公开(公告)号：WO2004014627A3

公开(公告)日：2004-04-08

申请号：PCT/US0325357

申请日：2003-08-12

Applicant: GEN MOTORS CORP

Inventor： KIA HAMID G ,  KIA SHEILA F

IPC: B29C20060101 ,  B29C31/00 ,  B29C33/38 ,  B29C37/00 ,  B29C41/22 ,  B29C43/02 ,  B29C70/30 ,  B60J7/00 ,  D06N7/04

CPC classification number: B29C43/021 ,  B29C37/0032 ,  B29C37/0053 ,  B29C70/30 ,  B29C2037/0035 ,  B29C2043/023 ,  B29L2031/3008

Abstract: A composite article (12) is manufactured in an open tool molding process, advantageously with a mold made of a polymer material. A coating layer (20) is applied onto the mold surface (18) and physically deformed to provide a textured surface (22) away from the mold prior to complete cure. Thereafter a composite material is applied onto the textured coating surface such that the composite material adjacent to textured coating surface substantially conforms to the shape of the textured coating surface. The composite article may be a gel coat material (14) from which the coating layer is removed after de-molding to reveal a textured surface layer in the gel coat.

Abstract translation: 复合制品（12）在开放的工具模制工艺中制造，有利地是由聚合物材料制成的模具。 将涂层（20）施加到模具表面（18）上并物理变形，以在完全固化之前提供远离模具的纹理表面（22）。 此后，将复合材料施加到纹理化涂层表面上，使得与纹理化涂层表面相邻的复合材料基本上符合纹理化涂层表面的形状。 复合制品可以是凝胶涂层材料（14），在脱模后从该涂层材料去除涂层，以在凝胶涂层中露出纹理表面层。

公开(公告)号：WO2004013236A3

公开(公告)日：2004-05-27

申请号：PCT/US0322677

申请日：2003-07-21

Applicant: GEN MOTORS CORP

Inventor： KIA SHEILA F ,  RAI DEVI N ,  KIA HAMID G

IPC: B29C37/00 ,  B29C41/02 ,  B29C70/02 ,  B29C70/30 ,  B29C71/02 ,  B32B5/26 ,  B32B17/04 ,  B32B17/10 ,  B32B27/20 ,  B32B27/30 ,  B32B27/36 ,  C08G18/67 ,  C09D175/16

CPC classification number: B32B27/40 ,  B32B17/04 ,  B32B27/08 ,  B32B27/20 ,  B32B27/30 ,  B32B27/36 ,  B32B2315/085 ,  B32B2367/00 ,  B32B2375/00 ,  B32B2605/08 ,  C08G18/672 ,  C08G2220/00 ,  C09D175/16 ,  Y10T428/31565 ,  Y10T428/31786 ,  Y10T428/31794 ,  C08G18/68 ,  C08G18/42

Abstract: Composite articles are prepared by a spray up operation. In a first step, a gel coat is applied onto a mold surface (12) which has been optionally pretreated with a mold release coating (14). Next, a barrier coating (16) is applied over the gel coat in the mold and thereafter a laminate formula (18) is applied over the barrier coat (16). The laminate contains from 20-60% by weight reinforcing fibers. In a preferred embodiment, the multilayer composite has a thickness of about 15 mm or less, and is useful as an automobile body panel. The gel coat contains a curable polyester polyurethane acrylate resin, and the composite article has a surface that has high gloss and color retention after prolonged exposure to ultraviolet radiation. The laminate preferably comprises a low shrink, low density glass fiber filled polyester resin. In a preferred embodiment, the paste of the laminate contains a dicyclopentadiene unsaturated polyester resin, polymeric hollow microspheres, and an initiator capable of initiating curing at room temperature or at temperature of 50°C or less.

Abstract translation: 复合制品通过喷雾操作制备。 在第一步骤中，将凝胶涂层施加到已经任选地用脱模涂层（14）预处理的模具表面（12）上。 接下来，将阻挡涂层（16）施加在模具中的凝胶涂层上，然后将层压配方（18）涂覆在阻挡涂层（16）上。 层压材料含有20-60％（重量）的增强纤维。 在优选的实施方案中，多层复合材料具有约15mm或更小的厚度，并且可用作汽车车身面板。 凝胶涂层含有可固化的聚酯聚氨酯丙烯酸酯树脂，并且复合制品具有在长时间暴露于紫外线辐射之后具有高光泽和保色性能的表面。 层压体优选包括低收缩，低密度玻璃纤维填充的聚酯树脂。 在优选的实施方案中，层压体的糊状物含有二环戊二烯不饱和聚酯树脂，聚合物中空微球体和能够在室温或50℃或更低温度下引发固化的引发剂。

公开(公告)号：WO2004015004A3

公开(公告)日：2004-03-18

申请号：PCT/US0322668

申请日：2003-07-21

Applicant: GEN MOTORS CORP ,  VALSPAR SOURCING INC

Inventor： KIA SHEILA F ,  RAI DEVI N ,  KIA HAMID G ,  GARNER ARCHIE W ,  ASHAI EHTISHAM A ,  ROBERTSON BRIAN A ,  MELNYK THOMAS J

IPC: C08G18/32 ,  C08G18/67 ,  C09D175/16 ,  C08G18/04

CPC classification number: C09D175/16 ,  C08G18/3271 ,  C08G18/672 ,  C08G18/42 ,  C08G18/68

Abstract: A gel coat for a surface of a composite article contains a curable urethane acrylate resin preferably based on aliphatic polyester polyols and aliphatic polyisocyanates. The gel coat provides a surface that has high gloss and color retention after prolonged exposure to ultraviolet radiation. The gel coat composition contains resin and acrylic diluents, including optional difunctional and trifunctional diluents. The gel coat is optionally pigmented to produce an article that may be used without further surface treatment.

Abstract translation: 用于复合制品表面的胶衣包含优选基于脂族聚酯多元醇和脂族多异氰酸酯的可固化氨基甲酸酯丙烯酸酯树脂。 在长时间暴露于紫外线辐射之后，胶衣提供了具有高光泽度和颜色保持力的表面。 凝胶涂料组合物含有树脂和丙烯酸稀释剂，包括任选的双官能和三官能稀释剂。 任选地将凝胶涂层着色以产生可以在没有进一步表面处理的情况下使用的制品。

公开(公告)号：EP1545851A4

公开(公告)日：2006-03-29

申请号：EP03785261

申请日：2003-08-12

Applicant: GEN MOTORS CORP

Inventor： KIA HAMID G ,  KIA SHEILA F

IPC: B29C31/00 ,  B29C20060101 ,  B29C33/38 ,  B29C37/00 ,  B29C41/22 ,  B29C43/02 ,  B29C70/30 ,  B60J7/00 ,  D06N7/04

CPC classification number: B29C43/021 ,  B29C37/0032 ,  B29C37/0053 ,  B29C70/30 ,  B29C2037/0035 ,  B29C2043/023 ,  B29L2031/3008

Abstract: A composite article (12) is manufactured in an open tool molding process, advantageously with a mold made of a polymer material. A coating layer (20) is applied onto the mold surface (18) and physically deformed to provide a textured surface (22) away from the mold prior to complete cure. Thereafter a composite material is applied onto the textured coating surface such that the composite material adjacent to textured coating surface substantially conforms to the shape of the textured coating surface. The composite article may be a gel coat material (14) from which the coating layer is removed after de-molding to reveal a textured surface layer in the gel coat.

Abstract translation: 复合制品（12）在开放的工具模制工艺中制造，有利地由由聚合物材料制成的模具制成。 将涂层（20）施加到模具表面（18）上并物理变形，以在完全固化之前提供远离模具的纹理表面（22）。 此后，将复合材料施加到纹理化涂层表面上，使得与纹理化涂层表面相邻的复合材料基本上符合纹理化涂层表面的形状。 复合制品可以是凝胶涂层材料（14），在脱模后从该涂层材料去除涂层，以在凝胶涂层中露出纹理表面层。

公开(公告)号：EP1539452A4

公开(公告)日：2006-04-05

申请号：EP03766882

申请日：2003-07-21

Applicant: GEN MOTORS CORP

Inventor： KIA SHEILA F ,  RAI DEVI N ,  KIA HAMID G

IPC: B29C37/00 ,  B29C41/02 ,  B29C70/02 ,  B29C70/30 ,  B29C71/02 ,  B32B5/26 ,  B32B17/04 ,  B32B17/10 ,  B32B27/20 ,  B32B27/30 ,  B32B27/36 ,  C08G18/67 ,  C09D175/16

CPC classification number: B32B27/40 ,  B32B17/04 ,  B32B27/08 ,  B32B27/20 ,  B32B27/30 ,  B32B27/36 ,  B32B2315/085 ,  B32B2367/00 ,  B32B2375/00 ,  B32B2605/08 ,  C08G18/672 ,  C08G2220/00 ,  C09D175/16 ,  Y10T428/31565 ,  Y10T428/31786 ,  Y10T428/31794 ,  C08G18/68 ,  C08G18/42

Abstract: Composite articles are prepared by a spray up operation. In a first step, a gel coat is applied onto a mold surface (12) which has been optionally pretreated with a mold release coating (14). Next, a barrier coating (16) is applied over the gel coat in the mold and thereafter a laminate formula (18) is applied over the barrier coat (16). The laminate contains from 20-60% by weight reinforcing fibers. In a preferred embodiment, the multilayer composite has a thickness of about 15 mm or less, and is useful as an automobile body panel. The gel coat contains a curable polyester polyurethane acrylate resin, and the composite article has a surface that has high gloss and color retention after prolonged exposure to ultraviolet radiation. The laminate preferably comprises a low shrink, low density glass fiber filled polyester resin. In a preferred embodiment, the paste of the laminate contains a dicyclopentadiene unsaturated polyester resin, polymeric hollow microspheres, and an initiator capable of initiating curing at room temperature or at temperature of 50°C or less.

Abstract translation: 复合制品通过喷雾操作制备。 在第一步中，将凝胶涂层施加到模具表面上。 接下来，在模具中的凝胶涂层上施加阻隔涂层，然后将层压配方施加在阻挡涂层上。 在优选的实施方案中，多层复合材料具有约15mm或更小的厚度，并且可用作汽车车身面板。 凝胶涂层含有可固化的聚酯聚氨酯丙烯酸酯树脂，并且复合制品具有在长时间暴露于紫外线辐射之后具有高光泽和保色性能的表面。

公开(公告)号：JP2002052555A

公开(公告)日：2002-02-19

申请号：JP2001169587

申请日：2001-06-05

Applicant: GEN MOTORS CORP

Inventor： KIA HAMID G ,  KIA SHEILA F ,  SIMMER JOSEPH C ,  WATHEN TERRENCE J ,  BUFFA MARK A

IPC: B29C41/22 ,  B29C37/00 ,  B29C41/08 ,  B29K31/00 ,  B29K33/00 ,  B29K101/10 ,  B29K105/08 ,  D06N7/04

Abstract: PROBLEM TO BE SOLVED: To manufacture a composite article subjected to texture finish resistant to damage by casting work at a low cost using a polymer casting mold having a casting surface. SOLUTION: In a casting process using a texture interface layer 20 for separating the surface of the casting mold 10 from the surface of the composite article 12 manufactured using the casting mold 10, a solution is deposited on the surface 18 of the casting mold 10 in order to form the interface layer 20. The surface of the interface layer provided on the opposite side of the casting mold is formed into a textured surface. Next, the texture of the interface layer 20 is transferred to the surface of the composite article 12 manufactured by the casting mold 10. After the casting mold 10 is detached, the interface layer 20 is bonded to the composite article 12 as a protective coating. Since the textured surface provided on the under side of the article 12 is exposed, the interface layer 20 can be easily removed from the article 12.

公开(公告)号：DE60326078D1

公开(公告)日：2009-03-19

申请号：DE60326078

申请日：2003-08-12

Applicant: GEN MOTORS CORP

Inventor： KIA HAMID G ,  KIA SHEILA F

IPC: B29C31/00 ,  B29C20060101 ,  B29C33/38 ,  B29C37/00 ,  B29C41/22 ,  B29C43/02 ,  B29C70/30 ,  B60J7/00 ,  D06N7/04

公开(公告)号：DE60303068T2

公开(公告)日：2007-02-08

申请号：DE60303068

申请日：2003-07-23

Applicant: GEN MOTORS CORP

Inventor： KIA HAMID G ,  MITCHELL HARRY A ,  WATHEN TERRENCE J ,  BUFFA MARK A

IPC: B29C70/30 ,  B29C41/08 ,  B29C41/32 ,  B29C70/00 ,  B29C70/34 ,  B29C71/02 ,  B32B5/26 ,  B32B17/04 ,  B32B27/00 ,  B32B27/08 ,  B32B27/12

Abstract: Composite articles are prepared by a spray up operation. In a first step, a gel coat is applied onto a mold surface which has been optionally pretreated with a mold release coating. Next, a barrier coat is applied over the gel coat in the mold and thereafter a laminate formula is applied over the barrier coat. The laminate contains from 40-80% by weight paste and from 20-60% by weight reinforcing fibers. In a preferred embodiment, the paste comprises 90% or more by weight resin, up to 5% filler, and an initiator composition capable of initiating cure at a temperature of 50 DEG C or lower. In a preferred embodiment, the multilayer composite has a thickness of about 15 mm or less, and is useful as an automobile body panel. The laminate preferably comprises a low shrink, low density glass fiber filled polyester resin. In a preferred embodiment, the paste of the laminate contains a dicyclopentadiene unsaturated polyester resin, polymeric hollow microspheres, and an initiator capable of initiating curing at room temperature or at temperature of 50 DEG C or less.

公开(公告)号：ID30424A

公开(公告)日：2001-12-06

申请号：ID20010420

申请日：2001-05-29

Applicant: GEN MOTORS CORP

Inventor： KIA HAMID G ,  KIA SHEILA F ,  SIMMER JOSEPH C ,  WATHEN TERRENCE J ,  BUFFA MARK A

IPC: B29C41/22 ,  B29C37/00 ,  B29C41/08 ,  B29K31/00 ,  B29K33/00 ,  B29K101/10 ,  B29K105/08 ,  D06N7/04

Abstract: A molding process that uses a textured interfacial layer to isolate the surface of a mold (10) from the surface of a composite article produced with the mold (10). A solution (20) is deposited on the mold surface (18) to form the interfacial layer, whose surface (22) opposite the mold (10) is textured. The texture of the interfacial layer is then transferred to the surface of the composite article produced with the mold (10). After demolding, the interfacial layer adheres to the article as a protective coating, but can be readily removed from the article to expose an underlying textured surface of the article.

公开(公告)号：DE68913654T2

公开(公告)日：1994-06-09

申请号：DE68913654

申请日：1989-10-05

Applicant: GEN MOTORS CORP

Inventor： KIA HAMID G

IPC: B29C45/00 ,  B29C33/56 ,  B29C45/14 ,  B29C45/16 ,  B29C70/46 ,  B29K105/08 ,  B29L9/00 ,  B29C67/14

Abstract: A method of producing a glass fibre mat-reinforced plastic panel having at least one smooth appearance surface, using a set of two matched mould members (12,14) having interior mould surfaces defining a mould cavity contained therein, of which at least one (18) of said interior surfaces is the mirror image of the appearance surface of said panel, said method comprising the steps of placing at least one layer of glass fibre mat (20) in said mould cavity, pouring a liquid polymeric material into said cavity to saturate said glass fibre mat (20), closing said two mould members (12,14) together with at least one layer (22) of a flexible sheeting material disposed over and adjacent to the interior mould surface opposing said mirror image interior mold surface (18) for producing the appearance surface of said panel, clamping said two mould members (12,14) together, curing said polymeric material for a time sufficient to form the saturated mat (20) into a hard plastic panel, and then opening said matched mould members (12,14) to release a finished panel having at least one smooth appearance surface substantially free from fibre readout defects.