a co-extrusion of a 10MR zeolite and a 12MR zeolite in combination with a hydrogenation component. The hydrogenation component can be a mixture of non-noble metal components or a mixture of noble metal components. This novel and inventive process demonstrated a significant activity boost (as measured by increased cloud point reduction) and/or selectivity boost (as measured by reduced diesel loss) compared to either single zeolite component.
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公开(公告)号：US11638912B2
公开(公告)日：2023-05-02
申请号：US16947699
申请日：2020-08-13
Inventor： Chuansheng Bai , Majosefina Cunningham , Jihad M. Daaka , Preeti Kamakoti , Aruna Ramkrishnan
IPC: B01J23/80 , C07C41/01 , B01J37/03 , B01J37/08 , B01J37/06 , B01J37/02 , B01J37/00 , B01J37/18 , B01J35/02 , B01J35/00 , B01J35/10 , B01J37/04
Abstract: Methods of producing metal catalysts can include mixing two or more metal salts and an aluminum salt in water to produce a metal catalyst precursor solution having a pH of about 2.5 to about 4.0; mixing the metal catalyst precursor solution and a basic solution having a pH of about 10 to about 13 to produce a mixture with a pH of about 6 to about 7 and a precipitate; producing a powder from the precipitate; and calcining the powder to produce a metal catalyst. Such metal catalysts may be useful in producing bifunctional catalyst systems that are useful in, among other things, converting syngas to dimethyl ether in a single reactor.
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公开(公告)号：US11602734B2
公开(公告)日：2023-03-14
申请号：US16993219
申请日：2020-08-13
Inventor： Chuansheng Bai , Majosefina Cunningham , Jihad M. Dakka , Preeti Kamakoti , Aruna Ramkrishnan , Anjaneya S. Kovvali , Anita S. Lee
IPC: B01J29/06 , B01J23/80 , C07C41/01 , B01J29/46 , B01J27/188 , B01J27/19 , B01J35/02 , B01J35/10 , B01J37/04 , B01J37/08 , B01J37/10 , B01J37/00 , B01J37/18 , B01J21/04 , C07C31/04 , C07C43/04 , C07C29/154
Abstract: A method of producing a acid/metal bifunctional catalyst may include: mixing an acid catalyst, a metal catalyst, and a fluid to produce a slurry, wherein the acid catalyst is present at 50 wt % or less relative to a total catalyst weight in the slurry; heating the slurry; producing a powder from the slurry; and calcining the powder to produce the acid/metal bifunctional catalyst. Such acid/metal bifunctional catalyst would be useful in the direct conversion of syngas to dimethyl ether as well as other reactions.
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公开(公告)号：US11420182B2
公开(公告)日：2022-08-23
申请号：US15910212
申请日：2018-03-02
Inventor： Chuansheng Bai , Majosefina Cunningham , Patrick P. McCall , Hans Thomann , Jeannine Elizabeth Elliott , Vinh Nguyen
Abstract: The disclosure generally relates to CCS sorbents, particularly for CO2/H2O displacement desorption process. The sorbent includes an aluminum oxide support and an alkali metal salt impregnated on the support, and a silicon modification of the sorbent to reduce water uptake by the sorbent and make it more hydrophobic. The silicon modification can be an organosilyl moiety added after the initial sorbent is complete, or a silica source added to the aluminum oxide structure, typically via impregnation. The sorbents demonstrate better H2O/CO2 ratios. Compositions and methods of making are disclosed.
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