4.
    发明专利
    未知

    公开(公告)号:DE4439248A1

    公开(公告)日:1996-05-09

    申请号:DE4439248

    申请日:1994-11-03

    Applicant: HOECHST AG

    Abstract: Polyolefin moulding materials with a reduced tendency to peeling consist of an olefin polymer and 0.001-5 phr of an oxidised wax (I). Also claimed is a process for reducing peeling in the extrusion of polyolefin moulding materials, by adding 0.001-5 phr (I) to the material. Pref. (I) is an oxidised polyolefin wax. Pref. moulding material is based on polyethylene, propylene, polybutene-1, polyhexene-1, poly-4-methylpentene-1, polyoctene-1 or copolymers thereof.

    PROCESS FOR PREPARING LOW-MOLECULAR POLY-1-OLEFINS

    公开(公告)号:CZ2794A3

    公开(公告)日:1994-07-13

    申请号:CZ2794

    申请日:1994-01-06

    Applicant: HOECHST AG

    Abstract: A catalyst formed by reacting a magnesium alkoxide dispersion whose particle size is from 100 to 3000 nm with a compound of a metal from the group consisting of titanium, zirconium, vanadium and chromium and then with a chlorine-containing organoaluminium compound has very good hydrogen sensitivity and high activity even in the presence of molecular weight regulators such as hydrogen. This makes the catalyst highly suitable for the preparation of low-molecular-weight polyolefins. The catalyst enables the preparation of waxes having a reduced residual ash content. The large particle diameter and the low fines content of the polymer powder prepared by suspension polymerisation using this catalyst enable ready separation and drying of the suspension medium. The catalyst is furthermore advantageous in solution polymerisation and, due to the large particle diameter, can be used in gas-phase polymerisation for the preparation of low-molecular-weight poly-1-olefins.

    9.
    发明专利
    未知

    公开(公告)号:BR9400034A

    公开(公告)日:1994-07-26

    申请号:BR9400034

    申请日:1994-01-06

    Applicant: HOECHST AG

    Abstract: A catalyst formed by reacting a magnesium alkoxide dispersion whose particle size is from 100 to 3000 nm with a compound of a metal from the group consisting of titanium, zirconium, vanadium and chromium and then with a chlorine-containing organoaluminium compound has very good hydrogen sensitivity and high activity even in the presence of molecular weight regulators such as hydrogen. This makes the catalyst highly suitable for the preparation of low-molecular-weight polyolefins. The catalyst enables the preparation of waxes having a reduced residual ash content. The large particle diameter and the low fines content of the polymer powder prepared by suspension polymerisation using this catalyst enable ready separation and drying of the suspension medium. The catalyst is furthermore advantageous in solution polymerisation and, due to the large particle diameter, can be used in gas-phase polymerisation for the preparation of low-molecular-weight poly-1-olefins.

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