公开(公告)号：US3555062A

公开(公告)日：1971-01-12

申请号：US3555062D

申请日：1967-09-11

Applicant: GEN ELECTRIC

Inventor： BROWN EDGAR D JR

IPC: C10M169/04 ,  C07F7/08 ,  C07F7/12 ,  C07F7/21 ,  C10N30/06

CPC classification number: C07F7/0889 ,  C07F7/085 ,  C07F7/12 ,  C07F7/21 ,  C10M1/08 ,  C10M2201/041 ,  C10M2201/042 ,  C10M2201/102 ,  C10M2201/103 ,  C10M2201/105 ,  C10M2203/10 ,  C10M2203/102 ,  C10M2203/108 ,  C10M2227/04 ,  C10M2229/02 ,  C10M2229/04 ,  C10M2229/041 ,  C10M2229/042 ,  C10M2229/043 ,  C10M2229/044 ,  C10M2229/05 ,  C10M2229/051 ,  C10N2240/402 ,  C10N2240/403 ,  C10N2240/404 ,  C10N2240/405 ,  C10N2240/406 ,  C10N2240/407 ,  C10N2240/408 ,  C10N2240/409 ,  C10N2250/10

Abstract: MIXTURES OF DIHALOGENOETHYL-SUBSTITUTED ORGANOSILICON COMPOSITIONS HAVE BEEN PREPARED BY ADDING EITHER IBR OR IC1 TO VINYL-SUBSTITUTED SILANCES AND SIOLXANES. LUBRICATIING COMPOSITIONS OF EXTREME PRESSURE AND HIGH TEMPERATURE CHARACTERISTICS ARE PREPARED BY ADDING THE MXTURES TO OILS OF LUBRICATING VISCOITY. THE LUBRICATING COMPOSITIONS ARE ESPECIALLY USEFUL FOR LUBRICATING HIGH TEMPERATURE ALLOYS.

公开(公告)号：US3515670A

公开(公告)日：1970-06-02

申请号：US3515670D

申请日：1967-09-11

Applicant: GEN ELECTRIC

Inventor： BROWN EDGAR D JR

IPC: C10M1/50

CPC classification number: C10M1/08 ,  C10M2201/041 ,  C10M2201/042 ,  C10M2201/103 ,  C10M2201/105 ,  C10M2203/108 ,  C10M2227/04 ,  C10M2229/02 ,  C10M2229/041 ,  C10M2229/042 ,  C10M2229/05 ,  C10M2229/051 ,  C10M2229/052 ,  C10N2240/02 ,  C10N2240/08 ,  C10N2240/40 ,  C10N2240/402 ,  C10N2240/403 ,  C10N2240/404 ,  C10N2240/405 ,  C10N2240/406 ,  C10N2240/407 ,  C10N2240/408 ,  C10N2240/409 ,  C10N2250/10

公开(公告)号：US3505378A

公开(公告)日：1970-04-07

申请号：US3505378D

申请日：1966-12-12

Applicant: GEN ELECTRIC

Inventor： BROWN EDGAR D JR

IPC: C07F7/08

CPC classification number: C10M3/00 ,  C07F7/085 ,  C10M2229/051

公开(公告)号：US3694358A

公开(公告)日：1972-09-26

申请号：US3694358D

申请日：1970-05-11

Applicant: GEN ELECTRIC

Inventor： BROWN EDGAR D JR

IPC: C07F7/08 ,  C07F7/12 ,  C07F7/21 ,  C10M1/50

CPC classification number: C10M1/08 ,  C07F7/085 ,  C07F7/0889 ,  C07F7/12 ,  C07F7/21 ,  C10M2201/041 ,  C10M2201/042 ,  C10M2201/102 ,  C10M2201/103 ,  C10M2201/105 ,  C10M2203/10 ,  C10M2203/102 ,  C10M2203/108 ,  C10M2227/04 ,  C10M2229/02 ,  C10M2229/04 ,  C10M2229/041 ,  C10M2229/042 ,  C10M2229/043 ,  C10M2229/044 ,  C10M2229/05 ,  C10M2229/051 ,  C10N2240/402 ,  C10N2240/403 ,  C10N2240/404 ,  C10N2240/405 ,  C10N2240/406 ,  C10N2240/407 ,  C10N2240/408 ,  C10N2240/409 ,  C10N2250/10

Abstract: MIXTURES OF DIHALOGENOETHYL-SUBSTITUTED ORGANOSILICON COMPOSITIONS HAVE BEEN PREPARED BY ADDING EITHER IBR OR ICI TO VINYL-SUBSTITUTED SILANES AND SILOXANES. LUBRICATING COMPOSITIONS OF EXTREME PRESSURE AND HIGH TEMPERATURE CHARACTERISTICS ARE PREPARED BY ADDING THE MIXTURES TO OILS OF LUBRICATING VISCOSITY. THE LUBRICATING COMPOSITIONS ARE ESPECIALLY USEFUL FOR LUBRICATING HIGH TEMPERATURE ALLOYS.

公开(公告)号：US3676349A

公开(公告)日：1972-07-11

申请号：US3676349D

申请日：1970-09-25

Applicant: GEN ELECTRIC

Inventor： BROWN EDGAR D JR

IPC: C07C43/12 ,  C10M131/10 ,  C10M131/12 ,  C10M1/30

CPC classification number: C07C43/12 ,  C07C43/126 ,  C10M131/10 ,  C10M131/12 ,  C10M2201/041 ,  C10M2201/042 ,  C10M2201/102 ,  C10M2201/103 ,  C10M2201/105 ,  C10M2203/02 ,  C10M2203/022 ,  C10M2203/024 ,  C10M2203/04 ,  C10M2211/042 ,  C10M2211/044 ,  C10M2211/06 ,  C10N2240/40

Abstract: Compositions substituted with iodine, with either bromine or chlorine, and with either alkoxy, acyloxy, or hydroxy groups are prepared by adding a mixture of iodine and either bromine or chlorine or IBr or ICl to alpha-olefins in the presence of alcohols, carboxylic acids, or water. Lubricating compositions useful for lubricating high temperature alloys are prepared by adding such compounds to oils of lubricating viscosity.

Abstract translation: 通过在醇，羧酸存在下，通过将碘和溴或氯或IBr或ICl的混合物加入到α-烯烃中来制备用溴或氯代烷氧基，酰氧基或羟基取代的组合物 ，或水。 用于润滑高温合金的润滑组合物是通过将这些化合物加入润滑粘度的油中制备的。

公开(公告)号：US3579467A

公开(公告)日：1971-05-18

申请号：US3579467D

申请日：1968-11-27

Applicant: GEN ELECTRIC

Inventor： BROWN EDGAR D JR

IPC: C07F7/08 ,  C08G77/38 ,  C08L83/06 ,  C09K15/32 ,  C10M169/00 ,  C10M169/04 ,  C10M1/50

CPC classification number: C08L83/06 ,  C07F7/085 ,  C08G77/38 ,  C09K15/328 ,  C10M3/00 ,  C10M7/00 ,  C10M169/04 ,  C10M2201/063 ,  C10M2201/105 ,  C10M2207/125 ,  C10M2207/129 ,  C10M2209/107 ,  C10M2215/065 ,  C10M2223/04 ,  C10M2223/041 ,  C10M2229/025 ,  C10M2229/0405 ,  C10M2229/041 ,  C10M2229/0415 ,  C10M2229/0425 ,  C10M2229/0435 ,  C10M2229/0445 ,  C10M2229/045 ,  C10M2229/0455 ,  C10M2229/046 ,  C10M2229/0465 ,  C10M2229/047 ,  C10M2229/0475 ,  C10M2229/048 ,  C10M2229/0485 ,  C10M2229/0505 ,  C10M2229/051 ,  C10M2229/0515 ,  C10M2229/0525 ,  C10M2229/053 ,  C10M2229/0535 ,  C10M2229/0545 ,  C10N2210/01 ,  C10N2240/08 ,  C10N2250/10

Abstract: ORGANOPOLYSILOXANES USEFUL AS HYDRAULIC FLUIDS COMPRISE ORGANOPOLYSILOXANES IN WHICH A MAJORITY OF THE SILOXANE GROUPS CONTAIN METHYL RADICALS AND HIGHER ALKYL RADICALS, AND A MINOR PROPORTION OF THE SILOXANE GROUPS CONTAIN SILICON-BONDED TERTIARY BUTYL-SUBSTITUTED HYDROXYARYL RADICALS ATTACHED TO SILICON THROUGH A DIVALENT PROPYLENE RADICAL. OPTIONALLY, A MINOR AMOUNT OF ARYL AND ARALKYL RADICALS CAN ALSO BE PRESENT ON THE SILOXANE GROUPS. THESE COMPOUNDS ARE PREPARED BY REACTING POLYSILOXANES CONTAINING METHYLHYDROGEN UNITS AND PHENYLHYDROGEN UNITS WITH HIGHER ALKENES AND HYDROXYARYL COMPOUNDS CONTAINING BOTH NUCLEAR SUBSTITUTED ALLYL RADICALS AND NUCLEAR SUBSTITUTED TERTIARY BUTYL RADICALS.

公开(公告)号：US3639238A

公开(公告)日：1972-02-01

申请号：US3639238D

申请日：1970-06-10

Applicant: GEN ELECTRIC

Inventor： BROWN EDGAR D JR

IPC: C07F7/08 ,  C07F7/12 ,  C07F7/21 ,  C10M1/50

CPC classification number: C10M1/08 ,  C07F7/0852 ,  C07F7/0859 ,  C07F7/12 ,  C07F7/21 ,  C10M2201/041 ,  C10M2201/042 ,  C10M2201/102 ,  C10M2201/103 ,  C10M2201/105 ,  C10M2203/10 ,  C10M2203/102 ,  C10M2203/108 ,  C10M2227/04 ,  C10M2229/02 ,  C10M2229/04 ,  C10M2229/041 ,  C10M2229/042 ,  C10M2229/043 ,  C10M2229/044 ,  C10M2229/05 ,  C10M2229/051 ,  C10N2240/02 ,  C10N2240/08 ,  C10N2240/40 ,  C10N2240/401 ,  C10N2240/402 ,  C10N2240/403 ,  C10N2240/404 ,  C10N2240/405 ,  C10N2240/406 ,  C10N2240/407 ,  C10N2240/408 ,  C10N2240/409 ,  C10N2250/10

Abstract: Lubricating compositions useful for lubricating high-temperature alloys are prepared by adding organosilicon compounds containing silicon-bonded ethyl groups substituted with iodine, with bromine or chlorine, and with alkoxy, acyloxy or hydroxy groups to oils of lubricating viscosity. The organosilicon compounds are prepared by adding I2 and Br2, I2 and Cl2, IBr, or ICl to vinylsubstituted silanes and siloxanes in the presence of alcohols or carboxylic acids or with subsequent water treatment.

Abstract translation: 用于润滑高温合金的润滑组合物通过将含有与碘取代的硅键合乙基的有机硅化合物与溴或氯以及与烷氧基，酰氧基或羟基相加的润滑粘度的油加入来制备。 通过在醇或羧酸存在下将I2和Br2，I2和Cl2，IBr或IC1加入到乙烯基取代的硅烷和硅氧烷中或随后的水处理来制备有机硅化合物。

公开(公告)号：US3557175A

公开(公告)日：1971-01-19

申请号：US3557175D

申请日：1969-11-03

Applicant: GEN ELECTRIC

Inventor： BROWN EDGAR D JR

IPC: C07F7/08 ,  C07F7/12 ,  C07F7/21 ,  C07F7/18

CPC classification number: C10M1/08 ,  C07F7/0852 ,  C07F7/0859 ,  C07F7/12 ,  C07F7/21 ,  C10M2201/041 ,  C10M2201/042 ,  C10M2201/102 ,  C10M2201/103 ,  C10M2201/105 ,  C10M2203/10 ,  C10M2203/102 ,  C10M2203/108 ,  C10M2227/04 ,  C10M2229/02 ,  C10M2229/04 ,  C10M2229/041 ,  C10M2229/042 ,  C10M2229/043 ,  C10M2229/044 ,  C10M2229/05 ,  C10M2229/051 ,  C10N2240/02 ,  C10N2240/08 ,  C10N2240/40 ,  C10N2240/401 ,  C10N2240/402 ,  C10N2240/403 ,  C10N2240/404 ,  C10N2240/405 ,  C10N2240/406 ,  C10N2240/407 ,  C10N2240/408 ,  C10N2240/409 ,  C10N2250/10

Abstract: ORGANOSILICON COMPOUNDS CONTAINING SILICON-BONDED ETHYL GROUPS SUBSTITUTED WITH IODINE, WITH BROMINE OR CHLORINE, AND WITH ALKOXY, ACYLOXY, OR HYDROXY GROUPS HAVE BEEN PREPARED BY ADDING I2 AND BR2, I2 AND CL2, IBR, OR ICI TO VINYL-SUBSTITUTED SILANES AND SILOXANES IN THE PRESENCE OF ALCOHOLS OR CARBOXYLIC ACIDS OR WITH SUBSEQUENT WATER TREATMENT. LUBRICATING COMPOSITIONS USEFUL FOR LUBRICATING HIGH TEMPERATURE ALLOYS ARE PREPARED BY ADDING SUCH SUBSTITUTED ORGANOSILICON COMPOUNDS TO OILS OF LUBRICATING VISCOSITY.

公开(公告)号：US3479290A

公开(公告)日：1969-11-18

申请号：US3479290D

申请日：1966-12-12

Applicant: GEN ELECTRIC

Inventor： BROWN EDGAR D JR

IPC: C07F7/08 ,  C08G77/16 ,  C08G77/38 ,  C08L83/06 ,  C09K15/32 ,  C10M169/04 ,  C10M1/44 ,  C10M1/50

CPC classification number: C10M169/04 ,  C07F7/085 ,  C08G77/38 ,  C08L83/06 ,  C09K15/328 ,  C10M3/00 ,  C10M7/00 ,  C10M107/50 ,  C10M137/04 ,  C10M2201/063 ,  C10M2201/105 ,  C10M2207/125 ,  C10M2207/129 ,  C10M2209/107 ,  C10M2215/065 ,  C10M2223/04 ,  C10M2223/041 ,  C10M2229/025 ,  C10M2229/0405 ,  C10M2229/041 ,  C10M2229/0415 ,  C10M2229/0425 ,  C10M2229/0435 ,  C10M2229/0445 ,  C10M2229/045 ,  C10M2229/0455 ,  C10M2229/046 ,  C10M2229/0465 ,  C10M2229/047 ,  C10M2229/0475 ,  C10M2229/048 ,  C10M2229/0485 ,  C10M2229/05 ,  C10M2229/0505 ,  C10M2229/051 ,  C10M2229/0515 ,  C10M2229/0525 ,  C10M2229/053 ,  C10M2229/0535 ,  C10M2229/0545 ,  C10N2210/01 ,  C10N2240/08 ,  C10N2250/10

Abstract: 1,205,222. Organopolysiloxanes. GENERAL ELECTRIC CO. 28 Nov., 1967 [12 Dec., 1966], No. 54185/67. Heading C3T. [Also in Division C5] An organopolysiloxane or a mixture of organopolysiloxanes useful as lubricants have the formula or average general formula in which R is a higher alkyl radical (i.e. at least 8 carbon atoms), R 1 is a t-butyl-substituted hydroxyaryl radical; a + b = 5-40 and the ratio b to a + b = 0.005-0.05. R 1 may be selected from radicals: A composition may comprise a mixture of an organopolysiloxane: and a second organopolysiloxane of formula in which a = 5-40, c = 0-39, d = 1-40 and c+d=1-40. A composition in accordance with Formula I may also comprise a mixture of an organopolysiloxane of formula (B) (a= 5-10) and a cyclic polymer of formula in which e = 3 to 7. In a preferred polymer R is tetradecyl and R 1 has the formula of Formula II above. The organopolysiloxane(s) are liquids but may be compounded with a thickener, e.g. silica, to form a silicone grease. The polyorganosiloxanes may, for example, be prepared from a phenolic compound having t-butyl radicals in both meta-positions to the OH group by first replacing one of the t-butyl radicals with an allyl radical to give a compound R 1 CH 2 -CH = CH 2 (R 1 as previously defined) and reacting this compound with an organopolysiloxane containing Si-H linkages.

公开(公告)号：US3441585A

公开(公告)日：1969-04-29

申请号：US3441585D

申请日：1966-12-12

Applicant: GEN ELECTRIC

Inventor： BROWN EDGAR D JR

IPC: C07F7/08 ,  C10M1/50

CPC classification number: C07F7/0896 ,  C07F7/085 ,  C10M1/08 ,  C10M2201/105 ,  C10M2229/054 ,  C10N2220/02 ,  C10N2250/10