Recuperación de lignina y producción de furfural a partir de corrientes de prehidrolizado de biomasa.

    公开(公告)号:CL2018002992A1

    公开(公告)日:2018-12-14

    申请号:CL2018002992

    申请日:2018-10-19

    Applicant: FPINNOVATIONS

    Abstract: LA PRESENTE INVENCIÓN SE REFIERE A UN MÉTODO PARA PRODUCIR FURFURAL Y EXTRAER LIGNINA DE UNA SOLUCIÓN DE BIOMASA HEMICELULÓSICA QUE COMPRENDE UNA CANTIDAD TOTAL DE AZÚCARES C5, QUE COMPRENDE LA ETAPA DE CALENTAR LA SOLUCIÓN DE BIOMASA HEMICELULÓSICA A UNA TEMPERATURA DE AL MENOS APROXIMADAMENTE 200 °C; ACIDIFICAR LA SOLUCIÓN DE BIOMASA HEMICELULÓSICA CON UN ÁCIDO PARA PRODUCIR EL FURFURAL EN FASE DE VAPOR; Y CONDENSAR EL FURFURAL PARA RECUPERAR FURFURAL EN SOLUCIÓN, EN DONDE EL FURFURAL SE PRODUCE EN UN RENDIMIENTO MOLAR TOTAL DE AL MENOS 70 % DE MOLES DE FURFURAL PRODUCIDO/LOS MOLES TOTALES DE AZÚCARES C5 PRESENTES EN LA SOLUCIÓN DE BIOMASA HEMICELULÓSICA INICIAL. LA LIGNINA DE BAJO PESO MOLECULAR PUEDE RECUPERARSE A PARTIR DE LA SOLUCIÓN DE BIOMASA HEMICELULÓSICA ANTES DE LA PRODUCCIÓN FURFURAL MEDIANTE CONCENTRACIÓN DE MEMBRANA, ACIDIFICACIÓN, COAGULACIÓN Y FILTRACIÓN.

    MELTABLE LIGNIN COMPOSITIONS, METHOD FOR PRODUCING THEM AND THEIR USES

    公开(公告)号:CA3090711C

    公开(公告)日:2021-05-25

    申请号:CA3090711

    申请日:2019-02-07

    Applicant: FPINNOVATIONS

    Abstract: CA 03090711 2020-08-07 (12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property 1 11111 1111111 11 111111 111 11111 11111111 1 1 111 1111 1111 1111 11111 11111 111 11111111111 111 1111 Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2019/153085 Al 15 August 2019 (15.08.2019) WIPO I PCT (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every C08J 3/12 (2006.01) CO8L 97/00 (2006.01) kind of national protection available): AE, AG, AL, AM, B29B 7/00 (2006.01) D21C 11/00 (2006.01) AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, (21) International Application Number: DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, PCT/CA2019/050161 HR, HU, ED, EL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, (22) International Filing Date: KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, 0'7 February 2019 (0'7.02.2019) MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, (25) Filing Language: English SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, (26) Publication Language: English TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (30) Priority Data: (84) Designated States (unless otherwise indicated, for every 62/628,358 09 February 2018 (09.02.2018) US kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, (71) Applicant: FPINNOVATIONS [CA/CA]; 5'70, boul. St-UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, Jean, Pointe-Claire, Québec H9R 3J9 (CA). TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, (72) Inventors: LALEG, Makhlouf; 69 Ave. Aurora, Pointe-EE, ES, FI, FR, GB, GR, HR, HU, EE, IS, IT, LT, LU, LV, Claire, Québec H9R 3G3 (CA). JEMAA, Naceur; 52 MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, Somervale Grds, Pointe-Claire, Québec H9R 3H5 (CA). TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, WAFA AL DAJANI, Waleed; 243 Chemin de la Rive KM, ML, MR, NE, SN, TD, TG). Boisée, #2, Pierrefonds, Québec H8Z 2Y4 (CA). ZHANG, Yaolin; 1016 rue Simone-Albert, Quebec, Québec G1W Published: 0A6 (CA). PALEOLOGOU, Michael; 29'7 Alice Carriere, ¨ with international search report (Art. 21(3)) Beaconsfield, Québec H9W 6E5 (CA). = (74) Agent: NORTON ROSE FULBRIGHT CANADA LLP / S.E.N.C.R.L., S.R.L.; Suite 2500, 1, Place Ville Marie, Montreal, Québec H3B 1R1 (CA). (54) Title: MELTABLE LIGNIN COMPOSITIONS, METHOD FOR PRODUCING THEM AND THEIR USES * vjfile . 4 9 11111110111 -* ' -.0!C oc ==i¨ .. 5 kin 1-1 (57) Abstract: Novel meltable lignin compositions having tailored compatibilities, moisture/water-resistant adhesion characteristics, CT and low to medium glass transition temperatures (30 to 120 C) desirable for applications in the manufacturing of various products and the integration in the formulations of adhesives, coatings, plastics, composites and masterbatches, are obtained by blending at low NI temperatures (0-120 C) dry lignins (0 to 10% moisture), in their hydrogen or protonated forms - hereby referred to as H-forms (pH = C 2.3-6.5 for a 10% aqueous suspension), with a reactive and/or interactive molecule or combination of molecules.

    LIGNIN RECOVERY AND FURFURAL PRODUCTION FROM BIOMASS PREHYDROLYSATE STREAMS

    公开(公告)号:CA3018578A1

    公开(公告)日:2017-10-26

    申请号:CA3018578

    申请日:2017-04-20

    Applicant: FPINNOVATIONS

    Abstract: The present invention relates to a method of producing furfural and extracting lignin from a hemi-cellulosic biomass solution comprising a total quantity of C5 sugars, comprising the steps of heating the hemi-cellulosic biomass solution to a temperature of at least about 200°C; acidifying the hemi-cellulosic biomass solution with acid to produce the furfural in vapor phase; and condensing the furfural to recover furfural in solution, wherein the furfural is produced at a total molar yield of at least 70% of moles of furfural produced/the total moles C5 sugars present in the initial hemi-cellulosic biomass solution. Low molecular weight lignin can also be recovered from the hemi-cellulosic biomass solution prior to furfural production by membrane concentration, acidification, coagulation and filtration.

    LIGNIN RECOVERY AND FURFURAL PRODUCTION FROM BIOMASS PREHYDROLYSATE STREAMS

    公开(公告)号:CA3018578C

    公开(公告)日:2020-09-08

    申请号:CA3018578

    申请日:2017-04-20

    Applicant: FPINNOVATIONS

    Abstract: The present invention relates to a method of producing furfural and extracting lignin from a hemi-cellulosic biomass solution comprising a total quantity of C5 sugars, comprising the steps of heating the hemi-cellulosic biomass solution to a temperature of at least about 200°C; acidifying the hemi-cellulosic biomass solution with acid to produce the furfural in vapor phase; and condensing the furfural to recover furfural in solution, wherein the furfural is produced at a total molar yield of at least 70% of moles of furfural produced/the total moles C5 sugars present in the initial hemi-cellulosic biomass solution. Low molecular weight lignin can also be recovered from the hemi-cellulosic biomass solution prior to furfural production by membrane concentration, acidification, coagulation and filtration.

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