公开(公告)号：US20220396534A1

公开(公告)日：2022-12-15

申请号：US17820147

申请日：2022-08-16

Applicant: ExxonMobil Technology and Engineering Company

Inventor： Matthew J. Vincent ,  Keith H. Kuechler

IPC: C07C2/12 ,  C07C7/04

Abstract: A method for producing an isoolefinic stream may include: oligomerizing an ethylene stream to a C4+ olefin stream in a first olefin oligomerization unit comprising a serial reactor and a lights removal column, wherein the C4+ olefin stream contains no greater than 10 wt % of methane, ethylene, and ethane combined; and wherein the ethylene stream contains at least 50 wt % ethylene, at least 2000 wppm ethane, no greater than 1000 wppm of methane, and no greater than 20 wppm each of carbon monoxide and hydrogen; and oligomerizing the C4+ olefin stream and a propylene/C4+ olefin stream in a second oligomerization unit to produce the isoolefinic stream.

公开(公告)号：US12012562B2

公开(公告)日：2024-06-18

申请号：US17820159

申请日：2022-08-16

Applicant: ExxonMobil Technology and Engineering Company

Inventor： Matthew J. Vincent ,  Keith H. Kuechler

IPC: C10G69/12 ,  B01D3/14 ,  C07C1/24 ,  C07C2/08 ,  C07C2/12 ,  C07C5/03 ,  C07C7/04 ,  C07C7/08 ,  C10L1/08

CPC classification number: C10G69/126 ,  B01D3/14 ,  B01D3/143 ,  C07C1/24 ,  C07C2/08 ,  C07C2/12 ,  C07C5/03 ,  C07C7/04 ,  C07C7/08 ,  C10L1/08 ,  C07C2529/85 ,  C07C2529/89 ,  C10G2300/1092 ,  C10G2300/301 ,  C10G2400/08 ,  C10L2270/04

Abstract: A nonlimiting example method for producing a diesel boiling range composition comprises: oligomerizing an ethylene stream to a C4+ olefin stream in a first olefin oligomerization unit, wherein the C4+ olefin stream contains no greater than 10 wt % of methane, ethylene, and ethane combined in a first oligomerization; and wherein the ethylene stream contains at least 50 wt % ethylene, at least 2000 wppm ethane, no greater than 1000 wppm of methane, and no greater than 20 wppm each of carbon monoxide and hydrogen; oligomerizing the C4+ olefin stream and a propylene/C4+ olefin stream in a second oligomerization unit to produce an isoolefinic stream; wherein at least a portion of the isoolefinic stream is used to create the diesel boiling range composition.

公开(公告)号：US20230212092A1

公开(公告)日：2023-07-06

申请号：US17820159

申请日：2022-08-16

Applicant: ExxonMobil Technology and Engineering Company

Inventor： Matthew J. Vincent ,  Keith H. Kuechler

IPC: C07C2/08 ,  C07C7/08 ,  C07C5/03 ,  C07C1/24 ,  B01D3/14

CPC classification number: C07C2/08 ,  B01D3/143 ,  C07C1/24 ,  C07C5/03 ,  C07C7/08

Abstract: A nonlimiting example method for producing a diesel boiling range composition comprises: oligomerizing an ethylene stream to a C4+ olefin stream in a first olefin oligomerization unit, wherein the C4+ olefin stream contains no greater than 10 wt% of methane, ethylene, and ethane combined in a first oligomerization; and wherein the ethylene stream contains at least 50 wt% ethylene, at least 2000 wppm ethane, no greater than 1000 wppm of methane, and no greater than 20 wppm each of carbon monoxide and hydrogen; oligomerizing the C4+ olefin stream and a propylene/C4+ olefin stream in a second oligomerization unit to produce an isoolefinic stream; wherein at least a portion of the isoolefinic stream is used to create the diesel boiling range composition.

公开(公告)号：US20220396741A1

公开(公告)日：2022-12-15

申请号：US17820152

申请日：2022-08-16

Applicant: ExxonMobil Technology and Engineering Company

Inventor： Matthew J. Vincent ,  Keith H. Kuechler

IPC: C10G69/12 ,  C07C2/08 ,  C07C5/03 ,  C07C1/24 ,  C07C7/08 ,  C10L1/08 ,  B01D3/14

Abstract: A method for producing a blended jet boiling range composition stream may include: oligomerizing an ethylene stream to a C4+ olefin stream in a first olefin oligomerization unit, wherein the C4+ olefin stream contains no greater than 10 wt % of methane, ethylene, and ethane combined; wherein the ethylene stream contains at least 50 wt % ethylene, at least 2000 wppm ethane, no greater than 1000 wppm of methane, and no greater than 20 wppm each of carbon monoxide and hydrogen; oligomerizing the C4+ olefin stream and a propylene/C4+ olefin stream in a second oligomerization unit to produce an isoolefinic stream; subjecting at least a portion of the isoolefinic stream to a hydroprocessing process with hydrogen as treat gas to produce an isoparaffinic stream having no greater than 10 wt % olefin content; and using least a portion of the isoparaffinic stream to create the blended jet boiling range.

公开(公告)号：US12012561B2

公开(公告)日：2024-06-18

申请号：US17820147

申请日：2022-08-16

Applicant: ExxonMobil Technology and Engineering Company

Inventor： Matthew J. Vincent ,  Keith H. Kuechler

IPC: C10G69/12 ,  B01D3/14 ,  C07C1/24 ,  C07C2/08 ,  C07C2/12 ,  C07C5/03 ,  C07C7/04 ,  C07C7/08 ,  C10L1/08

CPC classification number: C10G69/126 ,  B01D3/14 ,  B01D3/143 ,  C07C1/24 ,  C07C2/08 ,  C07C2/12 ,  C07C5/03 ,  C07C7/04 ,  C07C7/08 ,  C10L1/08 ,  C07C2529/85 ,  C07C2529/89 ,  C10G2300/1092 ,  C10G2300/301 ,  C10G2400/08 ,  C10L2270/04

Abstract: A method for producing an isoolefinic stream may include: oligomerizing an ethylene stream to a C4+ olefin stream in a first olefin oligomerization unit comprising a serial reactor and a lights removal column, wherein the C4+ olefin stream contains no greater than 10 wt % of methane, ethylene, and ethane combined; and wherein the ethylene stream contains at least 50 wt % ethylene, at least 2000 wppm ethane, no greater than 1000 wppm of methane, and no greater than 20 wppm each of carbon monoxide and hydrogen; and oligomerizing the C4+ olefin stream and a propylene/C4+ olefin stream in a second oligomerization unit to produce the isoolefinic stream.

公开(公告)号：US12084622B2

公开(公告)日：2024-09-10

申请号：US17820152

申请日：2022-08-16

Applicant: ExxonMobil Technology and Engineering Company

Inventor： Matthew J. Vincent ,  Keith H. Kuechler

IPC: B01D3/14 ,  C07C1/24 ,  C07C2/08 ,  C07C2/12 ,  C07C5/03 ,  C07C7/04 ,  C07C7/08 ,  C10G69/12 ,  C10L1/08

CPC classification number: C10G69/126 ,  B01D3/14 ,  B01D3/143 ,  C07C1/24 ,  C07C2/08 ,  C07C2/12 ,  C07C5/03 ,  C07C7/04 ,  C07C7/08 ,  C10L1/08 ,  C07C2529/85 ,  C07C2529/89 ,  C10G2300/1092 ,  C10G2300/301 ,  C10G2400/08 ,  C10L2270/04

Abstract: A method for producing a blended jet boiling range composition stream may include: oligomerizing an ethylene stream to a C4+ olefin stream in a first olefin oligomerization unit, wherein the C4+ olefin stream contains no greater than 10 wt % of methane, ethylene, and ethane combined; wherein the ethylene stream contains at least 50 wt % ethylene, at least 2000 wppm ethane, no greater than 1000 wppm of methane, and no greater than 20 wppm each of carbon monoxide and hydrogen; oligomerizing the C4+ olefin stream and a propylene/C4+ olefin stream in a second oligomerization unit to produce an isoolefinic stream; subjecting at least a portion of the isoolefinic stream to a hydroprocessing process with hydrogen as treat gas to produce an isoparaffinic stream having no greater than 10 wt % olefin content; and using least a portion of the isoparaffinic stream to create the blended jet boiling range.